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DavePhos-Pd-G3

DavePhos-Pd-G3 Struktur
1445085-87-9
CAS-Nr.
1445085-87-9
Englisch Name:
DavePhos-Pd-G3
Synonyma:
DavePhos-Pd-G3 95%;DavePhos-Pd-G3 AldrichCPR;Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethyla...;DavePhos Pd G3 / Methanesulfonato 2-dicyclohexylphosphino-2-(N,N-;METHANESULFONATO 2-DICYCLOHEXYLPHOSPHINO-2-(N,N-DIMETHYLAMINO)BIPHENYL(2+;[2-(dicyclohexylphosphino)-2-(N,N-dimethylamino)-1,1-biphenyl]-2-(2-amino-1,1-biphenyl)]palladium(II) methanesulfonate;Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II);2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl]-2-(2'-amino-1,1'-biphenyl)]palladium(II) methanesulfonate;Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II);DavePhos Pd G3 / Methanesulfonato 2-dicyclohexylphosphino-2-(N,N-dimethylamino)biphenyl(2′-amino-1,1′-biphenyl-2-yl) palladium(II)
CBNumber:
CB72709676
Summenformel:
C39H49N2O3PPdS
Molgewicht:
763.29
MOL-Datei:
1445085-87-9.mol
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DavePhos-Pd-G3 Eigenschaften

Schmelzpunkt:
183-200°C (decomp)
Aggregatzustand
Powder
Farbe
white
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H351 Kann vermutlich Krebs verursachen. Karzinogenität Kategorie 2 Warnung P201, P202, P281, P308+P313, P405,P501
Sicherheit
P201 Vor Gebrauch besondere Anweisungen einholen.
P202 Vor Gebrauch alle Sicherheitshinweise lesen und verstehen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P308+P313 BEI Exposition oder falls betroffen: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.
P405 Unter Verschluss aufbewahren.
P501 Inhalt/Behälter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen.

DavePhos-Pd-G3 Chemische Eigenschaften,Einsatz,Produktion Methoden

Verwenden

Pd precatalyst for cross-coupling

Allgemeine Beschreibung

DavePhos-Pd-G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solutions and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.

DavePhos-Pd-G3 Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

DavePhos-Pd-G3 Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 78)Lieferanten
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  • Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-diMethylaMino)-1,1'-biphenyl](2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) CH2Cl2 adduct, Min. 98% [DavePhos Palladacycle]
  • DavePhos-Pd-G3 AldrichCPR
  • DavePhos-Pd-G3 95%
  • Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) CH2Cl2 adduct
  • METHANESULFONATO[2-(DICYCLOHEXYLPHOSPHINO)-2'-(N,N-DIMETHYLAMINO)-1,1'-BIPHENYL](2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II)CH2CL2ADDUCT,MIN.98%[DAVEPHOSPALLADACYCLEGEN.3]
  • [2-(dicyclohexylphosphino)-2-(N,N-dimethylamino)-1,1-biphenyl]-2-(2-amino-1,1-biphenyl)]palladium(II) methanesulfonate
  • Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II) CH2Cl2 adduct,[DavePhos Palladacycle Gen. 3]
  • Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-diMethylaMino)-1,1'-biphenyl](2'-aMino-1,1'-biphenyl-2-yl)palladiuM(II) CH2Cl2 adduct [DavePhos Palladacycle]
  • Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • DavePhos Pd G3 / Methanesulfonato 2-dicyclohexylphosphino-2-(N,N-dimethylamino)biphenyl(2′-amino-1,1′-biphenyl-2-yl) palladium(II)
  • DavePhos Pd G3 / Methanesulfonato 2-dicyclohexylphosphino-2-(N,N-
  • Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethyla...
  • Palladium, [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][2'-(dicyclohexylphosphino-κP)-N,N-dimethyl[1,1'-biphenyl]-2-amine](methanesulfonato-κO)-
  • METHANESULFONATO 2-DICYCLOHEXYLPHOSPHINO-2-(N,N-DIMETHYLAMINO)BIPHENYL(2+
  • Methanesulfonato[2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl](2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • 2-(dicyclohexylphosphino)-2'-(N,N-dimethylamino)-1,1'-biphenyl]-2-(2'-amino-1,1'-biphenyl)]palladium(II) methanesulfonate
  • 1445085-87-9
  • C39H49N2O3PPdS
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Pd
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