BrettPhos Pd G3
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- CAS-Nr.
- 1470372-59-8
- Englisch Name:
- BrettPhos Pd G3
- Synonyma:
- BuBrettPhos Pd G3;BrettPhos-G3-Pd;BrettPhos Pd G3;BrettPhos Pd G3 95%;BrettPhos Palladacycle Gen.3;BrettPhosPdG3 BrettPhos Pd G3;BrettPhos Pd G3 ISO 9001：2015 REACH;BrettPhosPalladacycle3rdGeneration,98%;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4'...;Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladiu
- CBNumber:
- CB62686118
- Summenformel:
- C48H66NO5PPdS
- Molgewicht:
- 906.51
- MOL-Datei:
- 1470372-59-8.mol
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BrettPhos Pd G3 Eigenschaften
- Schmelzpunkt:
- 150-193°C (decomposition)
- storage temp.
- under inert gas (nitrogen or Argon) at 2–8 °C
- Aggregatzustand
- Powder
- Farbe
- yellow to beige
- InChIKey
- ASZHREKEHVNFFW-UHFFFAOYSA-N
- SMILES
- P(C1CCCCC1)(C1CCCCC1)(C1C(=CC=C(OC)C=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)OC)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C
BrettPhos Pd G3 Chemische Eigenschaften,Einsatz,Produktion Methoden
Verwenden
BrettPhos Pd G3 may be used for the C-N coupling reaction between monosubstituted ureas and 1,2 dihaloaromatic system to form benzimidazolones.
It may be used in the synthesis of following compounds:
- [Pd(cinnamyl)(BrettPhos)]OTf by reacting with [(cinnamyl)PdCl]2 and AgOTf.
- [Pd(crotyl)(BrettPhos)]OTf by reacting with [(crotyl)PdCl]2 and AgOTf.
- [Pd(allyl)(BrettPhos)]OTf by reacting with [(allyl)PdCl]2 and AgOTf.
- Pd(allyl)(BrettPhos)Cl by reacting with [(allyl)PdCl]2.
Allgemeine Beschreibung
BrettPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. BrettPhos Pd G3 is an excellent reagent for Buchwald-Hartwig cross-coupling reaction. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.
BrettPhos Pd G3 Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
BrettPhos Pd G3 Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 141)Lieferanten
- Methanesulfonato2-Dicyclohexylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- BrettPhos Pd G3 95%
- [2'-(Amino)[1,1'-biphenyl]-2-yl][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine](methanesulfonato)palladium
- Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladiu
- [2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)palladium
- Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98% [BrettPhos Palladacycle]
- Methanesulfonato(2-dicyclohexylphosphino-3,6-diMethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II), Min. 98%
- BrettPhos Pd G3
- Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′- triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′ -biphenyl)]palladium(II) methanesulfonate
- [(2-Di-cyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-triisopropyl-1,1’- biphenyl)-2-(2’-amino-1,1’-biphenyl)]palladium(II) methanesulfonate methanesulfonate
- Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98% [BrettPhos Palladacycle Gen. 3]
- BrettPhos Palladacycle Gen.3
- Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / BrettPhos Pd G3
- Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][dicyclohexyl[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine-κP](methanesulfonato-κO)-
- BrettPhosPalladacycle3rdGeneration,98%
- BrettPhos Pd G3 ISO 9001：2015 REACH
- 2-(2-aminophenyl)phenyl]palladio methanesulfonate, dicyclohexyl({3,6-dimethoxy-2-[2,4,6-tris(propan-2-yl)phenyl]phenyl})phosphane
- Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4'...
- BrettPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- BuBrettPhos Pd G3
- BrettPhos-G3-Pd
- BrettPhosPdG3 BrettPhos Pd G3
- (2-Di-cyclohexylphosphino-3,6-dimethoxy-2′,4′,6′- triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′ -biphenyl)]palladium(II) methanesulfonate[BrettPhos Pd G3]
- Methanesulfonato(2-dicyclohexylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
- 1470372-59-8
- C48H66NO5PPdS
- Buchwald Ligands&Precatalysts
- Buchwald Precatalysts Series
- Pd
