(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%

(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Struktur
256390-47-3
CAS-Nr.
256390-47-3
Englisch Name:
(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
Synonyma:
SL-A104-1;(R)-3,4,5-MeO-MeOBIPHEP;-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine;(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine;(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine];(R)-2,2'-Bis[bis(3,4,5-trimethoxyphenyl)phosphino]-6,6'- dimethoxy-1,1'-biphenyl;(R)-(+)-2,2'-Bis[di-(3,4,5-trimethoxyphenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl;(R)-(+)-2,2''-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6''-dimethoxy-1,1''-biphenyl;(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(R)-(+)-2,2''-BIS[DI(3,4,5-TRIMETHOXYPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
CBNumber:
CB11180979
Summenformel:
C50H56O14P2
Molgewicht:
942.92
MOL-Datei:
256390-47-3.mol

(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Eigenschaften

Siedepunkt:
883.4±65.0 °C(Predicted)
Aggregatzustand
Powder
Farbe
off-white
Sensitive 
air sensitive, store cold
CAS Datenbank
256390-47-3

Sicherheit

WGK Germany  3
HS Code  29319090

(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemische Eigenschaften,Einsatz,Produktion Methoden

Chemische Eigenschaften

Light yellow powder

Verwenden

Atropisomeric MeOBIPHEP ligands

Reaktionen

In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
1. Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.
2. Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
3. Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
4. Conjugate addition using 2-heteroaryl titanates and zinc reagents.
Reactions of 256390-47-3

Allgemeine Beschreibung

sold in collaboration with Solvias AG

(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


(R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97% Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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256390-47-3()Verwandte Suche:


  • (R)-(+)-2,2'-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%
  • (R)-(+)-2,2''-BIS[DI(3,4,5-TRIMETHOXYPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
  • (R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine]
  • (R)-3,4,5-MeO-MeOBIPHEP, SL-A104-1, (R)-2,2μ-Bis[bis(3,4,5-trimethoxyphenyl)phosphino]-6,6μ-dimethoxy-1,1μ-biphenyl
  • (R)-3,4,5-MeO-MeOBIPHEP
  • SL-A104-1
  • (R)-(+)-2,2'-Bis[di-(3,4,5-trimethoxyphenyl)-phosphino]-6,6'-dimethoxy-1,1'-biphenyl
  • (R)-(6,6'-DiMethoxybiphenyl-2,2'-diyl)bis[bis(3,4,5-triMethoxyphenyl)phosphine] >=97%, optical purity ee: >=99%
  • (R)-2,2'-Bis[bis(3,4,5-trimethoxyphenyl)phosphino]-6,6'- dimethoxy-1,1'-biphenyl
  • Phosphine, 1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(3,4,5-trimethoxyphenyl)-
  • 1,1'-[(1R)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(3,4,5-trimethoxyphenyl)phosphine]
  • -diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine
  • (R)-(+)-2,2''-Bis[di(3,4,5-trimethoxyphenyl)phosphino]-6,6''-dimethoxy-1,1''-biphenyl
  • (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,4,5-trimethoxyphenyl)phosphine
  • 256390-47-3
  • Chiral Phosphine
  • MeOBIPHEP Series
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