ChemicalBook >> CAS DataBase List >>TRIBUTYLSTANNYLACETYLENE
TRIBUTYLSTANNYLACETYLENE
- CAS No.
- 994-89-8
- Chemical Name:
- TRIBUTYLSTANNYLACETYLENE
- Synonyms
- TRIBUTYLETHYNYLSTANNANE;SKL1071;NSC 203201;ETHYNYLTRIBUTYLIN;ethenyltributyltin;ETHYNYLTRIBUTYLTIN;TRIBUTYL(ETHYNYL)TIN;TribuTylTin aceTylene;TRI-N-BUTYLETHYNYLTIN;ETHYNYLTRI-N-BUTYLTIN
- CBNumber:
- CB0161680
- Molecular Formula:
- C14H28Sn
- Molecular Weight:
- 315.08
- MDL Number:
- MFCD00009420
- MOL File:
- 994-89-8.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
Boiling point | 70 °C0.2 mm Hg(lit.) |
---|---|
Density | 1.089 g/mL at 25 °C(lit.) |
refractive index |
n |
Flash point | 165 °F |
storage temp. | Sealed in dry,Store in freezer, under -20°C |
Specific Gravity | 1.089 |
Water Solubility | Not miscible or difficult to mix with water. |
Sensitive | Moisture Sensitive |
BRN | 3537659 |
InChIKey | YEMJHNYABQHWHL-UHFFFAOYSA-N |
CAS DataBase Reference | 994-89-8(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS06,GHS08,GHS09 |
|||||||||
---|---|---|---|---|---|---|---|---|---|---|
Signal word | Danger | |||||||||
Hazard statements | H301-H312-H315-H319-H360FD-H372-H410 | |||||||||
Precautionary statements | P202-P273-P280-P301+P310-P302+P352+P312-P305+P351+P338 | |||||||||
Hazard Codes | T,N,Xn | |||||||||
Risk Statements | 21-25-36/38-48/23/25-50/53 | |||||||||
Safety Statements | 35-36/37/39-45-60-61 | |||||||||
RIDADR | UN 2788 6.1/PG 3 | |||||||||
WGK Germany | 3 | |||||||||
F | 21 | |||||||||
TSCA | No | |||||||||
HazardClass | 6.1 | |||||||||
PackingGroup | III | |||||||||
HS Code | 29319090 | |||||||||
NFPA 704 |
|
TRIBUTYLSTANNYLACETYLENE price More Price(19)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 275069 | Ethynyltributylstannane 95% | 994-89-8 | 1g | $90.7 | 2023-06-20 | Buy |
Sigma-Aldrich | 275069 | Ethynyltributylstannane 95% | 994-89-8 | 5g | $109 | 2023-06-20 | Buy |
Alfa Aesar | L20178 | Ethynyltri-n-butyltin, 96% | 994-89-8 | 1g | $75.5 | 2023-06-20 | Buy |
Alfa Aesar | L20178 | Ethynyltri-n-butyltin, 96% | 994-89-8 | 5g | $246 | 2023-06-20 | Buy |
GFS CHEMICALS | 10112 | TRIBUTYLSTANNYLACETYLENE | 994-89-8 | 5G | $230.2 | 2021-12-16 | Buy |
TRIBUTYLSTANNYLACETYLENE Chemical Properties,Uses,Production
Chemical Properties
clear colorless liquid
Uses
Ethynyltributylstannane can be used as a reactant to prepare:
- Terminal arylacetylene derivatives by Stille coupling reaction with aryl halides in the presence of palladium catalyst.
- 1,4-bis(tributylstannyl)but-1-en-3-yne by dimerization using a metal complex having bulky ligand catalyst system.
- Isoquinolone derivatives by reacting with benzotriazinones via denitrogenative insertion in the presence of nickel catalyst.
- Enyne key intermediates in the total synthesis of (-)-acutumine and (-)-dechloroacutumine.
Uses
Used to prepare vinylstannanes and stannylisoxazoles. Ethynylation reagent for azaaromatics.
Purification Methods
Purify it by dissolving the reagent (ca 50g) in heptane (250mL), washing it with H2O (100mL), drying (MgSO4), evaporating and distilling in a vacuum. It has IR: max 3280 ( C), 2950, 2850, 2005 (CC), 1455, 1065 and 865cm-1. [Bottaro et al. J Org Chem 46 5221 1981, Stille & Simpson J Am Chem Soc 109 2138 1987, Zavgorodnii et al. J Gen Chem USSR (Engl Edn) 37 1469 1967.]
TRIBUTYLSTANNYLACETYLENE Preparation Products And Raw materials
Raw materials
Preparation Products
TRIBUTYLSTANNYLACETYLENE Suppliers
Global( 160)Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39894 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49374 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | factory@coreychem.com | China | 29811 | 58 |
Guangzhou Yuheng Pharmaceutical Technology Co., Ltd | +8613580539051 | joe@yuhengpharm.com | CHINA | 21142 | 58 |
Kindchem(Nanjing)Co.,Ltd | +86-025-025-85281586 +8618651653755 | sales@kindchem.cn | China | 1226 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34563 | 58 |
Shanghai UCHEM Inc. | +862156762820 +86-13564624040 | sales@myuchem.com | China | 7514 | 58 |
Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 7724 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52849 | 58 |
Henan Alfa Chemical Co., Ltd | China | 13225 | 58 |
View Lastest Price from TRIBUTYLSTANNYLACETYLENE manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2022-02-22 | Tributylstannylacetylene
994-89-8
|
US $0.00 / KG | 1KG | 97.6% | 100 tons | Honest Joy Holdings Limited
|
||
2021-08-12 | TRIBUTYLSTANNYLACETYLENE
994-89-8
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd | ||
2019-12-25 | TRIBUTYLSTANNYLACETYLENE
994-89-8
|
US $1.00 / KG | 1KG | 99% | 200kg | Career Henan Chemical Co |
- Tributylstannylacetylene
994-89-8
- US $0.00 / KG
- 97.6%
- Honest Joy Holdings Limited
- TRIBUTYLSTANNYLACETYLENE
994-89-8
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
- TRIBUTYLSTANNYLACETYLENE
994-89-8
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
994-89-8(TRIBUTYLSTANNYLACETYLENE)Related Search:
YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE
Scandium trifluoromethanesulfonate
GALLIUM(III) TRIFLUOROMETHANESULFONATE
Diethyl acetylenedicarboxylate
2-Ethynyl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane
1of3
Ethynyltri-n-butylstannane~Tri-n-butyl(ethynyl)tin~Tri-n-butylstannylacetylene
Ethynyltri-n-butyltin,97%
TRI-N-BUTYLETHYNYLTIN
TRI-N-BUTYLSTANNYLACETYLENE
TRIBUTYLSTANNYLACETYLENE
TRIBUTYL(ETHYNYL)TIN
Tributylethynylstannane,98%
Tributylethynylstannane,95%
ethynyltri-n-butylstannane
ETHYNYLTRIBUTYLIN
TribuTylTin aceTylene
ethenyltributyltin
ETHYNYLTRIBUTYLSTANNANE
ETHYNYLTRIBUTYLTIN
ETHYNYLTRI-N-BUTYLTIN
Tributylstannylacetylene ,95%
Ethynyltributylstaane
Tributylethynylstannane, 95% 2.5GR
(Tributylstannyl)acetylide
(Tributylstannyl)ethyne
NSC 203201
Ethynyltributylstannane 95%
Stannane, tributylethynyl-
Ttibutylstannylacetylene
TRIBUTYLSTANNYLACETYLENE ISO 9001:2015 REACH
SKL1071
TRIBUTYLETHYNYLSTANNANE
Acetynyltrin-butyltin
TRIBUTYLSTANNYLACETYLEN
994-89-8
HCCSnCH2CH2CH2CH33
HC8801CSnCH2CH2CH2CH33
C14H28Sn
C4H93SnCCH
Classes of Metal Compounds
Sn (Tin) Compounds
Typical Metal Compounds
Functionalized Acetylenes
Acetylenes
Organotin
Organotins
Organometallic Reagents
organic tin
Stannanes
Acetylenes
Classes of Metal Compounds
Functionalized Acetylenes
Sn (Tin) Compounds
Typical Metal Compounds