(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON
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- CAS-Nr.
- 36548-60-4
- Englisch Name:
- (R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON
- Synonyma:
- IRON ACETYL CHIRAL;IRON ACETYL COMPLEX (+)-(S)-ENANTIOMER;IRON ACETYL COMPLEX (-)-(R)-ENANTIOMER;(S)-(+)-Acetylcarbonyl(eta-5,2,4-cyclopentadien-1-y;acetylcyclopentadienyl/ iron carbonyl triphenylphosphine;(R)-(-)-ACETYLCYCLOPENTADIENYLIRONCARBONYLTRIPHENYLPHOSPHINE COMPLEX;(S)-(+)-ACETYLCYCLOPENTADIENYLIRONCARBONYLTRIPHENYLPHOSPHINE COMPLEX;S(+)-CYCLOPENTADIENYL IRON ACETYL CARBONYL TRIPHENYLPHOSPHINE COMPLEX;(S)-(+)-ACETYLCYCLO- PENTANEDIENYL IRON CARBONYL TRIPHENYLPHOSPHINE COMPLEX;(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON
- CBNumber:
- CB3274947
- Summenformel:
- C26H23FeO2P5*
- Molgewicht:
- 454.28
- MOL-Datei:
- 36548-60-4.mol
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(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON Eigenschaften
- Schmelzpunkt:
- 151-156 °C
- storage temp.
- 2-8°C
- Löslichkeit
- soluble in THF, CHCl3, CH2Cl2, acetone
Sicherheit
(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON Chemische Eigenschaften,Einsatz,Produktion Methoden
S-Sätze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Verwenden
(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON is used as chiral acetate enolate equivalent which can be deprotonated with BuLi or LDA in THF at -78 °C; the enolate reacts stereoselectively with a variety of achiral, prochiral, and chiral electrophiles to generate functionalized organoiron compounds from which the iron can subsequently be removed.
(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
(R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 10)Lieferanten
36548-60-4()Verwandte Suche:
- IRON ACETYL COMPLEX (-)-(R)-ENANTIOMER
- IRON ACETYL COMPLEX (+)-(S)-ENANTIOMER
- (R)-(-)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON
- (R)-(-)-ACETYLCARBONYL((ETA)5-2,4-CYCLOPENTADIENE-1-YL)(TRIPHENYLPHOSPHINE)IRON
- (R)-(-)-ACETYLCYCLOPENTADIENYLIRONCARBONYLTRIPHENYLPHOSPHINE COMPLEX
- S(+)-CYCLOPENTADIENYL IRON ACETYL CARBONYL TRIPHENYLPHOSPHINE COMPLEX
- (S)-(+)-ACETYLCYCLOPENTADIENYLIRONCARBONYLTRIPHENYLPHOSPHINE COMPLEX
- (S)-(+)-ACETYLCYCLO- PENTANEDIENYL IRON CARBONYL TRIPHENYLPHOSPHINE COMPLEX
- (S)-(+)-ACETYLARBONYL((ETA)5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON
- (S)-(+)-ACETYLCARBONYL(ETA5-2,4-CYCLOPENTADIEN-1-YL)(TRIPHENYLPHOSPHINE)IRON
- (S)-(+)-Acetylcarbonyl(eta-5,2,4-cyclopentadien-1-y
- (S)-(+)-ACETYL-CYCLOPENTADIENYL-IRON CARBONYL TRIPHENYLPHOSPHINE COMPLEX PURUM 97%
- acetylcyclopentadienyl/ iron carbonyl triphenylphosphine
- Iron acetyl chiral, (S)-(+)-Cyclopentadienyl iron acetyl carbonyl triphenylphosphine complex
- IRON ACETYL CHIRAL
- 36548-60-4
- C26H23FeO2P
- Asymmetric Synthesis
- Chiral Catalysts, Ligands, and Reagents
- Carbonyl/Imine Addition