Thalliumbromid Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R26/28:Sehr giftig beim Einatmen und Verschlucken.
R33:Gefahr kumulativer Wirkungen.
R51/53:Giftig für Wasserorganismen, kann in Gewässern längerfristig schädliche Wirkungen haben.
S-Sätze Betriebsanweisung:
S13:Von Nahrungsmitteln, Getränken und Futtermitteln fernhalten.
S28:Bei Berührung mit der Haut sofort abwaschen mit viel . . . (vom Hersteller anzugeben).
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Beschreibung
Thallium bromide is a yellow-white solid and hygroscopic. It is similar to silver bromide.
It gets darker when light shines on it. It is very toxic, like all thallium compounds. It does
not dissolve in water. Thallium bromide is used in gamma ray and x-ray detectors and
also in semiconductors. Prolonged period of exposure to thallium compounds has been
reported to cause adverse health effects such as joint pain, severe pain in legs, loss of appetite,
fatigue, and albuminuria.
Chemische Eigenschaften
THALLIUM(I) BROMIDE is yellow crystalline powder
Verwenden
THALLIUM(I) BROMIDE is used for mixed crystals with thallium iodide for infrared radiation transmitters used in military detection devices.
Vorbereitung Methode
Single crystals are synthesized by the Stockbarger method after putting high grade sources into a well dried alumina crucible. The crystal is easy to process according to its nonfragile character.
Sicherheitsprofil
Poison by ingestion and subcutaneous routes. Reacts violently with Na, K. When heated to decomposition it emits very toxic fumes of Brand T1. See also BROMIDES and THALLIUM COMPOUNDS.
läuterung methode
Thallous bromide (20g) is purified by refluxing for 2-3hours with water (200mL) containing 3mL of 47% HBr. It is then washed until acid-free, heated to 300o for 2-3hours and stored in brown bottles. It solubility in H2O (w/w) is 0.034% at 0o, 0.048% at 20o, and 0.204% at 100o. [D.nges in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 870 1963]. POISONOUS.
Thalliumbromid Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
