2,2':5',2''-TERTHIOPHENE
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- CAS-Nr.
- 1081-34-1
- Englisch Name:
- 2,2':5',2''-TERTHIOPHENE
- Synonyma:
- 3TH;TTh;S1130;2,2':5';2,2':5',2;terthienyl;TERTHIOPHENE;a-Terthienyl;5-BroMo-[2,2';JACS-1081-34-1
- CBNumber:
- CB7713541
- Summenformel:
- C12H8S3
- Molgewicht:
- 248.39
- MOL-Datei:
- 1081-34-1.mol
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2,2':5',2''-TERTHIOPHENE Eigenschaften
- Schmelzpunkt:
- 93-95 °C(lit.)
- Siedepunkt:
- 160 °C (0.1 mmHg)
- Dichte
- 1.4602 (rough estimate)
- Brechungsindex
- 1.6200 (estimate)
- Flammpunkt:
- 160°C/0.1mm
- storage temp.
- Keep in dark place,Sealed in dry,Room Temperature
- Löslichkeit
- Chloroform (Slightly), Methanol (Slightly)
- Aggregatzustand
- Solid
- Farbe
- Light Yellow
- Wasserlöslichkeit
- Insoluble in water.
- Merck
- 14,9174
- BRN
- 178604
- CAS Datenbank
- 1081-34-1(CAS DataBase Reference)
- EPA chemische Informationen
- .alpha.-Terthiophene (1081-34-1)
2,2':5',2''-TERTHIOPHENE Chemische Eigenschaften,Einsatz,Produktion Methoden
R-Sätze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-Sätze Betriebsanweisung:
S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.
Chemische Eigenschaften
YELLOW TO YELLOW-BROWN POWDER
Verwenden
α-Terthienyl was first recognized as a nematicidal
constituent of marigolds, but in the presence of light, it
is also highly toxic to larvae of several insect species,
including mosquitoes. This electron donor thiophenederivative
phototoxin is biosynthesized from polyacetylene
precursors and appears to function as a photosensitizer
catalyzing the formation of reactive oxygen species at the
target site (25).
Allgemeine Beschreibung
2,2′:5′,2′′-Terthiophene (TTh) may be prepared by nickel catalysed coupling reaction of grignard′s reagent derived from 2-bromothiophene and magnesium. It generates singlet oxygen. In nature, it is found in the floral extract of
Tagetes minuta and
Echinops grijisii. It is known to be toxic to mosquitoes. It also exihibits antifungal activity.
Stoffwechselwegen
When 14C-a-terthienyl is administered orally to rats in
a single dose, two metabolites [1,4-di(2'-thienyl)]-1,4-
butadione and 2-2' -bithiophene-5-carboxylic acid are
identified in the urine.
läuterung methode
Possible impurities are bithienyl and polythienyls. Suspend it in H2O and steam distil it to remove bithienyl. The residue is cooled and extracted with CHCl3, dried (MgSO4), filtered, evaporated and the residue chromatographed on Al2O3 using pet ether/3% Me2CO as eluent. The terphenyl zone is then eluted from the Al2O3 with Et2O, the extract is evaporated and the residue is recrystallised from MeOH (40mL per g). The platelets are washed with cold MeOH and dried in air. [UV: Sease & Zechmeister J Am Chem Soc 69 270 1947; Uhlenbroek & Bijloo Recl Trav Chim Pays-Bas 79 1181 1960.] It has also been recrystallised from MeOH, *C6H6, pet ether or AcOH. [UV: Zechmeister & Sease J Am Chem Soc 69 273 1947, Steinkopf et al. Justus Liebigs Ann Chem 546 180 1941.] It is a phototoxic nematocide [Cooper & Nitsche Bioorg Chem 13 36 1985, Chan et al. Phytochem 14 2295 1975]. [Beilstein 19 III/IV 4763, 19/9 V 226.]
2,2':5',2''-TERTHIOPHENE Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
2,2':5',2''-TERTHIOPHENE Anbieter Lieferant Produzent Hersteller Vertrieb Händler.
Global( 324)Lieferanten
- 2,5-BIS(2-THIENYL)THIOPHENE
- 2,5-DI(2-THIENYL)THIOPHENE
- 2,2′:5′,2′′-Terthiophene,α-Terthienyl, 2,5-Di(2-thienyl)thiophene
- 2,2':5',2-TERTHIENYL
- 2,2',5',2''-TERTHIOPHENE
- 2,2':5',2''-Terthiophene 99%
- 2,2':5',2''-Terthiophene (purified by sublimation)
- ALPHA-TERTHIENYL
- 2,5-Di(thien-2-yl)thiophene
- 2,2 :5 ,2 -Terthiophene
- 2,5-Di(2-thienyl)thiophene
alpha-Terthienyl
- 2,2':5',2''-Terthiophene (=α-Terthienyl)
- 5-BroMo-[2,2'
- 2,2':5',2''-TERTHIOPHENE
- TERTHIOPHENE
- alpha-terthiophene
- terthienyl
- alpha-TERTHIENYL (2,2':5',2
- 5',2''Terthiophene
- 2,2':5'
- 2''-TERTHIOPHENE
- 2,2':5',2''-Terthiophene (=alpha-Terthienyl)
- α-Terthienyl, 2,5-Di(2-thienyl)thiophene
- Alpha-terthienyl,99+%
- 2,5-Bis(thiophene-2-yl)thiophene
- a-Terthienyl
- 2,2':5',2''-Terthiophene ,99%
- 2,3-dithiophen-2-ylthiophene
- 3TH
- 2,5-Di(2-thienyl)thiophene alpha-Terth
- TTh
- Alpha-trithiophene
- JACS-1081-34-1
- 2,2':5',2''-Terthiophene, 99%, for synthesis
- α-Terthiophene
- 2,2':5',2''-TERTHIOPHENE ISO 9001：2015 REACH
- S1130
- Sanlian thiophene
- 2,2':5',2''-Terthiophene (7CI, 8CI, 9CI, ACI)
- Osa（2-octen-1-ylsuccinic anhydride, mixture of cis and trans）
- 2,2 ': 5', 2 '' - Trithiophene
- 2,2',2''-Terthiophene
- 2,2':5',2''-Terthiophene
- 2,2',2''-Terthiophene
- 2,2':5',2"-Terthiophene
- 2,2':5',2
- 2,2':5',2'-TERTHIOPHENE
- 2,2,5,2-Terthiophene in isooctane
- 2,2,5,2-Terthiophene in toluene
- 1081-34-1
- 1081-34-4
- 108-34-1
- C12H8S3
- Heterocyclic Building Blocks
- Thiophenes
- Building Blocks
- Reagents for Conducting Polymer Research
- Thiophene Derivatives (for Conduting Polymer Research)
