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72824-04-5

72824-04-5 Structure

72824-04-5 Structure
IdentificationMore
[Name]

Allylboronic acid pinacol ester
[CAS]

72824-04-5
[Synonyms]

2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE
AKOS BRN-1082
ALLYLBORONIC ACID, PINACOL CYCLIC ESTER
ALLYLBORONIC ACID PINACOL ESTER
PINACOL ALLYLBORONATE
ALLBORONIC ACID,PINACOL CYCLIC ESTER
Allylboronic acid piracol ester
Allylboronic acid pinacol ester, 98+%
2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, Pinacol allylboronate
4,4,5,5-Tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane
Allylboronic acid pinacolate
[EINECS(EC#)]

672-877-3
[Molecular Formula]

C9H19BO3
[MDL Number]

MFCD00013347
[Molecular Weight]

186.06
[MOL File]

72824-04-5.mol
Chemical PropertiesBack Directory
[Appearance]

Clear corless liquid
[Boiling point ]

50-53 °C/5 mmHg (lit.)
[density ]

0.896 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.4268(lit.)
[Fp ]

115 °F
[storage temp. ]

Refrigerator
[solubility ]

Chloroform, Methanol (Slightly)
[form ]

Liquid
[color ]

Clear colorless
[Water Solubility ]

Not miscible or difficult to mix in water.
[BRN ]

4244068
[CAS DataBase Reference]

72824-04-5(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

UN 1993 3/PG 3
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

3
[PackingGroup ]

III
[HS Code ]

29310095
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane(72824-04-5).msds
Hazard InformationBack Directory
[Chemical Properties]

Clear corless liquid
[Uses]

Allylboronic acid pinacol ester can act as reagent used for Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis; Intermolecular radical additions; Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids and Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes ; Nucleic acid-templated energy transfer leading to a photorelease reaction .
[Uses]

Allylboronic acid pinacol ester reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield. Homoallylic alcohols can also be formed by allylboration of aldehydes. It is a reagent used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis, intermolecular radical additions, allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids, cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes, nucleic acid-templated energy transfer leading to a photorelease reaction and stereoselective indium-catalyzed Hosomi-Sakurai reactions.
Spectrum DetailBack Directory
[Spectrum Detail]

Allylboronic acid pinacol ester(72824-04-5)1HNMR
Allylboronic acid pinacol ester(72824-04-5)IR
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Allylboronic acid pinacol ester, 98%(72824-04-5)
[Alfa Aesar]

Allylboronic acid pinacol ester, 98+%(72824-04-5)
[Sigma Aldrich]

72824-04-5(sigmaaldrich)
[TCI AMERICA]

2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane,>97.0%(GC)(72824-04-5)
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