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(1S,2S)-(+)-1,2-Diaminocyclohexane

(1S,2S)-(+)-1,2-Diaminocyclohexane structure

CAS No.: 21436-03-3

Chemical Name:: (1S,2S)-(+)-1,2-Diaminocyclohexane

Synonyms: (1S,2S)-CYCLOHEXANE-1,2-DIAMINE;(S,S)-1,2-DIAMINOCYCLOHEXANE;trans-Cyclohexane-1,2-diamine;1S,2S-Diaminocyclohexane;(1S,2S)-1,2-DIAMINOCYCLOHEXANE;S-DACH;SS-DAC;(S,S)-DACH;(+)-(S,S)-DACH;(1S,2S)-(+)-1,2-Diam

CBNumber:: CB6357391

Molecular Formula:: C6H14N2

Molecular Weight:: 114.19

MDL Number:: MFCD00062986

MOL File:: 21436-03-3.mol

MSDS File:: SDS

Last updated:2023-12-12 17:13:46

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(1S,2S)-(+)-1,2-Diaminocyclohexane Properties

Melting point	40-43 °C (lit.)
Boiling point	104-110 °C/40 mmHg (lit.)
alpha	25.25 º (589nm, c=5, 1 M HCl)
Density	0.951
refractive index	1.4886
Flash point	169 °F
storage temp.	Keep in dark place,Inert atmosphere,2-8°C
pka	10.76±0.70(Predicted)
form	Crystals or Powder
color	White to light beige
optical activity	[α]20/D +25°, c = 5 in 1 M HCl
Water Solubility	soluble
Sensitive	Air Sensitive
BRN	2801645
InChIKey	SSJXIUAHEKJCMH-WDSKDSINSA-N
CAS DataBase Reference	21436-03-3(CAS DataBase Reference)
FDA UNII	D2V3LYG9F0
NIST Chemistry Reference	(1S,2S)-(+)-1,2-Diaminocyclohexane(21436-03-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05

Signal word

Danger

Hazard statements

H314

Precautionary statements

P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363

Hazard Codes

Risk Statements

Safety Statements

26-36/37/39-45

RIDADR

UN 3259 8/PG 3

WGK Germany

10-34

HazardClass

PackingGroup

III

HS Code

29213000

NFPA 704

	0
3		0

(1S,2S)-(+)-1,2-Diaminocyclohexane price More Price(51)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	346713	(1S,2S)-(+)-1,2-Diaminocyclohexane 98%	21436-03-3	1g	$174	2024-03-01	Buy
Sigma-Aldrich	346713	(1S,2S)-(+)-1,2-Diaminocyclohexane 98%	21436-03-3	5g	$310	2024-03-01	Buy
TCI Chemical	C1448	(1S,2S)-(+)-1,2-Cyclohexanediamine >98.0%(GC)(T)	21436-03-3	5g	$57	2024-03-01	Buy
TCI Chemical	C1448	(1S,2S)-(+)-1,2-Cyclohexanediamine >98.0%(GC)(T)	21436-03-3	25g	$173	2024-03-01	Buy
Alfa Aesar	L14072	(1S,2S)-(+)-1,2-Diaminocyclohexane, 98%	21436-03-3	1g	$78.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
346713	1g	$174	Buy
346713	5g	$310	Buy
C1448	5g	$57	Buy
C1448	25g	$173	Buy
L14072	1g	$78.65	Buy

(1S,2S)-(+)-1,2-Diaminocyclohexane Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powder

Uses

Versatile ligand for the formation of metal complexes. Used in the synthesis of chiral tropocoronands which have potential utility in asymmetric catalysis.

Uses

For synthesis of optically active products

Uses

suzuki reaction

Purification Methods

Distil or recrystallise the diamine from pet ether under N2 or Ar. Store it as above. The 1S,2S-base D-tartrate salt has M 264.3, m 180 -1 8 4o(dec) and [] 25 -12.5o (c 4, H2O) from which the free base can be purified or optically enriched. It is a useful chiral synthon. [Fjii et al. J Chem Soc, Chem Commun 45 1985, Takahashi et al. Tetrahedron Lett 30 7095 1989, Hanassian et al. J Org Chem 58 1991 1993, Beilstein 13 III 7.]

(1S,2S)-(+)-1,2-Diaminocyclohexane synthesis

Synthesis of (1S,2S)-(+)-1,2-Diaminocyclohexane from L(+)-Tartaric acid

(1S,2S)-(+)-1,2-Diaminocyclohexane Preparation Products And Raw materials

Raw materials

(+/-)-trans-1,2-Diaminocyclohexane 3-Methylbenzoyl chloride Acetic acid L(+)-Tartaric acid

Preparation Products

dibuty cebacate with ferric chloride (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE (1S,2S)-Boc-1,2-diaminocyclohexane N-[(1S,2S)-2-aMinocyclohexyl]-MethanesulfonaMide

(1S,2S)-(+)-1,2-Diaminocyclohexane Suppliers

Global( 381)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai UCHEM Inc.	+862156762820 +86-13564624040	sales@myuchem.com	China	7688	58
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29791	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	18751	58
Taizhou Tianhong Biochemistry Technology Co., Ltd.	0523-86132544	sales@thbiochem.com	CHINA	305	60
Beijing Cooperate Pharmaceutical Co.,Ltd	010-60279497	sales01@cooperate-pharm.com	CHINA	1803	55
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21634	55
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1803	55
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29880	58
Shanghai Arbor Chemical Co., Ltd.	021-60451682	act@arborchemical.com	CHINA	904	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28172	58

Supplier	Advantage
Shanghai UCHEM Inc.	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Taizhou Tianhong Biochemistry Technology Co., Ltd.	60
Beijing Cooperate Pharmaceutical Co.,Ltd	55
Henan Tianfu Chemical Co.,Ltd.	55
Shanghai Time Chemicals CO., Ltd.	55
career henan chemical co	58
Shanghai Arbor Chemical Co., Ltd.	58
Hubei Jusheng Technology Co.,Ltd.	58

View Lastest Price from (1S,2S)-(+)-1,2-Diaminocyclohexane manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-11-01	(1S,2S)-(+)-1,2-Diaminocyclohexane 21436-03-3	US $13.00-119.00 / g	5g	0.99	25kg	Shanghai UCHEM Inc.
2022-01-27	(1S,2S)-(+)-1,2-Diaminocyclohexane 21436-03-3	US $0.00 / KG	1KG	98.9%	100 tons	Honest Joy Holdings Limited
2021-07-02	(1S,2S)-(+)-1,2-Diaminocyclohexane 21436-03-3	US $15.00-10.00 / KG	1KG	99%+ HPLC	Monthly supply of 1 ton	Zhuozhou Wenxi import and Export Co., Ltd

(1S,2S)-(+)-1,2-Diaminocyclohexane
21436-03-3
US $13.00-119.00 / g
0.99
Shanghai UCHEM Inc.

(1S,2S)-(+)-1,2-Diaminocyclohexane
21436-03-3
US $0.00 / KG
98.9%
Honest Joy Holdings Limited

(1S,2S)-(+)-1,2-Diaminocyclohexane
21436-03-3
US $15.00-10.00 / KG
99%+ HPLC
Zhuozhou Wenxi import and Export Co., Ltd

(1S,2S)-(+)-1,2-Diaminocyclohexane Spectrum

(1S,2S)-(+)-1,2-Diaminocyclohexane(21436-03-3)¹HNMR (1S,2S)-(+)-1,2-Diaminocyclohexane(21436-03-3)IR (1S,2S)-(+)-1,2-Diaminocyclohexane(21436-03-3)Raman

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trans,trans-2,4-Undecadienal 1,4-CYCLOHEXANEDIAMINE trans-1,4-Diaminocyclohexane (+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

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(1S,2S)-Cyclohexane-1,2-Diamin (1S,2S)-(+)-1,2-Diaminocyclohexane,99%(S,S)-DACH (1S,2S)-(+)-1,2-DIAMINOCYCLOHEXANE (S,S)-DACH (1S,2S)-(+)-1,2-DIAMINOCYCLOHEXANE 98% S-DACH (+)-(S,S)-1,2-DIAMINOCYCLOHEXANE (S,S)-(+)-1,2-DIAMINOCYCLOHEXANE SS-DAC (+)-(S,S)-DACH (S,S)-DACH SS-DIAMINOCYCLOHEXANE (1S,2S)-(+)-1,2-DIAMINOCYCLOHEXANE (1S,2S)-(+)-1,2-CYCLOHEXANEDIAMINE (1S)-(+)-TRANS-1,2-DIAMINOCYCLOHEXANE (1S)-TRANS-1,2-DIAMINOCYCLOHEXANE (1S)-TRANS-1,2-CYCLOHEXANEDIAMINE (1S)-trans-1,2-Cyclohexanediamine, (1S)-trans-1,2-Diaminocyclohexane (1S,2S)-(+)-1,2-Diaminocyclohexane,98% 1,2-Cyclohexanediamine, (1S,2S)- (1S,2S)-(+)-1,2-Diam javascript:showMsgDetail (1S,2S)-(-)-1,3-DiaMinocyclohexane (1S,2S)-(+)-1,2-DiaMinocyclohexane, 98% 250MG (1S,2S)-(+)-1,2-CyclohexanediaMine (1S,2S)-1,2-Diaminocyclohexane,99%e.e. (1S,2S)-(+)-1,2-Diaminocyclohexane (Oxaliplatin) (1S,2S)-(+)-1,2-DiaminocycL (1S,2S)-(+)-1,2-Cyclohexanediamine > (1S,2S)-(+)-1,2-Diaminocyclohexane, 98%, for synthesis best offer (1S,2S)-(+)-1,2-Diaminocyclohexane (S,S)-1,2-DIAMINOCYCLOHEXANE (1S,2S)-1,2-DIAMINOCYCLOHEXANE (1S,2S)-CYCLOHEXANE-1,2-DIAMINE trans-Cyclohexane-1,2-diamine 1S,2S-Diaminocyclohexane (+)-trans-1,2-Diaminocyclohexane 21436-03-3 Amines (Chiral) Chiral Building Blocks Asymmetric Synthesis Organic Building Blocks Polyamines Chiral Nitrogen DACH&Trost Series organic amine Amines (Chiral) Chiral Building Blocks Synthetic Organic Chemistry Chiral Compound chiral API intermediates Chiral reagent