ChemicalBook >> CAS DataBase List >>(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)

(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)

CAS No.
172138-95-3
Chemical Name:
(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE)
Synonyms
(S,S)-DACH-pyridyl Trost ligand;(S,S)-DACH-pyridyl Trost ligand 95%;2,6-Bis[(4S)-benzyl-2-oxazolin-2-yl]-pyridine;N,N'-((1S,2S)-Cyclohexane-1,2-diyl)dipicolinaMide;(1S,2S)-1,2-Bis(2-pyridinecarboxamido)cyclohexane;N,N'-((1S,2S)-Cyclohexane-1,2-diyl)dipicolinamide;N-((1S,2S)-2-(picolinamido)cyclohexyl)picolinamide;(1R,2R)-(-)-1,2-Bis[(2-pyridinylcarbonyl)amino]cyclohexane;2-Pyridinecarboxamide, N,N'-(1S,2S)-1,2-cyclohexanediylbis-;1S,2S- N,N’-1,2-Diaminocyclohexanediylbis (2-pyridinecarboxamide)
CBNumber:
CB1119961
Molecular Formula:
C18H20N4O2
Molecular Weight:
324.38
MDL Number:
MFCD02684544
MOL File:
172138-95-3.mol
Last updated:2023-04-23 13:52:06

(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Properties

Melting point 170°C
Boiling point 663.4±50.0 °C(Predicted)
alpha +95° (c 1, CH3OH)
Density 1.25±0.1 g/cm3(Predicted)
storage temp. Inert atmosphere,2-8°C
pka 12.51±0.40(Predicted)
form Powder
color off-white
CAS DataBase Reference 172138-95-3

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P305+P351+P338
Hazard Codes  Xn
Risk Statements  36/37/38-22
Safety Statements  26-36/37/39-36/37
WGK Germany  3

(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 07-0341 (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98% (S,S)-DACH-Pyridyl Trost Ligand 172138-95-3 1g $108 2024-03-01 Buy
Strem Chemicals 07-0341 (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98% (S,S)-DACH-Pyridyl Trost Ligand 172138-95-3 5g $427 2024-03-01 Buy
Biosynth Carbosynth FD149625 (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide) 172138-95-3 10g $522 2021-12-16 Buy
American Custom Chemicals Corporation CHM0004350 (+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLO HEXANEDIYL BIS(2-PYRIDINE CARBOXAMIDE) 95.00% 172138-95-3 100MG $638.87 2021-12-16 Buy
Biosynth Carbosynth FD149625 (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide) 172138-95-3 25g $1043.75 2021-12-16 Buy
Product number Packaging Price Buy
07-0341 1g $108 Buy
07-0341 5g $427 Buy
FD149625 10g $522 Buy
CHM0004350 100MG $638.87 Buy
FD149625 25g $1043.75 Buy

(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Chemical Properties,Uses,Production

Reactions

  1. Ligands for Mo catalyzed asymmetric allylic substitutions. Especially useful for the synthesis of tertiary and quaternary stereocenters. Exclusive license for this technology acquired by ChiroTech and is protected by pending Stanford University patents.
  2. Dynamic kinetic asymmetric formation of tertiary and quaternary stereogenic centers
Reactions of 172138-95-3

Uses

Trost Ligands for Asymmetric Allylic Alkylation

(+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 49)Suppliers
Supplier Tel Email Country ProdList Advantage
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28172 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63687 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49374 58
Richest Group Ltd
18017061086 oled@richest-group.com CHINA 5600 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 11737 58
Shaoxin Catsyn Co., Ltd.
+undefined-0575-82040869 +86-0575-82040869; sales@catsyn.com China 6114 58
Aladdin Scientific
+1-+1(833)-552-7181 sales@aladdinsci.com United States 52924 58
Amadis Chemical Company Limited
571-89925085 sales@amadischem.com China 131957 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 021-61259108 18621169109 market03@meryer.com China 40228 62
1S,2S- N,N’-1,2-Diaminocyclohexanediylbis (2-pyridinecarboxamide) 2,6-Bis[(4S)-benzyl-2-oxazolin-2-yl]-pyridine (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),min.98% (+)-N,N''-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE), MIN. 98% N-((1S,2S)-2-(picolinamido)cyclohexyl)picolinamide (1S,2S)-N,Nμ-1,2-Cyclohexanediylbis(2-pyridinecarboxamide), (+)-N,Nμ-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), (1S,2S)-(+)-1,2-Bis[(2-pyridinylcarbonyl)amino]cyclohexane, (1S,2S)-1,2-Bis(2-pyridinecarboxamido)cyclohexane (S,S)-DACH-pyridyl Trost ligand (1R,2R)-(-)-1,2-Bis[(2-pyridinylcarbonyl)amino]cyclohexane (1R,2R)-N,Nμ-1,2-Cyclohexanediylbis(2-pyridinecarboxamide), (1R,2R)-1,2-Bis(2-pyridinecarboxamido)cyclohexane N,N'-((1S,2S)-Cyclohexane-1,2-diyl)dipicolinaMide (S,S)-DACH-pyridyl Trost ligand 95% (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),98% (1S,2S)-N,N'-1,2-Diaminocyclohexanediylbis(2- pyridinecarboxamide),99%e.e. (+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE),MIN.98%(S,S)-DACH-PYRIDYLTROSTLIGAND (+)-N,N'-(1S,2S)-1,2-DIAMINOCYCLOHEXANEDIYLBIS(2-PYRIDINECARBOXAMIDE) (1S,2S)-1,2-Bis(2-pyridinecarboxamido)cyclohexane (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide), min. 98% (S,S)-DACH-Pyridyl Trost Ligand N-[(1S,2S)-2-(pyridine-2-carbonylamino)cyclohexyl]pyridine-2-carboxamide 2-Pyridinecarboxamide, N,N'-(1S,2S)-1,2-cyclohexanediylbis- (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide) (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),98% N,N'-((1S,2S)-Cyclohexane-1,2-diyl)dipicolinamide (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide) (+)-N,N'-(1S,2S)-1,2-Diaminocyclohexanediylbis(2-pyridinecarboxamide),98% 172138-95-3 C18H20N4O2 Chiral Nitrogen DACH&Trost Series