(Carbomethoxymethyl)triphenylphosphonium bromide
- CAS No.
- 1779-58-4
- Chemical Name:
- (Carbomethoxymethyl)triphenylphosphonium bromide
- Synonyms
- CMMTPPB;NSC 136109;methyl (triphenylphosphonio)acetate bromide;(2-methoxy-2-oxoethyl)-triphenylphosphanium;CARBOMETHOXYMETHYL TRIPHENYLPHOSPHONIUM BROMIDE;carbmethoxy Methyl Triphenyl Phosphonium Bromide;MethoxycarbonylMethyl)triphenylphosphoniuM broMi;Triphenyl(2-oxo-2-methoxyethyl)phosphonium·bromide;(2-Oxo-2-methoxyethyl)triphenylphosphonium·bromide;(2-methoxy-2-oxoethyl)triphenylphosphonium bromide
- CBNumber:
- CB0254687
- Molecular Formula:
- C21H20BrO2P
- Molecular Weight:
- 415.26
- MDL Number:
- MFCD00011801
- MOL File:
- 1779-58-4.mol
- MSDS File:
- SDS
Melting point | 165-170 °C (dec.) (lit.) |
---|---|
storage temp. | Inert atmosphere,Room Temperature |
solubility | Soluble in methanol(almost transparency). |
form | solid |
color | White to Almost white |
Sensitive | Hygroscopic |
BRN | 3812975 |
InChIKey | VCWBQLMDSMSVRL-UHFFFAOYSA-M |
CAS DataBase Reference | 1779-58-4(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36-37/39 | |||||||||
WGK Germany | 3 | |||||||||
F | 9 | |||||||||
HS Code | 29319019 | |||||||||
NFPA 704 |
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(Carbomethoxymethyl)triphenylphosphonium bromide price More Price(22)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 259063 | (Methoxycarbonylmethyl)triphenylphosphonium bromide 98% | 1779-58-4 | 50g | $85.2 | 2023-01-07 | Buy |
Sigma-Aldrich | 259063 | (Methoxycarbonylmethyl)triphenylphosphonium bromide 98% | 1779-58-4 | 250g | $326 | 2023-01-07 | Buy |
TCI Chemical | M1326 | Methoxycarbonylmethyl(triphenyl)phosphonium Bromide >97.0%(HPLC)(T) | 1779-58-4 | 25g | $68 | 2024-03-01 | Buy |
Alfa Aesar | A16301 | (Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+% | 1779-58-4 | 25g | $33.65 | 2024-03-01 | Buy |
Alfa Aesar | A16301 | (Methoxycarbonylmethyl)triphenylphosphonium bromide, 98+% | 1779-58-4 | 100g | $93.65 | 2024-03-01 | Buy |
(Carbomethoxymethyl)triphenylphosphonium bromide Chemical Properties,Uses,Production
Chemical Properties
white powder
Uses
(Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction, substituted furanones for antifungal and cytostatic activities, photochromic dithienylethene derivatives, gem-diiodoalkanes containing allylic alcohols and highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization. As reactant for asymmetric hydrogenation of α,β-unsaturated ester-phosphonates, studies of thermal decomposition of phosphonium alkyl ester salts.
Purification Methods
Wash it with pet ether (b 40-50o), recrystallise it from CHCl3/Et2O and dry it at high vacuum at 65o. [Isler et al. Helv Chim Acta 40 1242 1957, Wittig & Haag Chem Ber 88 1654, 1664 1955, Beilstein 16 IV 981.]
(Carbomethoxymethyl)triphenylphosphonium bromide Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20287 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18777 | 58 |
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29882 | 58 |
Hebei Weibang Biotechnology Co., Ltd | +8615531157085 | abby@weibangbio.com | China | 8811 | 58 |
Xi'an Kono chem co., Ltd., | 029-86107037 13289246953 | info@konochemical.com | China | 2993 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39894 | 58 |
Zhengzhou Alfa Chemical Co.,Ltd | +8618530059196 | sale04@alfachem.cn | China | 13482 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12839 | 58 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418671 +8618949823763 | sales@tnjchem.com | China | 34553 | 58 |
Wuhan Fortuna Chemical Co., Ltd | +86-027-59207850 | info@fortunachem.com | China | 5978 | 58 |
View Lastest Price from (Carbomethoxymethyl)triphenylphosphonium bromide manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-11-22 | (Carbomethoxymethyl)triphenylphosphonium bromide
1779-58-4
|
US $0.00 / KG | 1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | ||
2024-01-14 | (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide
1779-58-4
|
US $5.00-0.50 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | ||
2023-01-31 | (Carbomethoxymethyl)triphenylphosphonium bromide
1779-58-4
|
US $0.00 / Kg/Drum | 1Kg/Drum | 99% | 5000KG | Hebei Mojin Biotechnology Co., Ltd |
- (Carbomethoxymethyl)triphenylphosphonium bromide
1779-58-4
- US $0.00 / KG
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
- (2-Methoxy-2-oxoethyl)triphenylphosphonium bromide
1779-58-4
- US $5.00-0.50 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
- (Carbomethoxymethyl)triphenylphosphonium bromide
1779-58-4
- US $0.00 / Kg/Drum
- 99%
- Hebei Mojin Biotechnology Co., Ltd
(Carbomethoxymethyl)triphenylphosphonium bromide Spectrum
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