ChemicalBook >> CAS DataBase List >>(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

CAS No.
135620-04-1
Chemical Name:
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
Synonyms
(S,S)-Jacbosen;(S,S)-JACOBSEN;(S,S)-Jacobsencat.;JACOBSEN'S CATALYST;(S,S)-JACOBSEN CATALYST;(S,S)-JACOBSEN'S CATALYST;-1,2-cyclohexanediamine]manganese(III);(S,S)-(+)-Jacobsen manganese (III) catalyst;(S,S)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX;(+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- HEXANEDIAMINO-MN CL
CBNumber:
CB0286099
Molecular Formula:
C36H52ClMnN2O2
Molecular Weight:
635.2
MDL Number:
MFCD02101663
MOL File:
135620-04-1.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Properties

Melting point 330-332 °C(lit.)
storage temp. Inert atmosphere,Room Temperature
form Powder
color brown
InChIKey VGAJDQCIDNCJQC-JINVCYSXSA-K
CAS DataBase Reference 135620-04-1
FDA UNII RIM5C05I0Z

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38-20/21/22
Safety Statements  26-36-36/37/39
WGK Germany  3
9
HS Code  29310099

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 404454 (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 135620-04-1 1g $34.32 2024-03-01 Buy
Sigma-Aldrich 404454 (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 135620-04-1 5g $112.2 2024-03-01 Buy
Strem Chemicals 25-0301 (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride, 98% (S,S)-Jacobsen Cat. 135620-04-1 1g $47 2024-03-01 Buy
Strem Chemicals 25-0301 (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride, 98% (S,S)-Jacobsen Cat. 135620-04-1 5g $183 2024-03-01 Buy
Sigma-Aldrich 404454 (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 135620-04-1 25g $663 2024-03-01 Buy
Product number Packaging Price Buy
404454 1g $34.32 Buy
404454 5g $112.2 Buy
25-0301 1g $47 Buy
25-0301 5g $183 Buy
404454 25g $663 Buy

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Chemical Properties,Uses,Production

Reaction

  1. Catalyst for the conversion of olefins to chiral epoxides in high enantiomeric excess.
  2. Pharmaceutically important, single enantiomer amino alcohols are efficiently produced from the corresponding chiral epoxide by acid or base-catalyzed epoxide ring-opening reactions.
  3. Asymmetric Kinetic resolution of secondary alcohols in water.
  4. Enantioselective Reformatsky reaction with ketones.
Reactions of 135620-04-1

Chemical Properties

dark brown powder

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 103)Suppliers
Supplier Tel Email Country ProdList Advantage
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58
Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
CONIER CHEM AND PHARMA LIMITED
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career henan chemical co
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Neostar United (Changzhou) Industrial Co., Ltd.
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+8618530059196 sale04@alfachem.cn China 13503 58
Shanghai UCHEM Inc.
+862156762820 +86-13564624040 sales@myuchem.com China 7514 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-89586680 +86-18192503167 1026@dideu.com China 7724 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com China 52849 58
Labnetwork lnc.
+86-27-50766799 +8618062016861 contact@labnetwork.com China 19987 58

View Lastest Price from (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE pictures 2020-01-08 (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
135620-04-1
US $1.00 / KG 1KG 99.0% 100kg Career Henan Chemical Co
(+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- HEXANEDIAMINO-MN CL (S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL (1S,2S)-(+)-(1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene))manganese(III)chloride (S,S)-Jacobsencat. (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III)chloride,98%(S,S)-JacobsenCat. (S,S)(+)N,N'-Bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chlorideco (S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chlo (1S,2S)-(+)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]Manganese(III) chloride (S,S)-Jacobsen Cat. (1S,2S)-(+)-〔1,2-Cyclohexanediamino-N,N-bis(3,5-di-t-butylsalicylidene)〕manganese(Ⅲ) Chloride (1S,2S)-(+)-[1,2-Cyclohexanediammino-N,N'-bis(3,5-di-t-butylsalicylidene)] manganese (III)chloride,98% (S,S)-Jacobsen Cat (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride (S,S)-(+)-N,N′-Bis(3,5-di-t-butylsalicylidene)-1,2-cyclohexanediamino-manganese(III) chloride (S,S)-Jacbosen -1,2-cyclohexanediamine]manganese(III) (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE JACOBSEN'S CATALYST (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE (S,S)-JACOBSEN CATALYST (S,S)-JACOBSEN'S CATALYST (S,S)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX (S,S)-JACOBSEN (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE ISO 9001:2015 REACH (III)(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) (S, S) - (+) - N, N '- bis (3,5-di-tert-butylsalicyl) -1,2-cyclohexanediamine manganese chloride (S,S)-(+)-Jacobsen manganese (III) catalyst (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride (4S,9S)-14,16,22,24-tetra-tert-butyl-18,20-dioxa-3,10-diaza-19-manganatetracyclo[19.4.0.0?,?.012,1?]pentacosa-1(25),2,10,12,14,16,21,23-octaen-19-ylium chloride (1S,2S)-(-)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III) chloride (S, S) - (+) - N, N '- bis (3,5-di-tert-butylsalicyl) -1,2-cyclohexanediamine manganese chloride 135620-04-1 CH33C2C6H22OCHN2C6H10MnCl C36H54Cl3MnN2O2 Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis Epoxidation Chiral Reagents Jacobsen Metal Other Metal