4-Hydroxybenzolsulfonsure
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- CAS-Nr.
- 98-67-9
- Bezeichnung:
- 4-Hydroxybenzolsulfonsure
- Englisch Name:
- 4-Hydroxybenzenesulfonic acid
- Synonyma:
- 4-Phenolsulfonic acid;P-PHENOLSULFONIC ACID;P-HYDROXYBENZENESULFONIC ACID;p-PhenoL;ARADUR 5003-1 BD;PHENOL-4-SULFONIC ACID;4-Hydroxyphenylsulfonic acid;C12849;p-Sulfophenol;SULFOCARBOLIC ACID
- CBNumber:
- CB6442408
- Summenformel:
- C6H6O4S
- Molgewicht:
- 174.17
- MOL-Datei:
- 98-67-9.mol
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4-Hydroxybenzolsulfonsure Eigenschaften
- Schmelzpunkt:
- 52 °C
- Siedepunkt:
- 275.14°C (rough estimate)
- Dichte
- 1.337 g/mL at 25 °C
- Dampfdruck
- 69.8Pa at 20℃
- Brechungsindex
- n20/D 1.489
- Löslichkeit
- Water (Slightly)
- Aggregatzustand
- Liquid
- pka
- 9.11(at 25℃)
- Wichte
- 1.337
- Farbe
- White to Light yellow to Light red
- Wasserlöslichkeit
- Soluble in water.
- Merck
- 14,7246
- BRN
- 1869034
- Stabilität:
- Stable. Combustible. Incompatible with strong oxidizing agents.
- InChIKey
- FEPBITJSIHRMRT-UHFFFAOYSA-N
- LogP
- 0.41 at 25℃
- CAS Datenbank
- 98-67-9(CAS DataBase Reference)
- NIST chemische Informationen
- Benzenesulfonic acid, 4-hydroxy-(98-67-9)
- EPA chemische Informationen
- p-Phenolsulfonic acid (98-67-9)
Sicherheit
- Risiko- und Sicherheitserklärung
- Gefahreninformationscode (GHS)
Bildanzeige (GHS) |
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Alarmwort |
Achtung |
Gefahrenhinweise |
Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
H290 |
Kann gegenüber Metallen korrosiv sein. |
Korrosiv gegenüber Metallen |
Kategorie 1 |
Warnung |
src="/GHS05.jpg" width="20" height="20" /> |
P234, P390, P404 |
H314 |
Verursacht schwere Verätzungen der Haut und schwere Augenschäden. |
Ätzwirkung auf die Haut |
Kategorie 1B |
Achtung |
src="/GHS05.jpg" width="20" height="20" /> |
P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501 |
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Sicherheit |
P280 |
Schutzhandschuhe/Schutzkleidung/Augenschutz tragen. |
P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen. |
P310 |
Sofort GIFTINFORMATIONSZENTRUM/Arzt/ anrufen. |
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4-Hydroxybenzolsulfonsure Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R34:Verursacht Verätzungen.
S-Sätze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36/37/39:Bei der Arbeit geeignete Schutzkleidung,Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn möglich, dieses Etikett vorzeigen).
Beschreibung
4-hydroxybenzenesulfonic acid is an arenesulfonic acid that is phenol substituted by a sulfo group at C-4. It is functionally related to a phenol. Results obtained in a comparative study using the disulfide-bridge containing peptide deaminoarginine-vasopressin and several commonly used matrices indicate that the reduction-inhibiting efficiency of 4-hydroxy benzene sulfonic acid is comparable to that of 3-nitrobenzyl alcohol while reduction is found to be important in matrices such as thioglycerol and glycerol. Experiments conducted on peptides such as met-enkephalin and bradykinin, nucleosides and other polar compounds reveal that 4-hydroxybenzenesulfonic acid is a good solvent and has physical properties similar to glycerol. This new matrix material is a radical scavenger, is surface active, allows persistent secondary-ion beams, and produces a low background signal[1].
Chemische Eigenschaften
yellowish oily liquid
Verwenden
4-Hydroxybenzenesulfonic Acid is used as a redox-mediator in the laccase-catalyzed degradation of indigo, a textile dye. Also used in oilfield chemicals, metal working, and as a polymerization catalyst.
Vorbereitung Methode
The synthesis of 4-Hydroxybenzenesulfonic acid is as follows:Phenol (25 kg) and 96% sulfuricacid(28 kg) are heated to 50 ℃; then1.25 kg additional sulfuric acid is added and the reaction mixture is heated at 110 ℃ for 5 – 6 h. Reaction water, together with about 5% of the phenol, is distilled off during this period. Yield 95%.
Definition
ChEBI: An arenesulfonic acid that is phenol substituted by a sulfo group at C-4.
4-Hydroxybenzolsulfonsure Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
4-Hydroxybenzolsulfonsure Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 410)Lieferanten
98-67-9(4-Hydroxybenzolsulfonsure)Verwandte Suche:
- 4-hydroxy-benzenesulfonicaci
- 4-hydroxyphenylsulfonicacid
- 4-phenolsulfonicacid
- Benzenesulfonic acid, p-hydroxy-
- Benzenesulfonicacid,4-hydroxy-
- Phenol-4-sulfonicacidsolutio
- phenol-4-sulfonicacidsolution
- p-hydroxy-benzenesulfonicaci
- p-Sulfophenol
- p-Phenolsulfonic acid monohydrate
- SULFOCARBOLIC ACID
- HYDROXYBENZENE-4-SULFONIC ACID
- 4-HYDROXYBENZENESULFONIC ACID
- 4-hydroxybenzenesulphonic acid
- 4-HYDROXYBENZENESULFONIC ACID, 65 WT. % SOLUTION IN WATER
- PHENOL-4-SULFONIC ACID SOLUTION, ~65% IN WATER
- 1-Phenol-4-sulfonic acid
- 4-PHENOLSULPHONICACID
- PARA-PHENOLSULPHONICACID
- PARA-HYDROXYBENZENESULFONATE
- 4-hydroxybenzenesulfonic acid solution
- Phenolsulphonic acid
- C12849
- 4-Hydroxybenzenesulf
- p-Phenolsulfonic Acid 
- 4-Hydroxybenzenesulfonic acid, 95%, 65 wt.% solution in water
- p-Hydroxybenzenesulfonic acid solution
- 4-Hydroxybenzenesulfonic acid solution 65 wt. % in H2O
- Phenol-4-sulfonic acid solution (33%)
- p-hydoroxybenzenesulfonic acid
- 4-HydroxybenzenesulfonicAcidHydrate>
- 4-Hydroxybenzenesulfonic acido
- Calcium Dobesilate Impurity 12
- P-PHENYLSULFONIC ACID
- 4-Hydroxybenzenesulfonic acid ISO 9001:2015 REACH
- 4-Hydroxyphenylsulfonic acid
- 4-Phenolsulfonic acid
- PHENOL-4-SULFONIC ACID
- P-HYDROXYBENZENESULFONIC ACID
- P-PHENOLSULFONIC ACID
- ARADUR 5003-1 BD
- p-PhenoL
- Phenol Sulphonic Acid (65%)
- Etamsylate Impurity B
- 98-67-9
- C6H6O4SxH2O
- C6H8N2O3S12H2O
- OHC6H4SO3H
- Building Blocks
- Organic Building Blocks
- Sulfonic/Sulfinic Acids
- Sulfur Compounds
- Intermediates of Dyes and Pigments
- Organic acids