exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-ylacetat

Isobornyl acetate Struktur
125-12-2
CAS-Nr.
125-12-2
Bezeichnung:
exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-ylacetat
Englisch Name:
Isobornyl acetate
Synonyma:
Isobornyl;Isomethyl lonone;Pichtosine;2-CAMPHANYL ACETATE;D,L-ISOBORNYL ACETATE;1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl acetate;exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl acetate;Nsc62486;FEMA 2160;Pichtosin
CBNumber:
CB0358907
Summenformel:
C12H20O2
Molgewicht:
196.29
MOL-Datei:
125-12-2.mol

exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-ylacetat Eigenschaften

Schmelzpunkt:
29°C
Siedepunkt:
229-233 °C (lit.)
Dichte
0.983 g/mL at 25 °C (lit.)
Dampfdruck
0.13 hPa (20 °C)
FEMA 
2160 | ISOBORNYL ACETATE
Brechungsindex
n20/D 1.4635(lit.)
Flammpunkt:
190 °F
storage temp. 
Store below +30°C.
Löslichkeit
0.16g/l
Aggregatzustand
Oil
Farbe
Colourless
Wichte
0.98
Geruch (Odor)
at 100.00 %. balsam camphor herbal woody sweet
Geruchsart
balsamic
Wasserlöslichkeit
Not miscible or difficult to mix with water.
JECFA Number
1388
BRN 
3197572
Stabilität:
Stable. Flammable. Incompatible with strong oxidizing agents.
InChIKey
XWIGWPJZNFZLBG-UHFFFAOYSA-N
LogP
3.86
CAS Datenbank
125-12-2(CAS DataBase Reference)
NIST chemische Informationen
Isobornyl acetate(125-12-2)
EPA chemische Informationen
Isobornyl acetate (125-12-2)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi
R-Sätze: 36/37/38-38
S-Sätze: 26-36/37/39-24/25
WGK Germany  1
RTECS-Nr. NP7350000
Selbstentzündungstemperatur 440 °C DIN 51794
TSCA  Yes
HS Code  29153900
Giftige Stoffe Daten 125-12-2(Hazardous Substances Data)
Toxizität LD50 orally in Rabbit: > 10000 mg/kg LD50 dermal Rabbit > 20000 mg/kg
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
Sicherheit
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P302+P352 BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.
P332+P313 Bei Hautreizung: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.

exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-ylacetat Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-Sätze Betriebsanweisung:

S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.

Beschreibung

Isobornyl acetate has a pleasant, camphor-like odor reminiscent of some varieties of pine needles and hemlock, and a fresh, burning taste. May be prepared by treatment of camphene with acetic acid, usually in the presence of a catalyst; also by acetylation of isobomeol; depending on the starting material (d-camphene or ι-camphene), the resulting acetate may exhibit a slight optical activity; the commercial product is considered to be optically inactive.

Chemische Eigenschaften

Isobornyl Acetate has been identified in a number of essential oils. It is a colorless liquid with a pleasant, pine-needle odor. Isobornyl acetate is prepared from camphene and acetic acid in the presence of acidic catalysts (e.g., sulfuric acid) or on a styrene–divinylbenzene acid ion-exchanger.
Isobornyl acetate is used in large amounts for perfuming soaps, bath products, and air fresheners. However, the major use of isobornyl acetate is as an intermediate in the production of camphor.

Occurrence

Reported found in thymus, Parmesan cheese, dill herb, Ocimum basilicum, rosemary and custard apple

Verwenden

Isobornyl acetate is one of the most important chemicals used in the perfumery industry. It is used in toiletries and soaps as a flavoring agent and antiseptics. One of main applications is as an intermediate to produce camphor.

synthetische

By treatment of camphene with acetic acid, usually in the presence of a catalyst; also by acetylation of isoborneol; depending on the starting material (d-camphene or l-camphene), the resulting acetate may exhibit slight optical activity; the commercial product is considered to be optically inactive

exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-ylacetat Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-ylacetat Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 442)Lieferanten
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125-12-2(exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-ylacetat)Verwandte Suche:


  • FEMA 2160
  • EXO-(1R)-1,7,7-TRIMETHYLBICYCLO[2.2.1]HEPT-2-YL ACETATE
  • ISO-BORNEOL ACETATE
  • Isobornylacetate,90%
  • Isobornyl acetat (Duft Stoff)
  • ISOBORNYL ACETATE(SG)
  • ISOBORNYLACETAT REIN
  • 2-CAMPHANYL ACETATE 96%
  • ISOBORNYL ACETATE WITH GC
  • Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, acetate, (1R,2R,4R)-
  • (1S,2β,4β)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol acetate
  • (1S,4β)-2β-Acetoxy-1,7,7-trimethylbicyclo[2.2.1]heptane
  • Acetic acid (1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl ester
  • 1,7,7-Trimethylbicyclo[2.2.1]heptan-2-yl acetate
  • Nsc62486
  • ISOBORNYL ACETATE FOR SYNTHESIS
  • Isobornyl acet
  • ISOBORNYL ACETATE
  • BORNYL ACETATE (ISO)
  • 2-BORNANOL:ACETATE, EXO
  • 1,7,7-trimethyl-,acetate,exo-bicyclo(2.2.1)heptan-2-o
  • 1,7,7-trimethyl-,acetate,exo-bicyclo[2.2.1]heptan-2-o
  • 1,7,7-trimethyl-,acetate,exo-Bicyclo[2.2.1]heptan-2-ol
  • Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, acetate, exo-
  • Bicyclo[2.2.1]heptan-2-ol,1,7,7-trimethyl-,acetate,(1R,2R,4R)-rel-
  • Bicyclo[2.2.1]heptan-2-ol,1,7,7-trimethyl-,acetate,exo-
  • exo-Bornyl acetate
  • Pichtosin
  • Bicyclo[2.2.1]heptan-2-ol, 1,7,7-trimethyl-, 2-acetate, (1R,2R,4R)-rel-
  • IsobornylAcetate>
  • Isobornyl acetate USP/EP/BP
  • 4-HydroxypyridineIsobornyl acetate
  • Isobornyl acetate,125-12-2
  • Pichtosine
  • D,L-ISOBORNYL ACETATE
  • exo-1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl acetate
  • Isomethyl lonone
  • Isobornyl
  • 2-CAMPHANYL ACETATE
  • 1,7,7-Trimethylbicyclo[2.2.1]hept-2-yl acetate
  • Isobornyl acetate IBA
  • 125-12-2
  • 0125-12-02
  • 125-12-20
  • Cd2H20O2
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