ChemicalBook >> CAS DataBase List >>1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER

1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER

1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER structure

CAS No.: 1515-75-9

Chemical Name:: 1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER

Synonyms: METHYL PENTANEDIENOATE;METHYL 2,4-PENTADIENOATE;methyl penta-2,4-dienoate;Dimethyl-2,4-pentandioate;(E)-Methyl 2,4-Pentadienoate;Vynilacrylic acid methyl ester;2,4-pentadienoic acid methyl ester;METHYL 1,3-BUTADIENE-1-CARBOXYLATE;1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER;methyl 1,3-butadiene-1-carboxylate mixt. of cis/trans

CBNumber:: CB0120580

Molecular Formula:: C6H8O2

Molecular Weight:: 112.13

MDL Number:: MFCD00042847

MOL File:: 1515-75-9.mol

Last updated:2025-01-27 09:38:02

Request For Quotation

1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER Properties

Boiling point	50-52 °C20 mm Hg(lit.)
Density	0.964 g/mL at 20 °C
refractive index	n20/D 1.484
Flash point	37 °C
storage temp.	-20°C
solubility	sol most organic solvents
form	liquid
BRN	1743332
LogP	1.340 (est)
UNSPSC Code	12352100
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS02,GHS07
Signal word	Warning
Hazard statements	H226-H315-H319-H335-H412
Precautionary statements	P261-P273-P305+P351+P338
Hazard Codes	Xi
Risk Statements	10-36/37/38-52/53
Safety Statements	26-36-61
RIDADR	UN 3272 3/PG 3
WGK Germany	3
F	8
HazardClass	3.2
PackingGroup	III
HS Code	29161995

1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER price More Price(1)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
American Custom Chemicals Corporation	CHM0124543	METHYL 2,4-PENTADIENOATE 95.00%	1515-75-9	5ML	$874.34	2021-12-16	Buy

Product number	Packaging	Price	Buy
CHM0124543	5ML	$874.34	Buy

1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER Chemical Properties,Uses,Production

Uses

1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER is used as a electron-poor diene capable of cycloaddition reactions with activated dienophiles to form carbocyclic and heterocyclic compounds; metal-promoted [6 + 4] cycloadditions and metal-promoted chain extensions.

Preparation

1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER is prepared by Wittig alkenation of Acrolein with (Methoxycarbonylmethylene)triphenylphosphorane; reaction of Malonic Acid with acrolein, followed by esterification.

Synthesis Reference(s)

Journal of the American Chemical Society, 94, p. 4395, 1972 DOI: 10.1021/ja00767a088
Synthesis, p. 534, 1988 DOI: 10.1055/s-1988-27626

General Description

Methyl 2,4-pentadienoate undergoes Aza-Morita-Baylis-Hillman reaction with aldimines in DMF in the presence of 3-hydroxyquinuclidine.

Precautions

Polymerizes easily.

1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER Preparation Products And Raw materials

Raw materials

Preparation Products

1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER Suppliers

Global( 44)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Antai Fine Chemical Technology Co.,Limited	18503026267	info@antaichem.com	CHINA	9636	58
Career Henan Chemica Co	+86-0371-86658258 +8613203830695	laboratory@coreychem.com	China	30233	58
Hebei Weibang Biotechnology Co., Ltd	+8617732866630	bess@weibangbio.com	China	18147	58
Aladdin Scientific	+1-+1(833)-552-7181	sales@aladdinsci.com	United States	57505	58
Qingdao Dexin Chemical Co., Ltd	+86-15553333686 +86-15553333686	15553333686@qq.com	China	3113	58
Hebei Fengmu Trading Co., Ltd.	+8613393234347	Lyla@fengmuchem.com	China	2946	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	94657	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	021-61259108 18621169109	market03@meryer.com	China	40228	62
Energy Chemical	021-021-58432009 400-005-6266	sales8178@energy-chemical.com	China	44689	61
Shanghai Aladdin Bio-Chem Technology Co.,LTD	400-6206333 18021050169	market@aladdin-e.com	China	25003	65

Supplier	Advantage
Antai Fine Chemical Technology Co.,Limited	58
Career Henan Chemica Co	58
Hebei Weibang Biotechnology Co., Ltd	58
Aladdin Scientific	58
Qingdao Dexin Chemical Co., Ltd	58
Hebei Fengmu Trading Co., Ltd.	58
J & K SCIENTIFIC LTD.	76
Meryer (Shanghai) Chemical Technology Co., Ltd.	62
Energy Chemical	61
Shanghai Aladdin Bio-Chem Technology Co.,LTD	65

1515-75-9(1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER)Related Search:

ETHYL SORBATE ETHYL BETA-APO-8'-CAROTENOATE (TRANS) FEMA 3148 BUTYL SORBATE MUCONOMYCIN A

3-CARBOMETHOXY-2-PYRONE Bixin Crocin METHYL SORBATE PENTAMETHYL CYCLOPENTADIENE-1,2,3,4,5-PENTACARBOXYLATE

11-METHOXY-3,7-11-TRIMETHYL-2,4-DODECADIENOIC ACID ISOPROPYL ESTER SORBIC ACID VINYL ESTER Ethyl-2,4-decadienoate 2,4-DECADIENOIC ACID METHYL ESTER 1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER

ALLYL SORBATE DIMETHYL 1,3-CYCLOHEXADIENE-1,4-DICARBOX YLATE, TECH., 90 PHORBOL 12-RETINOATE 13-ACETATE, 4BETA

1of4

Methyl 2,4-pentadienoate, stabilized with 0.5% hydroquinone, stabilized with 0.5% hydroquinone, 97% Methyl 2,4-pentadienoate Mixture of cis and trans, >=97.0% (GC) 1,3-BUTADIENE-1-CARBOXYLIC ACID METHYL ESTER Methyl 2,4-pentadienoate,1,3-Butadiene-1-carboxylic acid methyl ester, 2,4-Pentadienoic acid methyl ester, Methyl 1,3-butadiene-1-carboxylate (E)-Methyl 2,4-Pentadienoate METHYL PENTANEDIENOATE METHYL 2,4-PENTADIENOATE METHYL 1,3-BUTADIENE-1-CARBOXYLATE 2,4-pentadienoic acid methyl ester methyl 1,3-butadiene-1-carboxylate mixt. of cis/trans methyl penta-2,4-dienoate METHYL 1,3-BUTADIENE-1-CARBOXYLATE MIXT. OF CIS/TRANS, STAB. Vynilacrylic acid methyl ester Dimethyl-2,4-pentandioate 1,3-Butadiene-1-carboxylic acid methyl ester, 2,4-Pentadienoic acid methyl ester, Methyl 1,3-butadiene-1-carboxylate 1515-75-9 CH2CHCHCHCOOCH3 Esters Organic Building Blocks Carbonyl Compounds C6 to C7 Building Blocks