ChemicalBook--->CAS DataBase List--->8001-58-9

8001-58-9

8001-58-9 Structure

8001-58-9 Structure
IdentificationBack Directory
[Name]

CREOSOTE
[CAS]

8001-58-9
[Synonyms]

awpa#1
taroil
CREOSOTE
heavyoil
brickoil
CREOSATE
creosotum
creosotep1
creosoteoil
CARBOLINEUM
sakresote100
COALTARCRESOL
Coal creosote
caswellno.225
liquidpitchoil
naphthaleneoil
preserv-o-sote
cresyliccreosote
COAL TAR CREOSOTE
CREOSOTE COAL TAR
PETROLEUMCREOSOTE
Hodgsons Creosote
BEECHWOOD CREOSOTE
rcrawastenumberu051
COALTARCRESYLICACID
creosote,fromcoaltar
Pascoe's Creosote Oil KC-300
epapesticidechemicalcode025004
Creosote [The distillate of coal tar produced by the high temperature carbonization of bituminous coal. It consists primarily of aromatic hydrocarbons, tar acids and tar bases.]
[EINECS(EC#)]

232-419-1
[MDL Number]

MFCD00146582
Chemical PropertiesBack Directory
[Appearance]

The term “coal tar products,” as used by NIOSH, includes coal tar and two of the fractionation products of coal tar, creosote and coal tar pitch, derived from the carbonization of bituminous coal. Coal tar, coal tar pitch, and creosote (coal tar creosote 8001-58-9) derived from bituminous coal often contain identifiable components which by themselves are carcinogenic, such as benzo(a) pyrene, benzanthracene, chrysene, and phenanthrene. Other chemicals from coal tar products, such as anthracene, carbazole, fluoranthene, and pyrene may also cause cancer,but these causal relationships have not been adequately documented. Also, the research chemical methylcholanthrene (CAS: 56-49-5), a powerful carcinogen, fits this category. Coal tar pitch is a black viscous liquid. Aromatic solvent odor. Boiling point =>260°C; specific gravity (H2O:1) = 1.07-108; freezing/melting point = 250-°180C;flash point = 207°C (coal tar pitch); 74C (creosote oil);autoignition temperature =>510°C. Insoluble in water.Coal tar creosote (8001-58-9, crosote) is an black oily,tar-like substance. Pungent odor
[Melting point ]

20℃ (approx)
[Boiling point ]

200-220 °C(lit.)
[density ]

1.09 g/mL at 20 °C
[Fp ]

165°F (75°C); ignition temp 637°F (335°C)
[Odor]

Creosote or tarry; aromatic.
[Dielectric constant]

3.0(Ambient)
[IARC]

2A (Vol. Sup 7, 92) 2010
[EPA Substance Registry System]

Creosote (8001-58-9)
Hazard InformationBack Directory
[Chemical Properties]

dark green, brown or yellowish liquid
[Uses]

Wood preservative, disinfectant, insecticide.
[General Description]

CREOSOTE contains creosote, an EPA designated hazardous substance. CREOSOTE often contains substantial amounts of naphthalene and anthracene. The primary hazard is the threat posed to the environment. Immediate steps should be taken to limit its spread to the environment. Since CREOSOTE is a liquid CREOSOTE can easily penetrate the soil and contaminate groundwater and nearby streams.
[Air & Water Reactions]

CREOSOTE may be air sensitive. Insoluble in water.
[Reactivity Profile]

Phenols, such as CREOSOTE, do not behave as organic alcohols, as one might guess from the presence of a hydroxyl (-OH) group in their structure. Instead, they react as weak organic acids. Phenols and cresols are much weaker as acids than common carboxylic acids (phenol has Ka = 1.3 x 10^[-10]). These materials are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases. Such heating may initiate polymerization of the organic compound. Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature). The reactions generate heat. Phenols are also nitrated very rapidly, even by dilute nitric acid. CREOSOTE is incompatible with strong oxidizers.
[Health Hazard]

Vapors cause moderate irritation of nose and throat. Liquid causes severe burns of eyes and reddening and itching of skin. Prolonged contact with skin can cause burns. Ingestion causes salivation, vomiting, respiratory difficulties, thready pulse, vertigo, headache, loss of pupillary reflexes, hypothermia, cyanosis, mild convulsions.
[Fire Hazard]

Behavior in Fire: Heavy, irritating black smoke is formed.
[Hazard]

Toxic by inhalation of fumes, skin, and eye irritant. Use may be restricted. Probable carcinogen.
[Potential Exposure]

The coke-oven plant is the principal source of coal tar. The hot gases and vapors produced during the conversion of coal to coke are collected by means of a scrubber, which condenses the effluent into ammonia, water, crude tar, and other by-products. Crude tar is separated from the remainder of the condensate for refining and may undergo further processing. Employees may be exposed to pitch and creosote in metal and foundry operations; when installing electrical equipment; in construction, railway, utility; and briquette manufacturing.
[First aid]

If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.
[Shipping]

UN1136 Coal tar distillates, flammable, Hazard Class: 3; Labels: 3-Flammable liquid
[Incompatibilities]

Incompatible with strong oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Phenols, such as creosote react as weak organic acids. Phenols and cresols are much weaker as acids than common carboxylic acids (phenol has pKa = 9.88). These materials are incompatible with strong reducing agents such as hydrides, nitrides, alkali metals, and sulfides. Flammable hydrogen gas is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases. Such heating may initiate polymerization of the organic compound. Phenols are sulfonated very readily (e.g., by concentrated sulfuric acid at room temperature). The reactions generate heat. Phenols are also nitrated very rapidly, even by dilute nitric acid
[Waste Disposal]

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
[Definition]

The distillate of coal tar produced by the high temperature carbonization of bituminous coal. It consists primarily of aromatic hydrocarbons, tar acids and tar bases.
[Chemical Reactivity]

Reactivity with Water No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
Safety DataBack Directory
[Hazard Codes ]

T,C
[Risk Statements ]

23/24/25-34-48/20/21/22-68-45
[Safety Statements ]

26-36/37/39-45-53
[RIDADR ]

UN 2922 8/PG 2
[WGK Germany ]

3
[RTECS ]

GO5870000
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[HS Code ]

27079100
[Hazardous Substances Data]

8001-58-9(Hazardous Substances Data)
[Toxicity]

LD50 oral in rat: 725mg/kg
Raw materials And Preparation ProductsBack Directory
[Preparation Products]

Catechol-->Guaiacol-->3-Hydroxy-2-methyl-4H-pyran-4-one-->PYROLIGNEOUS ACID-->4-Ethyl-2-methoxyphenol
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