ChemicalBook >> CAS DataBase List >>3-Bromobenzoic acid
3-Bromobenzoic acid
- CAS No.
- 585-76-2
- Chemical Name:
- 3-Bromobenzoic acid
- Synonyms
- QVR CE;NSC 83519;Brombenzoesaure;Brombenzoicacid;3-BROMBENZOIC ACID;3-bromo-benzoicaci;M-BROMOBENZOIC ACID;3-BroMobenzoic aicd;3-BROMOBENZOIC ACID;RARECHEM AL BO 0037
- CBNumber:
- CB0441823
- Molecular Formula:
- C7H5BrO2
- Molecular Weight:
- 201.02
- MDL Number:
- MFCD00002487
- MOL File:
- 585-76-2.mol
- MSDS File:
- SDS
Last updated:2024-06-05 15:33:49
| Melting point | 155-158 °C(lit.) |
|---|---|
| Boiling point | >280 °C |
| Density | 1,948 g/cm3 |
| refractive index | 1.6080 (estimate) |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | methanol: soluble50mg/mL, clear, colorless |
| pka | 3.86(at 25℃) |
| form | Powder |
| color | White to light beige |
| Water Solubility | 0.54 g/L (32 ºC) |
| BRN | 2041792 |
| InChIKey | VOIZNVUXCQLQHS-UHFFFAOYSA-N |
| CAS DataBase Reference | 585-76-2(CAS DataBase Reference) |
| FDA UNII | 7DCT3A73LX |
| NIST Chemistry Reference | Benzoic acid, 3-bromo-(585-76-2) |
| EPA Substance Registry System | m-Bromobenzoic acid (585-76-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38-37/38-36 | |||||||||
| Safety Statements | 26-36-37/39 | |||||||||
| WGK Germany | 3 | |||||||||
| Hazard Note | Irritant | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29163990 | |||||||||
| NFPA 704 |
|
3-Bromobenzoic acid price More Price(46)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 186295 | 3-Bromobenzoic acid 98% | 585-76-2 | 25g | $64.4 | 2024-03-01 | Buy |
| TCI Chemical | B0551 | 3-Bromobenzoic Acid >98.0%(GC)(T) | 585-76-2 | 25g | $57 | 2024-03-01 | Buy |
| TCI Chemical | B0551 | 3-Bromobenzoic Acid >98.0%(GC)(T) | 585-76-2 | 250g | $317 | 2024-03-01 | Buy |
| Alfa Aesar | A12606 | 3-Bromobenzoic acid, 98+% | 585-76-2 | 25g | $52.65 | 2024-03-01 | Buy |
| Alfa Aesar | A12606 | 3-Bromobenzoic acid, 98+% | 585-76-2 | 100g | $186.65 | 2024-03-01 | Buy |
3-Bromobenzoic acid Chemical Properties,Uses,Production
Chemical Properties
white to light yellow crystal powder. soluble in alcohols and ethers, insoluble in water.Used as organic synthesis reagent.
Uses
3-Bromobenzoic acid was used as test solute in the determination of acidity constants by capillary zone electrophoresis. It was used as internal standard to study the retention mechanisms of an unmodified and a hydroxylated polystyrene-divinylbenzene polymer by solid-phase extraction. It was also used in synthesis of N-(1,1-dimethyl-2-hydroxyethyl)-3-bromobenzamide.
Preparation
3-Bromobenzoic acid is synthesized from 3-bromotoluene by oxidation of potassium permanganate. Mix m-bromotoluene, potassium hydroxide and water, heat to boiling, slowly add potassium permanganate, and reflux for 4 hours after adding. After acidification by filtration, the crude product was obtained by filtration. Then it is dissolved in ethanol with ammonia water, acidified with hydrochloric acid, filtered and washed with water to obtain 3-bromobenzoic acid.
Definition
ChEBI: 3-bromobenzoic acid is a bromobenzoic acid carrying a single bromo subsituent at the 3-position.
Synthesis Reference(s)
The Journal of Organic Chemistry, 15, p. 481, 1950 DOI: 10.1021/jo01149a007
Purification Methods
Crystallise the acid from acetone/water, MeOH or acetic acid. The anilide has m 137o (from EtOH/H2O). [Beilstein 9 IV 1013.]
3-Bromobenzoic acid Preparation Products And Raw materials
Raw materials
Preparation Products
3-PYRIDIN-4-YL-BENZOIC ACID
3-BROMO-2-((CYCLOPROPYLAMINO)METHYL)BENZALDEHYDE
6-BROMOISOBENZOFURAN-1(3H)-ONE
5-Bromo-2-iodobenzoic acid
ETHYL 3-BROMOBENZOATE
3-Bromobenzaldehyde
3-BROMO-4'-CHLOROBENZOPHENONE
3-(4-FLUOROPHENYL)BENZOIC ACID
3-(1H-IMIDAZOL-1-YL)BENZOIC ACID
3-(1-(TERT-BUTOXYCARBONYL)PIPERIDIN-4-YL)BENZOIC ACID
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Global( 428)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52849 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +86 13288715578 +8613288715578 | sales@hbmojin.com | China | 12840 | 58 |
| Zibo Hangyu Biotechnology Development Co., Ltd | +86-0533-2185556 +8617865335152 | Mandy@hangyubiotech.com | China | 10986 | 58 |
| Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 | admin@zlchemi.com | China | 3002 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18779 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32957 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29884 | 58 |
View Lastest Price from 3-Bromobenzoic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-11-22 | 3-Bromobenzoic acid
585-76-2
|
US $180.00 / kg | 1kg | 99% | 20ton | Hebei Zhuanglai Chemical Trading Co.,Ltd | |
 |
2024-08-27 | 3-Bromobenzoic acid
585-76-2
|
US $80.00-800.00 / kg | 10kg | 0.99 | 20tons | Zibo Hangyu Biotechnology Development Co., Ltd | |
 |
2023-10-21 | 3-Bromobenzoic acid
585-76-2
|
US $6.62 / g | 10g | 99% | 100kg | Wuhan Han Sheng New Material Technology Co.，Ltd |
-
- 3-Bromobenzoic acid
585-76-2
- US $180.00 / kg
- 99%
- Hebei Zhuanglai Chemical Trading Co.,Ltd
-
- 3-Bromobenzoic acid
585-76-2
- US $80.00-800.00 / kg
- 0.99
- Zibo Hangyu Biotechnology Development Co., Ltd
-
- 3-Bromobenzoic acid
585-76-2
- US $6.62 / g
- 99%
- Wuhan Han Sheng New Material Technology Co.，Ltd
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3-Bromobenzoic acid CAS NO.585-76-2
585-76-2
586-72-2
C7H5BrO2
Carbonyl Compounds
Carboxylic Acids
C7
Building Blocks
Organic Building Blocks
Building Blocks
Carbonyl Compounds
Carboxylic Acids
Chemical Synthesis
Organic Building Blocks
alkyl bromide| carboxylic acid
Carboxylic Acids
blocks
Carboxes
Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts
BenzoicAcidDerivative
Benzoic acid
Acids & Esters
Bromine Compounds
C7
Carbonyl Compounds
bc0001