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(Carbomethoxymethyl)triphenylphosphonium bromide

CAS No.
1779-58-4
Chemical Name:
(Carbomethoxymethyl)triphenylphosphonium bromide
Synonyms
CMMTPPB;NSC 136109;methyl (triphenylphosphonio)acetate bromide;(2-methoxy-2-oxoethyl)-triphenylphosphanium;CARBOMETHOXYMETHYL TRIPHENYLPHOSPHONIUM BROMIDE;carbmethoxy Methyl Triphenyl Phosphonium Bromide;MethoxycarbonylMethyl)triphenylphosphoniuM broMi;Triphenyl(2-oxo-2-methoxyethyl)phosphonium·bromide;(2-Oxo-2-methoxyethyl)triphenylphosphonium·bromide;(2-methoxy-2-oxoethyl)triphenylphosphonium bromide
CBNumber:
CB0254687
Molecular Formula:
C21H20BrO2P
Molecular Weight:
415.26
MDL Number:
MFCD00011801
MOL File:
1779-58-4.mol
MSDS File:
SDS
Last updated:2024-05-30 16:33:02

(Carbomethoxymethyl)triphenylphosphonium bromide Properties

Melting point 165-170 °C (dec.) (lit.)
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in methanol(almost transparency).
form solid
color White to Almost white
Sensitive Hygroscopic
BRN 3812975
InChIKey VCWBQLMDSMSVRL-UHFFFAOYSA-M
CAS DataBase Reference 1779-58-4(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
9
HS Code  29319019
NFPA 704
1
2 0

(Carbomethoxymethyl)triphenylphosphonium bromide price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 259063 (Methoxycarbonylmethyl)triphenylphosphonium bromide 98% 1779-58-4 50g $85.2 2023-01-07 Buy
Sigma-Aldrich 259063 (Methoxycarbonylmethyl)triphenylphosphonium bromide 98% 1779-58-4 250g $326 2023-01-07 Buy
TCI Chemical M1326 Methoxycarbonylmethyl(triphenyl)phosphonium Bromide >97.0%(HPLC)(T) 1779-58-4 25g $68 2024-03-01 Buy
Alfa Aesar A16301 (Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+% 1779-58-4 25g $33.65 2024-03-01 Buy
Alfa Aesar A16301 (Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+% 1779-58-4 100g $93.65 2024-03-01 Buy
Product number Packaging Price Buy
259063 50g $85.2 Buy
259063 250g $326 Buy
M1326 25g $68 Buy
A16301 25g $33.65 Buy
A16301 100g $93.65 Buy

(Carbomethoxymethyl)triphenylphosphonium bromide Chemical Properties,Uses,Production

Chemical Properties

white powder

Uses

(Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction, substituted furanones for antifungal and cytostatic activities, photochromic dithienylethene derivatives, gem-diiodoalkanes containing allylic alcohols and highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization. As reactant for asymmetric hydrogenation of α,β-unsaturated ester-phosphonates, studies of thermal decomposition of phosphonium alkyl ester salts.

Purification Methods

Wash it with pet ether (b 40-50o), recrystallise it from CHCl3/Et2O and dry it at high vacuum at 65o. [Isler et al. Helv Chim Acta 40 1242 1957, Wittig & Haag Chem Ber 88 1654, 1664 1955, Beilstein 16 IV 981.]

(Carbomethoxymethyl)triphenylphosphonium bromide Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 236)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 20287 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 18777 58
career henan chemical co
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Hebei Weibang Biotechnology Co., Ltd
+8615531157085 abby@weibangbio.com China 8811 58
Xi'an Kono chem co., Ltd.,
029-86107037 13289246953 info@konochemical.com China 2993 58
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Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 13482 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12839 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34553 58
Wuhan Fortuna Chemical Co., Ltd
+86-027-59207850 info@fortunachem.com China 5978 58

View Lastest Price from (Carbomethoxymethyl)triphenylphosphonium bromide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(Carbomethoxymethyl)triphenylphosphonium bromide pictures 2024-11-22 (Carbomethoxymethyl)triphenylphosphonium bromide
1779-58-4
US $0.00 / KG 1KG 98%min 30tons/month WUHAN FORTUNA CHEMICAL CO., LTD
(2-Methoxy-2-oxoethyl)triphenylphosphonium bromide pictures 2024-01-14 (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide
1779-58-4
US $5.00-0.50 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
(Carbomethoxymethyl)triphenylphosphonium bromide pictures 2023-01-31 (Carbomethoxymethyl)triphenylphosphonium bromide
1779-58-4
US $0.00 / Kg/Drum 1Kg/Drum 99% 5000KG Hebei Mojin Biotechnology Co., Ltd
(2-methoxy-2-oxoethyl)triphenylphosphonium bromide carbmethoxy Methyl Triphenyl Phosphonium Bromide Carbomethoxymethyl triphenylphosphonium bromide, 98+% CARBOMETHOXYMETHYL TRIPHENYLPHOSPHONIUM BROMIDE (METHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE methyl (triphenylphosphonio)acetate bromide PHOSPHONIUM,(2-METHOXY-2-OXOETHYL)TRIPHENYL-,BROMIDE (METHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE, 98+% CMMTPPB (2-Oxo-2-methoxyethyl)triphenylphosphonium·bromide Triphenyl(2-oxo-2-methoxyethyl)phosphonium·bromide Triphenyl(methoxycarbonylmethyl)phosphonium·bromide MethoxycarbonylMethyl)triphenylphosphoniuM broMi (MethoxycarbonylMethyl)triphenylphosphoniuM broMide, 98+%, 98+% NSC 136109 (2-methoxycarbonylphenyl)-methyl-diphenylphosphonium bromide Methoxycarbonylmethyl(triphenyl)phosphoniumBromide> (2-methoxy-2-oxoethyl)-triphenylphosphanium,bromide (2-methoxy-2-oxoethyl)-triphenylphosphanium (methyloxycarbonylmethyl)triphenylphosphonium bromide 1779-58-4 CH3O2CCH2PC6H53Br CH3OCOCH2PBrC6H53 C21H20O2PBr C-C Bond Formation Phosphonium Compounds Wittig & Horner-Emmons Reaction Wittig Reaction Synthetic Reagents Wittig Reagents Olefination Phosphonium Compounds Synthetic Organic Chemistry Wittig & Horner-Emmons Reaction Wittig Reaction bc0001