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Triphenylene

CAS No.
217-59-4
Chemical Name:
Triphenylene
Synonyms
ISOCHRYSENE;Triphenylene,98%;9,10-Benzphenanthrene;riphenylene;TRIPHENYLENE;Triphenylene 98%;Triphenylene >benzo(l)phenathrene;benzo[e]phenanthrene;benzo(1)phenanthrene
CBNumber:
CB0452742
Molecular Formula:
C18H12
Molecular Weight:
228.29
MDL Number:
MFCD00001108
MOL File:
217-59-4.mol
MSDS File:
SDS
Last updated:2024-01-02 16:51:54

Triphenylene Properties

Melting point 195-198 °C(lit.)
Boiling point 438 °C(lit.)
Density 1.302
refractive index 1.5500 (estimate)
Flash point 438°C
storage temp. Sealed in dry,Room Temperature
solubility Soluble in ethanol, benzene, acetic acid, oils and chloroform.
form Crystalline Needles
color White to beige
Water Solubility 6.6ug/L(25.00 ºC)
λmax 335nm(Hexane)(lit.)
Merck 14,9740
BRN 1342908
InChIKey SLGBZMMZGDRARJ-UHFFFAOYSA-N
CAS DataBase Reference 217-59-4(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 18WX3373I0
NIST Chemistry Reference Triphenylene(217-59-4)
IARC 3 (Vol. Sup 7, 92) 2010
EPA Substance Registry System Triphenylene (217-59-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS09
Signal word  Danger
Hazard statements  H318-H410
Precautionary statements  P273-P280-P305+P351+P338-P391-P501
Hazard Codes  Xi,N
Risk Statements  41-50/53
Safety Statements  22-24/25-61-60-39-26
RIDADR  UN 3077 9/PG 3
WGK Germany  3
RTECS  YK2925000
HazardClass  9
PackingGroup 
HS Code  29029090
NFPA 704
1
3 0

Triphenylene price More Price(39)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich BCR270 Triphenylene BCR 217-59-4 20mg $434 2024-03-01 Buy
Sigma-Aldrich 45804 Triphenylene analytical standard 217-59-4 100mg $63.7 2022-05-15 Buy
TCI Chemical T0513 Triphenylene >96.0%(GC) 217-59-4 100mg $16 2024-03-01 Buy
TCI Chemical T0513 Triphenylene >96.0%(GC) 217-59-4 1g $30 2024-03-01 Buy
Alfa Aesar L00955 Triphenylene, 98% 217-59-4 1g $66.65 2024-03-01 Buy
Product number Packaging Price Buy
BCR270 20mg $434 Buy
45804 100mg $63.7 Buy
T0513 100mg $16 Buy
T0513 1g $30 Buy
L00955 1g $66.65 Buy

Triphenylene Chemical Properties,Uses,Production

Chemical Properties

white to beige crystalline needles

Uses

Triphenylene is a polycyclic aromatic hydrocarbon (PAH) that can be isolated from coal tar. Triphenylene emits fluorescence in the ultraviolet region and is a useful compound for developing semiconductor devices.

Definition

ChEBI: Triphenylene is an ortho-fused polycyclic arene consisting of four fused benzene rings.

Application

Triphenylene is an important basic skeleton monomer of polycyclic aromatic hydrocarbons. It can be used to synthesize macromolecular compounds with multi-conjugated structure, and is widely used in the research of organic supramolecular materials.Triphenylene is used in optics and electronics. It is also used as a discotic mesogen in liquid crystalline materials. Further, it is a compound that fluoresces in the ultraviolet region. In addition to this, it is used in the preparation of triphenylene-2-carbaldehyde.

Preparation

Triphenylene synthesis: 2-Chlorobenzoic acid(78mg, 0.5mmol), iodonium salt (236mg, 0.55mmol), palladium acetate (2.8mg, 0.0125mmol), potassium carbonate (152mg, 1.1mmol) were dissolved in 3mL of NMP solvent was heated to 110 °C and stirred for 17 hours, cooled to room temperature, extracted with ethyl acetate, washed with saturated sodium chloride solution, dried over anhydrous sodium sulfate, filtered, concentrated, and subjected to column chromatography to obtain 92 mg of triphenylene as a white solid, The yield was 80%.

Synthesis Reference(s)

Synthesis, p. 756, 1992 DOI: 10.1055/s-1992-26218

General Description

Triphenylene belongs to the class of polycyclic aromatic hydrocarbons, which is commonly employed as a substrate for use as a precursor for the synthesis of graphenes, carbon nanotubes, buckminsterfullerenes as well as polycyclic heteroaromatics.

Purification Methods

Purify triphenylene by zone refining or crystallisation from EtOH or CHCl3 and sublime. [Beilstein 5 IV 2556.]

1610-39-5
217-59-4
Synthesis of Triphenylene from Dodecahydrotriphenylene
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View Lastest Price from Triphenylene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Triphenylene pictures 2024-11-01 Triphenylene
217-59-4
US $20.00-404.00 / g 25g 0.98 25kg Shanghai UCHEM Inc.
Triphenylene pictures 2023-11-09 Triphenylene
217-59-4
US $0.00-0.00 / kg 1kg 99.9% 30000 Kg Hebei Xinsheng New Material Technology Co., LTD.
Triphenylene pictures 2023-09-26 Triphenylene
217-59-4
US $35.00-25.00 / kg 1kg 99% 20 Ton Hebei Xinsheng New Material Technology Co., LTD.
  • Triphenylene pictures
  • Triphenylene
    217-59-4
  • US $20.00-404.00 / g
  • 0.98
  • Shanghai UCHEM Inc.
  • Triphenylene pictures
  • Triphenylene
    217-59-4
  • US $0.00-0.00 / kg
  • 99.9%
  • Hebei Xinsheng New Material Technology Co., LTD.
  • Triphenylene pictures
  • Triphenylene
    217-59-4
  • US $35.00-25.00 / kg
  • 99%
  • Hebei Xinsheng New Material Technology Co., LTD.
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