| Identification | More | [Name]
4-Iodotoluene | [CAS]
624-31-7 | [Synonyms]
1-IODO-4-METHYLBENZENE
4-IODOTOLUENE
AURORA KA-7367
IODOTOLUENE(4-)
P-IODOTOLUENE
1-iodo-4-methyl-benzen
1-Methyl-4-iodobenzene
4-Methyl-1-iodobenzene
4-Methyliodobenzene
4-Methylphenyliodide
benzene,1-iodo-4-methyl-
p-Iodomethylbenzene
p-Methyliodobenzene
p-Methylphenyliodide
p-Tolyl iodide
p-Tolyliodide
Toluene, p-iodo-
toluene,4-iodo-
Toluene,p-iodo-
4-Iodotouene | [EINECS(EC#)]
210-841-7 | [Molecular Formula]
C7H7I | [MDL Number]
MFCD00001059 | [Molecular Weight]
218.03 | [MOL File]
624-31-7.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE TO LIGHT YELLOW CRYSTALLINE LOW MELTING MASS | [Melting point ]
33-35 °C (lit.) | [Boiling point ]
211.5 °C (lit.) | [density ]
1,678 g/cm3 | [refractive index ]
1.6155 (estimate) | [Fp ]
194 °F
| [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [solubility ]
Solubility in methanol is almost transparent. | [form ]
Crystalline Low Melting Mass | [color ]
White to light yellow | [Water Solubility ]
insoluble | [Sensitive ]
Light Sensitive | [BRN ]
1903637 | [InChIKey]
UDHAWRUAECEBHC-UHFFFAOYSA-N | [CAS DataBase Reference]
624-31-7(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzene, 1-iodo-4-methyl-(624-31-7) | [EPA Substance Registry System]
624-31-7(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/38:Irritating to eyes and skin .
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S24/25:Avoid contact with skin and eyes .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice . | [WGK Germany ]
3
| [Hazard Note ]
Irritant | [TSCA ]
T | [HazardClass ]
IRRITANT | [HS Code ]
29036990 |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE TO LIGHT YELLOW CRYSTALLINE LOW MELTING MASS | [Uses]
suzuki reaction | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 52, p. 691, 1987 DOI: 10.1021/jo00380a041
Synthesis, p. 572, 1980 DOI: 10.1055/s-1980-29128 | [General Description]
4-Iodotoluene undergoes Suzuki-Miyaura coupling reaction with phenylboronic acid catalyzed by (Ni,Mg)3Si2O5(OH)4 solid-solution nanotubes loaded with palladium. Cobalt-catalyzed coupling of 4-iodotoluene with thiophenols and alkanethiols has been investigated. Palladium/copper-catalyzed Sonogashira cross-coupling reaction of 4-iodotoluene with phenylacetylene has been studied. | [Purification Methods]
Crystallise 4-iodotoluene from EtOH and.or distil it. [Beilstein 5 IV 840.] |
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