| Identification | More | [Name]
2-BUTENE | [CAS]
624-64-6 | [Synonyms]
2-BUTENE
2-BUTENE (TRANS)
2-BUTYLENE
CIS/TRANS-2-BUTENE
TRANS-2-BUTENE
TRANS-B-BUTYLENE
TRANS-BUTENE-2
TRANS-PSEUDOBUTYLENE
TRANS-SYM-DIMETHYLETHYLENE
(E)-2-Butene
(E)-2-C4H8
(E)-But-2-ene
2-Butene,(E)-
2-trans-Butene
beta-trans-butylene
low-boilingbutene-2
t-butene-2
trans-1,2-Dimethylethylene
trans-but-2-ene
trans-Butene | [EINECS(EC#)]
203-452-9 | [Molecular Formula]
C4H8 | [MDL Number]
MFCD00064458 | [Molecular Weight]
56.11 | [MOL File]
624-64-6.mol |
| Chemical Properties | Back Directory | [Appearance]
colourless gas | [Melting point ]
−140 °C(lit.)
| [Boiling point ]
1 °C(lit.)
| [density ]
0.5990 | [vapor density ]
2 (vs air)
| [vapor pressure ]
2575 mm Hg ( 37.7 °C)
| [refractive index ]
1.3932 | [Fp ]
<−30 °F
| [Stability:]
Stable. Incompatible with strong oxidizing agents, peroxides, peroxyacids, aluminium tetrahydroborate. Extremely flammable. | [explosive limit]
9.7% | [Merck ]
1520 | [BRN ]
1718756 | [InChIKey]
IAQRGUVFOMOMEM-ONEGZZNKSA-N | [CAS DataBase Reference]
624-64-6(CAS DataBase Reference) | [EPA Substance Registry System]
trans-2-Butene (624-64-6) |
| Safety Data | Back Directory | [Hazard Codes ]
F | [Risk Statements ]
R12:Extremely Flammable.
R11:Highly Flammable. | [Safety Statements ]
S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking .
S33:Take precautionary measures against static discharges .
S38:In case of insufficient ventilation, wear suitable respiratory equipment . | [RIDADR ]
UN 1012 2.1
| [WGK Germany ]
3
| [RTECS ]
EM2932000
| [Autoignition Temperature]
615 °F | [DOT Classification]
2.1 (Flammable gas) | [HazardClass ]
2.1 | [HS Code ]
2901230000 | [Hazardous Substances Data]
624-64-6(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
A colorless liquefied petroleum gas. An asphyxiant. Flammability limits of 1.8-9% by volume. | [Reactivity Profile]
The unsaturated aliphatic hydrocarbons, such as 2-BUTENE-TRANS(624-64-6), are generally much more reactive than the alkanes. Strong oxidizers may react vigorously with them. Reducing agents can react exothermically to release gaseous hydrogen. In the presence of various catalysts (such as acids) or initiators, compounds in this class can undergo very exothermic addition polymerization reactions. Aluminum borohydride reacts with alkenes and in the presence of oxygen, combustion is initiated even in the absence of moisture. | [Air & Water Reactions]
Highly flammable. Insoluble in water. | [Chemical Properties]
2-Butene, C4H8, can occur in trans or cis conformation;
the former is the more stable form. It is a colorless,
extremely flammable gas. 2-Butene occurs in coal gas
and has been detected in diesel exhaust. The more
highly reactive trans-2-butene occurs at much lower concentrations
in the atmosphere than other comparable
hydrocarbons. | [Chemical Properties]
colourless gas | [Uses]
trans-2-Butene can be used as a monomer unit to produce high molecular weight polyolefins with well-defined microstructures by nickle-catalyzed polymerization reaction. It is also used as a reactant in the isomerization reaction to produce the corresponding isomer using acid-activated catalysts. | [Definition]
ChEBI: But-2-ene is a butene. | [Production Methods]
2-Butene has been recovered from refining gases or produced
by petroleum cracking. It is a component in the
production of gasolines, butadiene, and a variety of other
chemicals. | [Purification Methods]
The gas is dried with CaH2 and purified by gas chromatography. [Beilstein 1 H 205, 1 II 176, 1 III 730, 1 IV 781.] HIGHLY FLAMMABLE. |
|
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