| Identification | Back Directory | [Name]
N-Benzylcinchonidinium chloride | [CAS]
69257-04-1 | [Synonyms]
BCDC
-hydroxy(quinolin-4-yl)
N-benzyl chlorideCinchonidine
N-BENZYLCINCHONIDINIUM CHLORIDE
N-Benzylcinchoninium chloride ,99%
N-Benzylcinchonidinium chloride ,99%
N-Benzylcinchonidinium Chloride
N-Benzylcinchonidinium chloride, BCDC
N-BENZYLCINCHONIDINIUM CHLORIDE HYDRATE
(8S,9R)-(-)-N-BENZYLCINCHONIDINIUM CHLORIDE
(8a,9r)-1-benzyl-9-hydroxycinchonanium chloride
(8S,9R)-(-)-BENZYLCINCHONIDINIUM CHLORID E, 98%
(8S,9R)-(-)-N-Benzylcinchonidinium chloride 98%
(8S,9R)-1-Benzyl-9-hydroxycinchonan-1-ium·chloride
(8alpha,9R)-1-benzyl-9-hydroxycinchonanium chloride
N-Benzylcinchonidinium Chloride [Chiral Phase-Transfer Catalyst]
Cinchonanium, 9-hydroxy-1-(phenylmethyl)-, chloride, (8.alpha.,9R)-
(αR,1S,4α)-α-(4-Quinolyl)-1β-benzyl-5β-vinyl-1-azoniabicyclo[2.2.2]octane-2α-methanol·chloride | [EINECS(EC#)]
273-938-3 | [Molecular Formula]
C26H29ClN2O | [MDL Number]
MFCD00082422 | [MOL File]
69257-04-1.mol | [Molecular Weight]
420.97 |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powde | [Melting point ]
210 °C (dec.)(lit.)
| [alpha ]
-188 º (c=0.4% in H2O) | [refractive index ]
-184 ° (C=1, H2O) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [solubility ]
soluble in Methanol | [form ]
powder to crystal | [color ]
White to Light yellow to Light orange | [optical activity]
[α]20/D 180°, c = 1.3 in H2O | [BRN ]
5421832 | [InChIKey]
FCHYSBWCOKEPNQ-WOIURNJWSA-M |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powde | [Purification Methods]
Dissolve the chloride in the minimum volume of H2O and add absolute Me2CO. Filter it off and dry it in a vacuum. It can also be recrystallised from hot EtOH or EtOH/Et2O. (A good chiral phase transfer catalyst-see above) [Colonna et al. J Chem Soc, Perkin Trans 1 547 1981, Imperali & Fisher J Org Chem 57 757 1992]. [Beilstein 23 H 446.] See cinchonidine below. |
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