Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>2-BROMO-1,3,2-BENZODIOXABOROLE

2-BROMO-1,3,2-BENZODIOXABOROLE

2-BROMO-1,3,2-BENZODIOXABOROLE Structure
2-BROMO-1,3,2-BENZODIOXABOROLE structure
CAS No.
51901-85-0
Chemical Name:
2-BROMO-1,3,2-BENZODIOXABOROLE
Synonyms
B-BROMOCATECHOLBORANE;Catechol boron bromide;2-broMobenzo[d][1,3,2]dioxaborole;B-Bromocatecholborane>beta-Bromocatecholborane;o-Phenylene bromoboronate;B-Bromocatecholborane;2-bromo-1,3,2-benzodioxaborale;2-BROMO-1,3,2-BENZODIOXABOROLE;1,3,2-Benzodioxaborole, 2-bromo-
CBNumber:
CB0195632
Molecular Formula:
C6H4BBrO2
Molecular Weight:
198.81
MDL Number:
MFCD00013341
MOL File:
51901-85-0.mol
MSDS File:
SDS
Last updated:2025-01-27 09:38:02
Request For Quotation

2-BROMO-1,3,2-BENZODIOXABOROLE Properties

Melting point 51-53 °C(lit.)
Boiling point 76 °C9 mm Hg(lit.)
Density 1.67±0.1 g/cm3(Predicted)
Flash point 107 °F
storage temp. 2-8°C
solubility sol dichloromethane
form powder to lump
color White to Amber to Dark purple
BRN 2445073
CAS DataBase Reference 51901-85-0
FDA UNII VQ20068KEZ
UNSPSC Code 12352103
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05
Signal word  Danger
Hazard statements  H228-H314
Precautionary statements  P210-P240-P260-P280-P303+P361+P353-P305+P351+P338
Hazard Codes  C
Risk Statements  14-34-37
Safety Statements  26-36/37/39-45
RIDADR  UN 2925 4.1/PG 2
WGK Germany  3
F  8-10-21
HS Code  2931.90.6000
HazardClass  4.1
PackingGroup  III
NFPA 704
2
3 3

2-BROMO-1,3,2-BENZODIOXABOROLE price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 304166 2-Bromo-1,3,2-benzodioxaborole 97% 51901-85-0 10g $228 2024-03-01 Buy
Sigma-Aldrich 304166 2-Bromo-1,3,2-benzodioxaborole 97% 51901-85-0 50g $710 2024-03-01 Buy
TCI Chemical B2132 B-Bromocatecholborane >97.0%(T) 51901-85-0 5g $87 2024-03-01 Buy
TCI Chemical B2132 B-Bromocatecholborane >97.0%(T) 51901-85-0 25g $294 2024-03-01 Buy
TRC B680453 2-​Bromo-​1,​3,​2-​benzodioxaborole 51901-85-0 2.5g $140 2021-12-16 Buy
Product number Packaging Price Buy
304166 10g $228 Buy
304166 50g $710 Buy
B2132 5g $87 Buy
B2132 25g $294 Buy
B680453 2.5g $140 Buy

2-BROMO-1,3,2-BENZODIOXABOROLE Chemical Properties,Uses,Production

Uses

B-Bromocatecholborane is a mild Lewis acid capable of selective cleavage of ether, ester and carbamate protecting groups; catalyst for Diels-Alder reactions.

Preparation

B-Bromocatecholborane can be conveniently prepared by treating Catechol with Boron Tribromide. The reagent is isolated by distillation as a moisture-sensitive, low-melting solid.

storage

B-Bromocatecholborane is a flammable solid, moisture sensitive; may be conveniently stored and dispensed as a 0.2 M solution in dichloromethane. If properly protected from moisture, these solutions are stable for a period of months[1]. Use in a fume hood.

Purification Methods

Keep at 20o/15mm for some time and then fractionally distil. [Gerrard J Chem Soc 1529 1959, Beilstein 6 IV 5612.]

References

1. Boeckman Jr., R. K.; Potenza, J. C. TL 1985, 26, 1411.

2-BROMO-1,3,2-BENZODIOXABOROLE Preparation Products And Raw materials

Raw materials

Preparation Products

ETHYL 4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZOATE

2-BROMO-1,3,2-BENZODIOXABOROLE Suppliers

Global( 67)Suppliers
Supplier Tel Email Country ProdList Advantage
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49732 58
career henan chemical co 		+86-0371-86658258 +8613203830695 factory@coreychem.com China 29807 58
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Dayang Chem (Hangzhou) Co.,Ltd. 		+86-0571-88938639 +8617705817739 info@dycnchem.com China 52846 58
Alfa Chemistry 		Info@alfa-chemistry.com United States 24072 58
Shandong Zhishang New Material Co., Ltd. 		+8617653113209 sales002@sdzschem.com China 3049 58
Hebei Chuanghai Biotechnology Co., Ltd 		+8615531151365 mina@chuanghaibio.com China 18128 58
GIHI CHEMICALS CO.,LIMITED 		+8618058761490 info@gihichemicals.com China 49983 58
Zhengzhou Anbu Chem Co.,Ltd 		+86-0371-88006763; +8615988602810 sales@anbuchem.com China 2998 58
Aladdin Scientific 		tp@aladdinsci.com United States 57505 58
Supplier Advantage
CONIER CHEM AND PHARMA LIMITED 		58
career henan chemical co 		58
Hefei TNJ Chemical Industry Co.,Ltd. 		58
Dayang Chem (Hangzhou) Co.,Ltd. 		58
Alfa Chemistry 		58
Shandong Zhishang New Material Co., Ltd. 		58
Hebei Chuanghai Biotechnology Co., Ltd 		58
GIHI CHEMICALS CO.,LIMITED 		58
Zhengzhou Anbu Chem Co.,Ltd 		58
Aladdin Scientific 		58

View Lastest Price from 2-BROMO-1,3,2-BENZODIOXABOROLE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
B-Bromocatecholborane pictures 2021-07-02 B-Bromocatecholborane
51901-85-0
 US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
:2-BROMO-1,3,2-BENZODIOXABOROLE pictures 2019-12-27 :2-BROMO-1,3,2-BENZODIOXABOROLE
51901-85-0
 US $1.00 / KG 1KG 97%-99.9% 100kg Career Henan Chemical Co

51901-85-0(2-BROMO-1,3,2-BENZODIOXABOROLE)Related Search:

CHLOROMETHYLPHENYLSILANE CATECHOLBORANE 2-BROMO-1,3,2-BENZODIOXABOROLE Chloromethyl isopropyl carbonate bis(2-ethylhexyl) tetrabromophthalate
Methyl salicylate 2-(tert-Butylamino)ethyl methacrylate

1of2

2-BROMO-1,3,2-BENZODIOXABOROLE beta-Bromocatecholborane 2-bromo-1,3,2-benzodioxaborale o-Phenylene bromoboronate B-Bromocatecholborane 1,3,2-Benzodioxaborole, 2-bromo- 2-Bromo-1,3,2-benzodioxaborole,B-Bromocatechol-borane 2-Bromo-1,3,2-benzodioxaborole 97% B-Bromocatecholborane> B-BROMOCATECHOLBORANE Catechol boron bromide 2-broMobenzo[d][1,3,2]dioxaborole 2- Bromo -1,3,2- benzodioxo-boron heterocycle pentene 51901-85-0 C6H4BBrO2 Boronic Acids and Derivatives Others Organometallic Reagents Synthetic Reagents C-X Bond Formation (Halogen) Haloboration B-Bromocatecholborane, etc. B (Classes of Boron Compounds) B (Classes of Boron Compounds) B-Bromocatecholborane, etc.