trans-1,4-Diaminocyclohexane
- CAS No.
- 2615-25-0
- Chemical Name:
- trans-1,4-Diaminocyclohexane
- Synonyms
- (1r,4r)-cyclohexane-1,4-diaMine;1,4-Cyclohexanediamine;TRANS-1,4-CYCLOHEXANEDIAMINE;cas:2615-25-0;TIMTEC-BB SBB008553;Trans 1,4-Diaminocyc;1,4-CyclohexyldiaMine(CHDA);TRANS-1,4-CYCLOHEXYLDIAMINE;rans-1,4-Diaminocyclohexane;TRANS-1,4-DIAMINOCYCLOHEXANE
- CBNumber:
- CB6702524
- Molecular Formula:
- C6H14N2
- Molecular Weight:
- 114.19
- MDL Number:
- MFCD00075174
- MOL File:
- 2615-25-0.mol
- MSDS File:
- SDS
Melting point | 67-72 °C |
---|---|
Boiling point | 197 °C(lit.) |
Density | 0.939±0.06 g/cm3(Predicted) |
vapor pressure | 18 mm Hg ( 87.2 °C) |
Flash point | 71 °C |
storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
solubility | soluble in Methanol |
pka | 10.78±0.70(Predicted) |
form | Crystals or Chunks |
color | Off-white to brown |
explosive limit | 6% |
BRN | 2801657 |
InChI | InChI=1S/C6H14N2/c7-5-1-2-6(8)4-3-5/h5-6H,1-4,7-8H2/t5-,6- |
InChIKey | VKIRRGRTJUUZHS-IZLXSQMJSA-N |
SMILES | [C@@H]1(N)CC[C@@H](N)CC1 |
CAS DataBase Reference | 2615-25-0(CAS DataBase Reference) |
EPA Substance Registry System | 1,4-Cyclohexanediamine, trans- (2615-25-0) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() ![]() GHS05,GHS07 |
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Signal word | Danger | |||||||||
Hazard statements | H302-H314 | |||||||||
Precautionary statements | P260-P270-P280-P301+P312-P303+P361+P353-P305+P351+P338 | |||||||||
Hazard Codes | C | |||||||||
Risk Statements | 22-34-20/21/22 | |||||||||
Safety Statements | 26-36/37/39-45 | |||||||||
RIDADR | UN 3259 8/PG 2 | |||||||||
WGK Germany | 2 | |||||||||
F | 10-34 | |||||||||
Autoignition Temperature | 680 °F | |||||||||
HazardClass | 8 | |||||||||
PackingGroup | II | |||||||||
HS Code | 29213000 | |||||||||
NFPA 704 |
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trans-1,4-Diaminocyclohexane price More Price(26)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 32851 | trans-1,4-Diaminocyclohexane ≥98.0% (GC) | 2615-25-0 | 25g | $154 | 2024-03-01 | Buy |
Sigma-Aldrich | 32851 | trans-1,4-Diaminocyclohexane ≥98.0% (GC) | 2615-25-0 | 100g | $214 | 2024-03-01 | Buy |
TCI Chemical | C1426 | trans-1,4-Cyclohexanediamine >98.0%(GC)(T) | 2615-25-0 | 5g | $16 | 2024-03-01 | Buy |
TCI Chemical | C1426 | trans-1,4-Cyclohexanediamine >98.0%(GC)(T) | 2615-25-0 | 25g | $38 | 2024-03-01 | Buy |
TCI Chemical | C1426 | trans-1,4-Cyclohexanediamine >98.0%(GC)(T) | 2615-25-0 | 100g | $112 | 2024-03-01 | Buy |
trans-1,4-Diaminocyclohexane Chemical Properties,Uses,Production
Chemical Properties
off-white to brown crystals or chunks
Uses
trans-1,4-Diaminocyclohexane was used in preparation of fully aliphatic polyimides. It was employed as the structure-directing agent in the synthesis of novel two-dimensional layered zinc phosphate.
Uses
trans-1,4-diaminocyclohexane be used as organic intermediates and epoxy curing agents.
Synthesis
Cyclohexane-1,4-diamine is one of several produced when p-phenylene diamine is hydrogenated on nickel or cobalt catalysts in methylcyclohexane or dioxane or decaline at 180° C./100 or 150 atmospheres. Trans-1,4-Diaminocyclohexane can be obtained from this isomeric mixture by fractional crystallization as described in U.S. Pat. No. 3,657,345, but several crystallizations are required to achieve this.
A process is disclosed for selectively making trans-1,4-Diaminocyclohexane by reacting ammonia with a mixture of cis and trans-cyclohexane-1,4-dicarboxylic acid, a lower alkyl ester, a glycol ester, an oligomeric ester or a polyester to make a solid trans-dicarboxylic acid diamide in a first step. The diamide is chlorinated to form trans-cyclohexane-1,4-dicarboxylic acid-bis-N-chloramide. The latter compound is then converted into a trans-1,4-Diaminocyclohexane with an alkali or alkaline earth metal hydroxide.
Purification Methods
Recrystallise the diamine from pet ether under N2 or Ar as it should be an even stronger base than the above 1,2-diamine isomers. It distils under N2. Store in the dark under N2. [Beistein 13 I 3, 13 III 11.]
trans-1,4-Diaminocyclohexane Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
SUZHOU SENFEIDA CHEMICAL CO.,LTD | +86-0512-83500002 +8615195660023 | sales@senfeida.com | China | 23053 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39916 | 58 |
Beijing Sunsoly S&T Co.,Ltd | +8613910445483 | amanda@sunsoly.com | China | 292 | 58 |
Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29798 | 60 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 16914 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21668 | 55 |
Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
Chembon Pharmaceutical Co., Ltd. | +86-28-8425-2981 | CHINA | 724 | 55 | |
Jiangsu Qingquan Chemical Co., Ltd. | +86-571-86589381,86589382,86589383 | sales1@qqpharm.com | CHINA | 154 | 55 |
ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32760 | 60 |
View Lastest Price from trans-1,4-Diaminocyclohexane manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
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2024-08-15 | trans-1,4-Diaminocyclohexane
2615-25-0
|
US $0.00-0.00 / KG | 0.5KG | 99% | 100kg | Beijing Sunsoly S&T Co.,Ltd | |
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2022-09-15 | Trans-1,4-Diaminocyclohexane
2615-25-0
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. | |
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2022-01-04 | trans-1,4-Diaminocyclohexane
2615-25-0
|
US $0.00-0.00 / KG | 1g | 98%min | 100kgs/month | Shanghai Rlavie Technology Co ltd |
-
- trans-1,4-Diaminocyclohexane
2615-25-0
- US $0.00-0.00 / KG
- 99%
- Beijing Sunsoly S&T Co.,Ltd
-
- Trans-1,4-Diaminocyclohexane
2615-25-0
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- trans-1,4-Diaminocyclohexane
2615-25-0
- US $0.00-0.00 / KG
- 98%min
- Shanghai Rlavie Technology Co ltd
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