13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine

CAS-Nr.

Englisch Name:: 13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine

Synonyma:: Methoxychelidonine;13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine

CBNumber:: CB32181081

Summenformel:: C20H15NO6

Molgewicht:: 365.3362

MOL-Datei:: Mol file

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Eigenschaften Sicherheit Verwendungswort

13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine Eigenschaften

Schmelzpunkt:: 221°C

Sicherheit

13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

This alkaloid has been obtained by Gadamer and Winterfeld during a systematic examination of the residues remaining after the isolation of chelidonine from Chelidonum majus L. The base forms colourless prisms on crystallization from EtOH and has [α]_D + 115.8°. It furnishes a crystalline hydrochloride and an aurichloride, m.p. 237-8°C. The O-acetate is amorphous, m.p. 147°C; [α]_D + 55.5°. One methoxyl group, two methylenedioxy groups, one hydroxyl group and a methylimino group are present in the molecule.

Einzelnachweise

Gadamer, Winterfeld., Arch. Pharm., 257,298 (1919)
Garlamer, Winterfeld., ibid, 258, 148 (1920)
Gadamer, Winterfeld., ibid, 262,249 (1924)
Bruchhausen, Bersch., Ber., 63,2520 (1930)
Bruchhausen, Bersch., ibid, 64,370 (1931)

13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

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