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61717-82-6

61717-82-6 Structure

61717-82-6 Structure
IdentificationMore
[Name]

2-Iodoxybenzoic acid
[CAS]

61717-82-6
[Synonyms]

1,2-BENZIODOXOL-3(1H)-ONE, 1-HYDROXY, 1-OXIDE
1-HYDROXY-1,2-BENZIODOXOL-3(1H)-ONE 1-OXIDE
1-HYDROXY-1,2-BENZIODOXOL-3(H)-ONE 1-OXIDE
2-IODOXYBENZOIC ACID, STABILIZED (45 WT&
IbxO-IodoxybenzoicAcid
2-Iodoxybenzoic acid, stabilized
2-Iodoxybenzoic acid
IBX(1-HYDROXY-1,2-BENZIODOXOL-3(1H)-ONE-1-OXIDE)
2-Iodoxybenzoic acid, stabilized (45 wt.% IBX)
SIBX, Stabilized IBX
2-Iodoxybenzoic acid ,39-50% [Stabilizer:Benzoic acid 23%,Isophtalic acid 30%]
1-Hydroxy-1,3-dioxo-3H-benz[d][1,2]iodoxol
1-Hydroxy-3H-benz[d][1,2]iodoxol-1,3-dione
[EINECS(EC#)]

629-407-7
[Molecular Formula]

C7H5IO4
[MDL Number]

MFCD02912492
[Molecular Weight]

280.02
[MOL File]

61717-82-6.mol
Chemical PropertiesBack Directory
[Appearance]

White to off-white powder, prills or agglomerates
[Melting point ]

280 °C
[storage temp. ]

Keep in dark place,Inert atmosphere,2-8°C
[solubility ]

DMSO (Very Slightly, Heated)
[form ]

powder to crystal
[color ]

White to Almost white
[Detection Methods]

HPLC
[Merck ]

14,5048
[InChIKey]

CQMJEZQEVXQEJB-UHFFFAOYSA-N
[CAS DataBase Reference]

61717-82-6(CAS DataBase Reference)
[Storage Precautions]

Light sensitive
Safety DataBack Directory
[Hazard Codes ]

C,Xi,Xn
[Risk Statements ]

R22:Harmful if swallowed.
R34:Causes burns.
R44:Risk of explosion if heated under confinement.
R42/43:May cause sensitization by inhalation and skin contact .
R36/37/38:Irritating to eyes, respiratory system and skin .
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S22:Do not breathe dust .
[RIDADR ]

UN 1759 8/PG 2
[WGK Germany ]

3
[HazardClass ]

8
[PackingGroup ]

[HS Code ]

29163990
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sulfuric acid-->Benzoic acid-->Potassium bromate-->Isophthalic acid-->2-Iodobenzoic acid-->o-Iodobenzoic acid sodium salt-->1-Hydroxy-2-oxa-1-ioda(III)indan-3-one-->2-Iodosobenzoic acid
[Preparation Products]

(5-BROMOTHIOPHEN-3-YL)METHANESULFONYL CHLORIDE-->Dess-Martin periodinane-->2,4-Dimethyl-3-pentanol-->Pinacol-->2-Methyl-2-butanol
Hazard InformationBack Directory
[Chemical Properties]

White to off-white powder, prills or agglomerates
[Uses]

2-Iodoxybenzoic Acid is used in the oxidation of alcohols in organic synthesis. It is also frequently used in the preparation of Dess-Martin periodinane.
[Definition]

ChEBI: A benziodoxole compound having hydroxy and oxo substituents at the 1-position and an oxo substituent at the 3-position.
[Synthesis Reference(s)]

The Journal of Organic Chemistry, 48, p. 4155, 1983 DOI: 10.1021/jo00170a070
[reaction suitability]

reagent type: oxidant
Spectrum DetailBack Directory
[Spectrum Detail]

2-Iodoxybenzoic acid(61717-82-6)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

2-Iodoxybenzoic acid, stabilized(61717-82-6)
[Sigma Aldrich]

61717-82-6(sigmaaldrich)
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