29684-56-8
中文名称
伯吉斯试剂
英文名称
Burgess reagent
CAS
29684-56-8
分子式
C8H18N2O4S
MDL 编号
MFCD00077815
分子量
238.3
MOL 文件
29684-56-8.mol
更新日期
2024/08/27 10:27:36
![29684-56-8 结构式](/CAS/GIF/29684-56-8.gif)
基本信息
中文别名
(甲氧基羰酰磺胺酰)三乙基氢氧化铵伯吉斯试剂
N-(三乙基铵磺酰)氨基甲酸甲酯
英文别名
BURGESS REAGENT(METHOXYCARBONYLSULFAMOYL)TRIETHYLAMMONIUM HYDROXIDE
(METHOXYCARBONYLSULFAMOYL)TRIETHYLAMMONIUM HYDROXIDE, INNER SALT
METHYL N-(TRIETHYLAMMONIOSULFONYL)CARBAMATE
N,N-DIETHYL-N-(((METHOXYCARBONYL)AMINO)SULFONYL)ETHANAMINIUM, INNER SALT
METHOXYCARBONYLSULFAMOYL-TRIETHYLAMMON. HYDROXIDE,INNER SALT
MethylN-(Triethylammoniumsulphonyl)Carbamate
BURGESS REAGENT METHYL N-(TRIETHYLAMMONIUMSULPHONYL)CARBAMATE
((methoxycarbonyl)sulfamoyl)triethylammonium
(METHOXYCARBONYLSULFAMOYL) TRIETHYLAMMONIUM HYDROX
(METHOXYCARBONYLSULFAMOYL)TRIETHYLAMMONIUM HYDROXIDE, INNER SALT (BURGESS REAGENT)
Burgess
(methoxycarbonylsulfamoyl)triethylammonium hydroxide, salt
Burgess reagent, Methyl N-(triethylammoniosulfonyl)carbamate
(Methoxycarbonylsulfamoyl)triethylammonium hydroxide, 97%, inner salt
(Methoxycarbonyl)[(triethylaminio)sulfonyl]amineanion
[(Triethylaminio)sulfonyl](methoxycarbonyl)amineanion
Methoxycarbonyl(triethylaminiosulfonyl)amineanion
N-(Triethylaminiosulfonyl)-1-oxo-2-oxa-1-propanamine anion
Triethylaminiosulfonyl(methoxycarbonyl)amineanion
所属类别
催化剂及助剂:催化剂物理化学性质
熔点76-79 °C(lit.)
密度1.3023 (rough estimate)
折射率1.6300 (estimate)
储存条件−20°C
溶解度易溶于有机溶剂。
形态结晶粉末
颜色浅黄色
敏感性湿气敏感
Merck1502
BRN1432131
InChIInChI=1S/C8H18N2O4S/c1-5-10(6-2,7-3)15(12,13)9-8(11)14-4/h5-7H2,1-4H3
InChIKeyYSHOWEKUVWPFNR-UHFFFAOYSA-N
SMILES[N+](CC)(CC)(CC)S(=O)(=O)[N-]C(=O)OC
常见问题列表
简介
伯吉斯试剂(Burgess试剂),即N-(三乙基铵磺酰)氨基甲酸甲酯,是一个氨基甲酸酯类的内盐,用作有机化学中的失水剂。它可溶于大多数有机溶剂中。常用在二级和三级醇发生顺式消除脱水成烯的反应中,反应温和,有选择性。但一级醇反应效果不佳。用途
伯吉斯试剂是一种温和的选择性脱水剂。它用于将具有相邻质子的仲醇和叔醇转化为烯烃。
知名试剂公司产品信息
Acros Organics
(甲氧基羰酰磺胺酰)三乙基氢氧化铵(Methoxycarbonylsulfamoyl)triethylammonium hydroxide, inner salt, 97%(29684-56-8)
Sigma Aldrich
29684-56-8(sigmaaldrich)