ChemicalBook >> CAS DataBase List >>Tetramethylguanidine
Tetramethylguanidine
- CAS No.
- 80-70-6
- Chemical Name:
- Tetramethylguanidine
- Synonyms
- TMG;1,1,3,3-TETRAMETHYLGUANIDINE;TETRAMETHYL GUANIDINE;N,N,N',N'-TETRAMETHYLGUANIDINE;1,1,3,3-Tetramethyl Guanidine (TMG);N,N’-Tetramethylguanidine;N,N-1,1,3,3-TETRAMETHYLGUANIDINE;Guanidine, N,N,N',N'-tetramethyl-;uanidine;TMG)1,1,3,3-TetraMeth
- CBNumber:
- CB0355799
- Molecular Formula:
- C5H13N3
- Molecular Weight:
- 115.18
- MDL Number:
- MFCD00008323
- MOL File:
- 80-70-6.mol
- MSDS File:
- SDS
Last updated:2024-09-13 19:17:58
| Melting point | -30 °C |
|---|---|
| Boiling point | 162-163 °C (lit.) |
| Density | 0.916 g/mL at 20 °C (lit.) |
| vapor pressure | 0.2 mm Hg ( 20 °C) |
| refractive index |
n |
| Flash point | 140 °F |
| storage temp. | Store below +30°C. |
| solubility | Acetonitrile (Slightly), DMSO (Slightly), Methanol (Slightly) |
| pka | 15.20±0.70(Predicted) |
| form | Liquid |
| color | APHA: ≤150 |
| Relative polarity | 5.5 |
| PH | 12.7 (10g/l, H2O, 25℃) |
| Odor | mild ammoniacal odor |
| explosive limit | 1.0-7.5%(V) |
| Water Solubility | miscible |
| Sensitive | Air Sensitive |
| BRN | 969608 |
| Dielectric constant | 23.100000000000001 |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents, mineral and organic acids, carbon dioxide. Air-sensitive. |
| InChIKey | KYVBNYUBXIEUFW-UHFFFAOYSA-N |
| LogP | -0.49 at 20℃ |
| CAS DataBase Reference | 80-70-6(CAS DataBase Reference) |
| FDA UNII | VEZ101E7ZU |
| NIST Chemistry Reference | N,N,N',N'-Tetramethylguanidine(80-70-6) |
| EPA Substance Registry System | Guanidine, N,N,N',N'-tetramethyl- (80-70-6) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H226-H290-H302-H314 | |||||||||
| Precautionary statements | P210-P233-P280-P301+P312-P303+P361+P353-P305+P351+P338 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 22-34-20/22-10 | |||||||||
| Safety Statements | 26-27-36/37/39-45-16 | |||||||||
| RIDADR | UN 2920 8/PG 2 | |||||||||
| WGK Germany | 1 | |||||||||
| F | 9-23 | |||||||||
| Autoignition Temperature | 222 °C | |||||||||
| Hazard Note | Harmful/Corrosive | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29252000 | |||||||||
| Toxicity | LD50 orally in Rabbit: 835 mg/kg | |||||||||
| NFPA 704 |
|
Tetramethylguanidine price More Price(44)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 8.21897 | N,N,N′,N′-Tetramethylguanidine for synthesis | 80-70-6 | 100mL | $84.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.21897 | N,N,N′,N′-Tetramethylguanidine for synthesis | 80-70-6 | 250ML | $185 | 2024-03-01 | Buy |
| Sigma-Aldrich | 241768 | 1,1,3,3-Tetramethylguanidine 99% | 80-70-6 | 5ml | $51.2 | 2024-03-01 | Buy |
| Sigma-Aldrich | 241768 | 1,1,3,3-Tetramethylguanidine 99% | 80-70-6 | 100ml | $78.8 | 2024-03-01 | Buy |
| TCI Chemical | T0148 | 1,1,3,3-Tetramethylguanidine >99.0%(GC)(T) | 80-70-6 | 25mL | $19 | 2024-03-01 | Buy |
Tetramethylguanidine Chemical Properties,Uses,Production
Chemical Properties
N,N,N',N' -Tetramethylguanidine (TMG) [80-70-6], C5H13N3, Mr 115.18, is a stable, unusually strong base, pKa 13.6 (25 ℃), with a free imino group. It is a colorless to light-yellow liquid, miscible with water and common organic solvents: 0.92 g/cm3 (25 ℃), bp 160 ℃, vapor pressure 0.03 kPa (25℃).
Uses
Base employed in the preparation of alkyl nitriles from alkyl halides and 3′-alkylthymidines from 3′-nitrothymidines.
Uses
1,1,3,3-Tetaramethylguanidine is used as a strong, non-nucleophilic base for alkylations in organic synthesis. 1,1,3,3-Tetramethylguanidine is an efficient and selective catalyst for the benzoylation of alcohols.
Uses
Tetramethylguanidine (TMG) is used as polyurethane foam catalyst, as accelerator for the syntheses of polysulfured rubber, as a strong base in the photochemical (e.g. couplers) and in the pharmaceutical (e.g. steroids) industries. Product Data Sheet
Flammability and Explosibility
Flammable
Synthesis
Prepared from cyanogen chloride and dimethylamine in a 1 : 2 molar ratio, TMG is used as a polyurethane foam catalyst, in the preparation of pigments for color photography, and in steroid synthesis.
Purification Methods
Reflux it over granulated BaO, then fractionally distil it. Protect it from CO2. [Beilstein 4 IV 227.]
Tetramethylguanidine Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 537)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12837 | 58 |
| Hebei Kingfiner Technology Development Co.Ltd | +86-15532196582 +86-15373005021 | lisa@kingfinertech.com | China | 2990 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20288 | 58 |
| airuikechemical co., ltd. | +undefined86-15315557071 | sales02@sdzhonghuimaterial.com | China | 983 | 58 |
| Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 | admin@zlchemi.com | China | 3002 | 58 |
| Hebei Mojin Biotechnology Co.,Ltd | +86-15028179902 | angelia@hbmojin.com | China | 1179 | 58 |
| HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD | +86-15350851019 +86-15383190639 | admin@86-ss.com | China | 1000 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21639 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
View Lastest Price from Tetramethylguanidine manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-11-03 | Tetramethylguanidine
80-70-6
|
US $999.00-666.00 / ton | 1ton | 99% | 5000 | HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD | |
 |
2024-11-01 | Tetramethylguanidine
80-70-6
|
US $45.00 / kg | 1kg | 99% | 5000kg/week | Hebei Zhuanglai Chemical Trading Co.,Ltd | |
 |
2024-11-01 | Tetramethylguanidine
80-70-6
|
US $0.00 / Kg/Drum | 1KG | 99% | 2000mt/year | Jinan Finer Chemical Co., Ltd |
-
- Tetramethylguanidine
80-70-6
- US $999.00-666.00 / ton
- 99%
- HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
-
- Tetramethylguanidine
80-70-6
- US $45.00 / kg
- 99%
- Hebei Zhuanglai Chemical Trading Co.,Ltd
-
- Tetramethylguanidine
80-70-6
- US $0.00 / Kg/Drum
- 99%
- Jinan Finer Chemical Co., Ltd
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1,1,3,3-Tetramethylguanidine,99%
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Guanidine, 1,1,3,3-tetramethyl-
n,n,n’,n’-tetramethyl-guanidin
N1,N1,N3,N3-Tetramethylguanidine
N,N,N',N'-Tetramethyl-α-iminomethanediamine
α,α-Bis(dimethylamino)methanimine
1,1,3,3-TetraMethylguanidine, 99% 100GR
1,1,3,3-TetraMethylguanidine, 99% 5GR
TetraMethylguanidine(TMG)
TetraMethylguanidine,1,1,3,3-TetraMethylguanidine
TMG)1,1,3,3-TetraMeth
TMG
N,N,N',N'-Tetramethylguanidine
1,1,3 tetramethyl guanidine
1,1,3,3-Tertamethylguanidine=TMG
uanidine
1,1,3,3-Tetramethylguanidine >
N,N,N',N'-TETRAMETHYLGUANIDINE FOR SYNTH
TMG
1,1,3,3-Tetramethyl Guanidine
1,1,3,3-Tetramethylguanidine extrapure AR, 99%
1,1,3,3-Tetramethyl Guanidine (TMG)
TMG
N,N-1,1,3,3-TETRAMETHYLGUANIDINE
N,N,N',N'-TETRAMETHYLGUANIDINE
TETRAMETHYL GUANIDINE
1,1,3,3-TETRAMETHYLGUANIDINE
N,N’-Tetramethylguanidine
Guanidine, N,N,N',N'-tetramethyl-
N,N,N',N'-tetramethylguanidine
80-70-6
CH32NCNHNCH32
Organic Building Blocks
Nitrogen Compounds
Guanidines
Building Blocks
Various hydrocyanic acid derivatives
Glycosylating Reagents
Bioactive Small Molecules
Building Blocks
Carbohydrate Chemistry
Cell Biology
Chemical Biology
Chemical Synthesis
Guanidines
Nitrogen Compounds
Organic Building Blocks
T
Hydrocyanic acid derivatives
Antidote / Antibiotic / Antimicrobial
80-70-6