| Identification | Back Directory | [Name]
(8α,9S)-9-aMino-Cinchonan-6'-ol | [CAS]
960050-59-3 | [Synonyms]
(8α,9S)-9-aMino-Cinchonan-6'-ol
(8α, 9S)-(+)-9-AMino-cinchonan-6'-ol, Min. 90% | [Molecular Formula]
C19H23N3O | [MDL Number]
MFCD27978392 |
| Questions And Answer | Back Directory | [Reaction]
1. [2+3]-dipolar cycloaddition of cyclic enones.
2. Activation of α,β-unsaturated carbonyl compounds:
a) vinylogous α-ketol rearrangement.
b) vinylogous Michael addition of β-substituted α,β-unsaturated cyclohexanones.
3. Michael addition
a) α-nitroacetate to α,β-unsaturated ketones.
b) Diastereodivergent Michael addition to α-substituted, α,β-unsaturated ketones.
4. α-benzoyloxylation of α-branched aldehydes.
5. [4+2]-cycloadditions of β-substituted α,β-unsaturated cyclohexanones with polyconjugated malonitriles.
6. Vinylogous organocascade catalysis with control of remote stereochemistry in the synthesis of spirocyclic oxindoles.
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