(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
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- CAS-Nr.
- 112022-81-8
- Englisch Name:
- (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
- Synonyma:
- (S)-2-METHYL-CBS-OXAZABOROLIDINE;(S)-1-METHYL-3,3-DIPHENYLHEXAHYDROPYRROLO[1,2-C][1,3,2]OXAZABOROLE;(S)-ME CBS;(S)-Me-CBS Catalyst;(S)-2-METHYL-CBS-OXAZABOROL;(S)-(-)-2-METHYL-CBS-OXAZABOROLIDINE;(s)-(-)-2-methyl-cbs-oxazaborolidine solution;(S)-5,5-DIPHENYL-2-METHYL-3,4-PROPANO-1,3,2-OXAZABOROLIDINE;(S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole, 0.9-1.1M in toluene [(S)-Methyloxazaborolidine;(s)-methyl
- CBNumber:
- CB3106062
- Summenformel:
- C18H20BNO
- Molgewicht:
- 277.17
- MOL-Datei:
- 112022-81-8.mol
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(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Eigenschaften
- Schmelzpunkt:
- 115-117°C
- Siedepunkt:
- 111 °C
- Dichte
- 0.93 g/mL at 20 °C(lit.)
- Brechungsindex
- -68 ° (C=1, MeOH)
- Flammpunkt:
- 40 °F
- storage temp.
- room temp
- pka
- 1.02±0.40(Predicted)
- Aggregatzustand
- Liquid
- Farbe
- Colorless to amber
- Wasserlöslichkeit
- Hydrolyzes in water.
- Sensitive
- Air & Moisture Sensitive
- BRN
- 8492123
- Expositionsgrenzwerte
- ACGIH: TWA 20 ppm
OSHA: Ceiling 300 ppm; TWA 200 ppm
NIOSH: IDLH 500 ppm; TWA 100 ppm(375 mg/m3); STEL 150 ppm(560 mg/m3)
- InChIKey
- VMKAFJQFKBASMU-KRWDZBQOSA-N
- CAS Datenbank
- 112022-81-8(CAS DataBase Reference)
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
R67:Dämpfe können Schläfrigkeit und Benommenheit verursachen.
R65:Gesundheitsschädlich: kann beim Verschlucken Lungenschäden verursachen.
R63:Kann das Kind im Mutterleib möglicherweise schädigen.
R48/20:Gesundheitsschädlich: Gefahr ernster Gesundheitsschäden bei längerer Exposition durch Einatmen.
R11:Leichtentzündlich.
R19:Kann explosionsfähige Peroxide bilden.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S62:Bei Verschlucken kein Erbrechen herbeiführen. Sofort ärztlichen Rat einholen und Verpackung oder dieses Etikett vorzeigen.
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S33:Maßnahmen gegen elektrostatische Aufladungen treffen.
S29:Nicht in die Kanalisation gelangen lassen.
S16:Von Zündquellen fernhalten - Nicht rauchen.
Chemische Eigenschaften
Colorless to yellow liquid
Verwenden
suzuki reaction
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 274)Lieferanten
112022-81-8()Verwandte Suche:
- (S)-1-METHYL-3,3-DIPHENYL-TETRAHYDRO-PYRROLO[1,2C][1,3,2]OXAZABOROLE
- α,α-diphenyl-l-prolinol methylboronic acid cycl-amide-ester
- (S)-(+)-Methyl-CBS-oxazaborolidine
- (S)-5,5-DIPHENYL-2-METHYL-3,4-PROPANO-1,3,2-OXAZABOROLIDINE 98+%
- (S)-METHYL-CBS-OXAZABOROLIDINE,1M SOLN.IN TOLUENE
- (S)-Methyl oxazaborolidine, in toluene, 1M solution
- (S)-3,3-DIPHENYL-1-METHYLTETRAHYDRO-3H-P YRROLO-OXAZABOROLE
- (S)-2-METHYL-CBS-OXAZABOROLIDINE, 1M SOL UTION IN TOLUENE
- (S)-2-METHYL-CBS-OXAZABOROLIDINE, 1M IN&
- (S)-Methyloxazaborolidine,1-1.5Mintoluene[(S)-MeCBS]CoreyCatalyst
- (s)-2-methyl-cbs-oxazaborolidine, 1m soln. in toluene
- (S)-1-Methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2c][1,3,2]oxazaborole, (S)-3,3-Diphenyl-1-methyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole, (S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole, α,α-Diphenyl-L-prolinol methylboronic acid cycl-amide ester
- (S)-Tetrahydro-1-methyl-3,3-triphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole, 1-1.5M in toluene [(S)-Methyl oxazaborolidine] Corey Catalyst
- (3aS)-1-Methyl-3,3-diphenyl-3aβ,4,5,6-tetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole
- (3aS)-1-Methyl-3,3-diphenyl-tetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole
- (3aS)-3,3aβ,4,5-Tetrahydro-1-methyl-3,3-diphenyl-6H-1-bora-2-oxa-6a-azapentalene
- (3aS)-3,3-Diphenyl-1-methyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole
- (3aS)-3aβ,4,5,6-Tetrahydro-1-methyl-3,3-diphenyl-3H-pyrrolo[1,2-c][1,3,2]oxazaborole
- (S)-()-2-Methyl-CBS-oxazaborolidine solution
1 M in THF
- (S)-2-Methyl-CBS-oxazaborolidine
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
- (S)-(-)-2-Methyl-CBS-oxazaborolidine >=95.0%
- (S)-(-)-2-Methyl-CBS-oxazaborolindine
- (S)-2-methyl-CBS-oxazaborolidine(1mol/L)
- (S)-2-methyl-CBS-oxazaborolidine(solid)
- (3aβ)-1-Methyl-3,3-diphenyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole
- 1-(S)-methyl CBS oxazaborolidine
- (S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole,0.9-1.1Mintoluene[(S)-Methyloxazaborolidine]CoreyCatalyst
- (S)-(-)-2-METHYL-CBS-[1,3,2]OXAZABOROLIDINE IN,TOLUENE
- (S)-2-Methyl-CBS-oxazaborolidine ,98%
- ALPHA,ALPHA-DIPHENYL-L-PROLINOL METHYLBORONIC ACID CYCL-AMIDE ESTER
- (S)-(-)-2-Methyl-CBS-oxazaborolidine, 1M solution in toluene, AcroSeal
- 1-Methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole
- (S)-2-METHYL-CBS-OXAZABOROLIDINE MONOHYDRATE
- (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
- (S)-3,3-DIPHENYL-1-METHYLTETRAHYDRO-1H,3H-PYRROLO[1,2-C][1,3,2]OXAZABOROLE
- (S)-3,3-DIPHENYL-1-METHYLTETRAHYDRO-3H-PYRROLO-[1,2-C][1,3,2]OXAZABOROLE
- (S)-METHYL OXAZABOROLIDINE
- (S)-TETRAHYDRO-1-METHYL-3,3-DIPHENYL-1H,3H PYRROLO[1,2-C][1,3,2] OXAZABOROLE
- (s)-methyl
- (s)-methyloxazaborolidine,(s)-mecbs,in
- (s)-methyloxazaborolidine,(s)-mecbs,intoluene
- (S)-Methyloxazaborolidine,1-1.5Mintoluene[(S)-MeCBS]
- (S)-Tetrahydro-1-Methyl-3
- 0.9-1.1Mintoluene[(S)-Methyloxazaborolidine]CoreyCatalyst
- (S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrole[1,2-c][1,3,2]oxazaborole, 0.9-1.1M in toluene [(S)-Methyloxazaborolidine] Corey Catalyst
- (S)-3,3-Diphenyl-1-methyltetrahydro-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole
(S)-Me-CBS Catalyst
- (S)-Methyl oxazaborolidine in toluene 1M
- (S)-Tetrahydro-1-Methyl-3,3-Triphenyl-1H,3H-Pyrrolo[1,2-c][1,3,2]Oxazaborole
- (S)-Methyloxazaborolidine 1M in toluene
- 1H,3H-Pyrrolo[1,2-c][1,3,2]oxazaborole,tetrahydro-1-Methyl-3,3-diphenyl-, (3aS)-
- (S)-(-)-2-Methyl-CBS-oxazaborolidine, 1.0 M solution in toluene
- (S)-(-)-2-Methyl-CBS-oxazaborolidine, 1.0 M solution in THF
- (S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole, 0.9-1.1M in toluene [(S)-Methyloxazaborolidine] (S)-CBS Catalyst
- (3aS)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole
- (S)-(-)-2-Methyl-CBS-oxazaborolidine, 1.0 M solution in toluene, J&KSeal
- (S)-(-)-2-MethyL
- (S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine - 1.0M in toluene
- (S) - 2-methyl-cbs-oxazolidine