| Identification | More | [Name]
Acrylyl chloride | [CAS]
814-68-6 | [Synonyms]
2-PROPENOYL CHLORIDE
ACRYLIC ACID CHLORIDE
ACRYLOYL CHLORIDE
acrylyl chloride
Chlorid kyseliny akrylove
chloridkyselinyakrylove
Propenoyl chloride
propenoylchloride
ACRYLOYL CHLORIDE, 96%, STABILIZED
ACRYLOYL CHLORIDE STAB. WITH 2 6-DI-TER
ACRYLOYL CHLORIDE, STAB.
Acryloylchloride,96%
Acryloyl chloride, 96%, stab. with 400ppm phenothiazine
Acryloyl Chloride (stabilized with MEHQ) | [EINECS(EC#)]
212-399-0 | [Molecular Formula]
C3H3ClO | [MDL Number]
MFCD00000731 | [Molecular Weight]
90.51 | [MOL File]
814-68-6.mol |
| Chemical Properties | Back Directory | [Appearance]
Liquid | [Melting point ]
76 °C(Solv: isopropyl ether (108-20-3)) | [Boiling point ]
72-76 °C (lit.) | [density ]
1.119 g/mL at 20 °C
| [vapor density ]
>1 (vs air)
| [vapor pressure ]
1.93 psi ( 20 °C)
| [refractive index ]
n20/D 1.435(lit.)
| [Fp ]
61 °F
| [storage temp. ]
2-8°C
| [solubility ]
Chloroform (Soluble), Methanol (Slightly) | [form ]
Oil | [color ]
Colourless to Pale Yellow | [Stability:]
Stable, but reacts violently with water. Incompatible with alcohols, oxidizing agents, strong bases. Light-sensitive. Highly flammable. | [Water Solubility ]
Miscible with water. | [Sensitive ]
Moisture & Light Sensitive | [BRN ]
635744 | [Exposure limits]
ACGIH: TWA 5 mg/m3 (Skin)
NIOSH: TWA 5 mg/m3 | [InChIKey]
HFBMWMNUJJDEQZ-UHFFFAOYSA-N | [CAS DataBase Reference]
814-68-6(CAS DataBase Reference) | [NIST Chemistry Reference]
2-Propenoyl chloride(814-68-6) | [EPA Substance Registry System]
814-68-6(EPA Substance) |
| Safety Data | Back Directory | [Hazard Codes ]
F,T+ | [Risk Statements ]
R11:Highly Flammable.
R14:Reacts violently with water.
R26:Very Toxic by inhalation.
R34:Causes burns. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S7/9:Keep container tightly closed and in a well-ventilated place . | [RIDADR ]
UN 3383 6.1/PG 1
| [WGK Germany ]
3
| [RTECS ]
AT7350000
| [F ]
8-10 | [TSCA ]
Yes | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29161980 | [Hazardous Substances Data]
814-68-6(Hazardous Substances Data) |
| Hazard Information | Back Directory | [General Description]
A liquid. Boiling point 75°C. Used to make plastics. Polymerization in a closed container can cause pressurization and explosive rupture. | [Reactivity Profile]
ACRYLYL CHLORIDE(814-68-6) is incompatible with strong oxidizing agents, alcohols, amines, alkali. Polymerizes readily upon exposure to oxygen. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291]. | [Air & Water Reactions]
Polymerizes readily upon exposure to oxygen in the air. Reacts exothermically with water to give hydrochloric acid and acrylic acid. | [Potential Exposure]
May be used as a monomer in preparation of specialty polymers or as a chemical intermediate | [Fire Hazard]
When heated to decomposition, ACRYLYL CHLORIDE emits toxic fumes of chlorides. Decomposes in water. | [First aid]
If this chemical gets into the eyes, remove any contact lenses at once and irrigate immediately for at least 15 minutes, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts the skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove from exposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR if heart action has stopped. Transfer promptly to a medical facility. When this chemical has been swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit. Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. | [Shipping]
UN3383 Poisonous Toxic by inhalation liquid, flammable, n.o.s. with an LC50 # 200 mL/m3 and saturated vapor concentration ≥500 LC50, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid, Technical Name Required, Inhalation Hazard Zone A. UN2924 Flammable liquids, corrosive, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, 8-Corrosive material, Technical Name Required | [Incompatibilities]
Use MEHQ (monomethyl ether of hydroquinone) as an inhibitor. Incompatible with oxidizers, polymerizes on contact with oxygen; alcohols, amines, alkalis. Reacts violently with water, releasing hydrochloric acid and acrylic acid. Attacks some metals. | [Chemical Properties]
Acryloyl chloride is a highly flammable, polymerizable, and toxic (inhalation), light yellow liquid. A lacrimator. | [Uses]
Acryloyl chloride is used in the production of plastics. It plays an important role in the preparation of acrylate monomers and polymers. It also acts as a substrate for cross-metathesis. Further, it is utilized in organic synthesis for the introduction of acrylic groups into other compounds. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 72, p. 72, 1950 DOI: 10.1021/ja01157a020 |
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