Magnesium chloride hexahydrate

Magnesium chloride hexahydrate Struktur
7791-18-6
CAS-Nr.
7791-18-6
Englisch Name:
Magnesium chloride hexahydrate
Synonyma:
cmh;NEDMAG-C FLAKES;MEGNESIUM CHLORID;Magnisum Chloride;MAGNESII CHLORIDUM;MagnesiumChlorideAr;MagnesiumChlorideUsp;Magnesium chloride h;Magnesium Chloride BP;MAGNESIUM CHLORIDE XTL
CBNumber:
CB8681652
Summenformel:
Cl2H12MgO6
Molgewicht:
203.3
MOL-Datei:
7791-18-6.mol

Magnesium chloride hexahydrate Eigenschaften

Schmelzpunkt:
117 °C
Dichte
1.569
storage temp. 
2-8°C
Löslichkeit
H2O: 1 M at 20 °C, clear, colorless
Aggregatzustand
Solid
Farbe
White to slightly gray
Wichte
1.569
Geruch (Odor)
Odorless
Säure-Base-Indikators(pH-Indikatoren)
7
PH
4.5-7.0 (50g/l, H2O, 20℃)
Wasserlöslichkeit
2350 g/L (20 ºC)
Sensitive 
Hygroscopic
maximale Wellenlänge (λmax)
λ: 260 nm Amax: 0.030
λ: 280 nm Amax: 0.025
Merck 
14,5662
Stabilität:
Stable. Incompatible with strong oxidizing agents. Protect from moisture.
InChIKey
DHRRIBDTHFBPNG-UHFFFAOYSA-L
LogP
-1.380 (est)
CAS Datenbank
7791-18-6(CAS DataBase Reference)
EPA chemische Informationen
Magnesium chloride, hexahydrate (7791-18-6)
Sicherheit
  • Risiko- und Sicherheitserklärung
  • Gefahreninformationscode (GHS)
Kennzeichnung gefährlicher Xi
R-Sätze: 36/37/38
S-Sätze: 24/25-36-26
WGK Germany  1
RTECS-Nr. OM2975000
3
TSCA  Yes
HS Code  28273100
Toxizität LD50 orally in Rabbit: 8100 mg/kg
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
Sicherheit
P264 Nach Gebrauch gründlich waschen.
P264 Nach Gebrauch gründlich waschen.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.
P302+P352 BEI BERÜHRUNG MIT DER HAUT: Mit viel Wasser/... (Hersteller kann, falls zweckmäßig, ein Reinigungsmittel angeben oder, wenn Wasser eindeutig ungeeignet ist, ein alternatives Mittel empfehlen) waschen.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach Möglichkeit entfernen. Weiter spülen.
P332+P313 Bei Hautreizung: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.
P337+P313 Bei anhaltender Augenreizung: Ärztlichen Rat einholen/ärztliche Hilfe hinzuziehen.

Magnesium chloride hexahydrate Chemische Eigenschaften,Einsatz,Produktion Methoden

R-Sätze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-Sätze Betriebsanweisung:

S24/25:Berührung mit den Augen und der Haut vermeiden.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.

Beschreibung

Magnesium chloride hexahydrate is the hydrated form of magnesium chloride. Magnesium chloride is a mineral supplement used to prevent and treat low amounts of magnesium in the blood and a versatile compound with a number of uses in food preparation, health and personal well-being areas. Magnesium chloride is also used in road care, to synthesize other magnesium compounds, to remove dyes and industrial dye wastes, for the dust control, in the textile production, and as an industrial dye and dye waste remover. Magnesium chloride hexahydrate is used as catalyst for organic synthesis, e.g. 3,4‐Dihydropyrimidin‐2‐(1H)‐one. Magnesium chloride hexahydrate is also a promising heat/thermal storage material.

Chemische Eigenschaften

The pure form of the compound is a colorless monoclinic crystal, but industrial versions typically have a yellowish-brown hue. It has a salty and bitter taste and is deliquescent. It is easily soluble in water and ethanol and will decompose when heated in air, releasing HCl gas around 118°C, which turns into oxychloride. When heated at high temperatures, it decomposes into MgO and HCl.

Verwenden

  • Magnesium chloride hexahydrate has been used in wash buffer for the purification of protein from Saccharomyces cerevisiae.
  • It has been used for the preparation of extracellular (Ringer) solution for juxtacellular recording of single neurons in freely moving rats.
  • It has been used as a supplement to study effect of desiccation on bacterial viability.

Definition

ChEBI: Magnesium dichloride hexahydrate is a hydrate that is the hexahydrate form of magnesium dichloride. It is a hydrate, a magnesium halide and an inorganic chloride. It contains a magnesium dichloride.

Allgemeine Beschreibung

Magnesium chloride hexahydrate is a colorless, crystalline solid. On heating, it loses water of crystallization and affords magnesium oxide. It has been tested as a potential phase change material (PCM) for use in cooking indoors and during the low intensity solar radiation periods. Due to its suitable thermo-physical properties, it can be used as storage media in solar cookers. Its flame retardancy action on 100% woven cotton fabric has been investigated. Its heat capacity has been evaluated.

Pharmazeutische Anwendungen

Magnesium Chloride Hexahydrate is often used in pharmaceuticals due to its high solubility. It is used to manufacture a range of medications that address various health concerns. It is also used as a source of magnesium in nutritional supplements. While it does not treat conditions by itself, it can help those with low magnesium levels improve certain bodily functions. In addition, magnesium chloride supplements have well-documented uses in type 2 diabetes, high blood pressure, osteoporosis, and migraines.

läuterung methode

Crystallise it from hot water (3.3g/mL) by cooling. Dry it in a vacuum at ~175o, or heat the hydrate in a stream of HCl. When the hydrate is heated above 180o it is hydrolysed to the oxychloride (Mg2OCl2). It is deliquescent; store it in a well-stoppered vessel. [Bryce-Smith Inorg Synth VI 9 1960, Ehrlich in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 908 1963.]

Einzelnachweise

[1] Radim Pilar, Ladislav Svoboda, Pavla Honcova and Lucie Oravova, Study of magnesium chloride hexahydrate as heat storage material, Thermochimica Acta, 2012, vol. 546, 81-86 DOI:10.1016/J.TCA.2012.07.021
[2] Guo-Lin Zhang and Xiao-Hua Cai, Magnesium Chloride Hexahydrate Catalyzed One‐Pot Synthesis of 3,4‐Dihydropyrimidin‐2‐(1H)ones Under Solvent‐Free Conditions, Synthetic Communications, 2006, 829-833 DOI:10.1081/SCC-200050956
[3] BH Tan, TT Teng and AKM Omar, Removal of dyes and industrial dye wastes by magnesium chloride, Water Research, 2000, vol. 34, 597-601 DOI:10.1016/S0043-1354(99)00151-7
[4] Purification of Laboratory Chemicals DOI:10.5860/choice.50-6768

Magnesium chloride hexahydrate Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Magnesium chloride hexahydrate Anbieter Lieferant Produzent Hersteller Vertrieb Händler.

Global( 562)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Jiangsu Kolod Food Ingredients Co.,Ltd.
+86-518-85110578 +8618805133257
sales3257@jskolod.com China 132 60
Qingdao Trust Agri Chemical Co.,Ltd
+8613573296305
aroma@qdtrustagri.com China 301 58
Hebei Saisier Technology Co., LTD
+86-18400010335 +86-18034520335
admin@hbsaisier.cn China 1015 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578
sales@hbmojin.com China 12840 58
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+8617531190177
peter@yan-xi.com China 5857 58
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+862156762820 +86-13564624040
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deasea125996@gmail.com China 2472 58
Shaanxi TNJONE Pharmaceutical Co., Ltd
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