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TRIS(2-AMINOETHYL)AMINE

CAS No.
4097-89-6
Chemical Name:
TRIS(2-AMINOETHYL)AMINE
Synonyms
TREN;TAEA;tri(2-aminoethyl)amine;tris(aminoethyl)amine;trenhp;Tris(2-aminoethyL;Tris(2-aMinoethyl)a;Trientine Impurity 5;Triaminotriethyl-amine;N1,N1-Bis(2-aminoethyl)
CBNumber:
CB0235693
Molecular Formula:
C6H18N4
Molecular Weight:
146.23
MDL Number:
MFCD00008177
MOL File:
4097-89-6.mol
MSDS File:
SDS
Last updated:2024-11-19 15:53:33

TRIS(2-AMINOETHYL)AMINE Properties

Melting point -16 °C
Boiling point 114 °C/15 mmHg (lit.)
Density 0.976 g/mL at 20 °C (lit.)
vapor density 5 (vs air)
vapor pressure 0.02 mm Hg ( 20 °C)
refractive index n20/D 1.497(lit.)
Flash point >230 °F
storage temp. 2-8°C
solubility Chloroform (Sparingly), DMSO (Slightly)
form saline suspension
pka 10.00±0.10(Predicted)
color Clear yellow
Specific Gravity 0.977
Water Solubility Miscible with water.
Sensitive Hygroscopic
BRN 1739626
Stability Stable. Hygroscopic. Absorbs carbon dioxide from the air. Incompatible with strong acids, strong oxidizing agents.
CAS DataBase Reference 4097-89-6(CAS DataBase Reference)
FDA UNII 3GY3QSG6H5
EPA Substance Registry System 1,2-Ethanediamine, N,N-bis(2-aminoethyl)- (4097-89-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06
Signal word  Danger
Hazard statements  H301-H310-H314
Precautionary statements  P270-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  T,Xi
Risk Statements  22-24-34-36/37/38-10
Safety Statements  26-36/37/39-45-16
RIDADR  UN 2922 8/PG 2
WGK Germany  3
RTECS  KH8587082
3-10-23
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29211990
Toxicity mouse,LD50,oral,1800mg/kg (1800mg/kg),LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSIONBEHAVIORAL: ATAXIAGASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA","Spravochnik po Toksikologii i Gigienicheskim Normativam Vol. -, Pg. 223, 1999.
NFPA 704
1
4 1

TRIS(2-AMINOETHYL)AMINE price More Price(33)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 225630 Tris(2-aminoethyl)amine 96% 4097-89-6 10ml $54.4 2024-03-01 Buy
Sigma-Aldrich 225630 Tris(2-aminoethyl)amine 96% 4097-89-6 100ml $266 2024-03-01 Buy
TCI Chemical T1243 Tris(2-aminoethyl)amine >98.0%(T) 4097-89-6 5mL $36 2024-03-01 Buy
TCI Chemical T1243 Tris(2-aminoethyl)amine >98.0%(T) 4097-89-6 25mL $105 2024-03-01 Buy
Alfa Aesar B21789 Tris(2-aminoethyl)amine, 97% 4097-89-6 25g $75.6 2024-03-01 Buy
Product number Packaging Price Buy
225630 10ml $54.4 Buy
225630 100ml $266 Buy
T1243 5mL $36 Buy
T1243 25mL $105 Buy
B21789 25g $75.6 Buy

TRIS(2-AMINOETHYL)AMINE Chemical Properties,Uses,Production

Chemical Properties

Colorless liquid

Uses

Tris(2-aminoethyl)amine is a tetradentate chelating ligand and forms stable complexes with transition metals. It is also used as a carbon dioxide absorbent. Further, it acts as a reagent for cleavage of the fluorenylmethyloxycarbonyl (Fmoc) group in peptide synthesis. It reacts with aryl isocyanates and isothiocyanates to give tris-urea and -thiourea derivatives.

Definition

ChEBI: Tris(2-aminoethyl)amine is a tetramine.

General Description

Tris(2-aminoethyl)amine (TREN) is a water soluble tripodal ligand that is majorly used in co-ordination chemistry. It has three aminoethylgroups that attach with the surface atoms to provide a scaffold assembly.

Hazard

A poison by ingestion and skin contact.

Safety Profile

A poison by ingestion and skin contact. When heated to decomposition it emits toxic vapors of NOx.

Purification Methods

For a separation from a mixture containing 62% TRIEN, see entry under triethylenetetramine. Also purify it by conversion to the hydrochloride (see below), recrystallise it and regenerate the free base [Xie & Hendrickson J Am Chem Soc 109 6981 1987]. [Beilstein 4 H 256, 4 II 695, 4 III 545, 4 IV 1250.]

817-09-4
4097-89-6
Synthesis of TRIS(2-AMINOETHYL)AMINE from TRIS(2-CHLOROETHYL)AMINE HYDROCHLORIDE
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View Lastest Price from TRIS(2-AMINOETHYL)AMINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
TRIS(2-AMINOETHYL)AMINE pictures 2024-11-19 TRIS(2-AMINOETHYL)AMINE
4097-89-6
US $0.00-0.00 / KG 1KG 98.0% 10000KGS Shaanxi Dideu New Materials Co. Ltd
TRIS(2-AMINOETHYL)AMINE pictures 2023-09-14 TRIS(2-AMINOETHYL)AMINE
4097-89-6
US $0.00-0.00 / kg 1kg 99.8 10000kg Wuhan Han Sheng New Material Technology Co.,Ltd
Tris(2-aminoethyl)amine pictures 2023-07-27 Tris(2-aminoethyl)amine
4097-89-6
US $1.50 / g 1g 99.0% Min 100 Tons Shaanxi Didu New Materials Co. Ltd
tris(beta-aminoethyl)amine 2,2',2''-Triaminotriethylamine,97%TREN 2,2'',2 -TRIAMINOTRIETHYLAMINE TREN 2,2μ,2μμ-Nitrilotriethylamine, 2,2μ,2μμ-Triaminotriethylamine, TAEA 2,2',2''-Nitrilotris(ethane-1-amine) 2,2',2''-Nitrilotrisethanamine Tris(2-aminoethyl)amine ,95% Tris(2-aMinoethyl)aMine, 96% 100ML Tris(2-aMinoethyl)aMine, 96% 5ML Tris(2-aminoethyl)amine,96% Tris(2-aMinoethyl)a Tris(2-aMinoethyl)aMine 96% N1,N1-Bis(2-aminoethyl) TRIS(2-AMINOETHYL)AMINE 2,2',2''-TRIAMINOTRIETHYLAMINE 2,2',2''-NITRILOTRIETHYLAMINE N1,N1-Bis-(2-amino-ethyl)-ethane-1,2-diamine nitrilotris(ethylamine) trenhp Triaminotriethyl-amine 2,2’,2’’-nitrilotris(ethylamine) 2,2’,2’’-triaminotris(ethylamine) 4-(2-Aminoethyl)diethylene triamine 4-(2-aminoethyl)-diethylenetriamin 4-(2-Aminoethyl)diethylenetriamine beta,beta’,beta’’-triaminotriethylamine 2,2',2''-Triaminotriethylamine, min. 98% TREN Tris(2-aminoethyL 1,2-Ethanediamine, N1,N1-bis(2-aminoethyl)- Trientine Impurity 5 Tris(2-aminoethyl)amine, 98+%, tris(aminoethyl)amine TAEA TREN tri(2-aminoethyl)amine 4097-89-6 C6H18N4 NCH2CH2NH23 NH2CH2CH23N Building Blocks Nitrogen Compounds Organic Building Blocks Polyamines