ChemicalBook--->CAS DataBase List--->99-72-9

99-72-9

99-72-9 Structure

99-72-9 Structure
IdentificationBack Directory
[Name]

FEMA 3078
[CAS]

99-72-9
[Synonyms]

FEMA 3078
2-(p-tolyl)propanal
2-(PARA-TOLYL)PROPANAL
p-methyl-hydratropaldehyd
P-METHYLHYDRATROPALDEHYDE
2-(p-tolyl)-propionaldehyd
2-(4-Methylphenyl)propanal
2-(P-TOLYL)-PROPIONALDEHYDE
2-(p-tolyl)propionicaldehyde
PARA-METHYLHYDRATROPALDEHYDE
2-(PARA-TOLYL)-PROPIONALDEHYDE
2-(PARA-TOLYL)-PROPIONICALDEHYDE
2-(4-Methylphenyl)propionaldehyde
2-(p-methylphenyl)propionaldehyde
Benzeneacetaldehyde, α,4-dimethyl-
alpha,4-dimethyl-benzeneacetaldehyd
alpha,4-dimethylbenzeneacetaldehyde
.alpha.,4-dimethyl-Benzeneacetaldehyde
Benzeneacetaldehyde, .alpha.,4-dimethyl-
[EINECS(EC#)]

202-782-0
[Molecular Formula]

C10H12O
[MDL Number]

MFCD00072170
[MOL File]

99-72-9.mol
[Molecular Weight]

148.2
Chemical PropertiesBack Directory
[Boiling point ]

208.81°C (rough estimate)
[density ]

0.8884 (rough estimate)
[FEMA ]

3078 | 2-(P-TOLYL)PROPIONALDEHYDE
[refractive index ]

1.5003 (estimate)
[Odor]

at 10.00 % in dipropylene glycol. floral green sweet woody herbal powdery
[Odor Type]

green
[JECFA Number]

1471
[LogP]

2.59
[EPA Substance Registry System]

Benzeneacetaldehyde, .alpha.,4-dimethyl- (99-72-9)
Hazard InformationBack Directory
[Chemical Properties]

2-(p-Tolyl)-propionaldehyde has an intense, sweet, refreshing odor, similar to peppermint.
[Occurrence]

Has apparently not been reported to occur in nature
[Uses]

2-(4-Methylphenyl)propanal is used as a reactant in the asymmetric synthesis of α-branched homoallylic aldehydes.
[Preparation]

By reaction of α-terpinene and chromyl chloride in carbon disulfide and subsequent hydrolysis of the resulting cymenechromyl chloride addition product; also by heating p-tolyl glycidic acid and water.
[Taste threshold values]

Taste characteristics at 10 ppm: green, woody, waxy and musty.
Safety DataBack Directory
[Toxicity]

The acute oral LD50 value in rats was reported as 3.50 g/kg (2.40-4.60 g/kg) (Moreno, 1973). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Moreno, 1973).
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