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Methanesulfonic anhydride

CAS No.
7143-01-3
Chemical Name:
Methanesulfonic anhydride
Synonyms
7143/1/3;methylsulfonyl methanesulfonate;Mesic anhydride;Mesyl anhydride;METHANESULPHONIC ANHYDRIDE;Methanesulfonyl anhydride;Methanesulfonic acid, anhydride;methanesulfonyl methanesulfonate;SKL265;7143-01-3-
CBNumber:
CB1109276
Molecular Formula:
C2H6O5S2
Molecular Weight:
174.19
MDL Number:
MFCD00007556
MOL File:
7143-01-3.mol
MSDS File:
SDS
Last updated:2024-05-13 09:33:23

Methanesulfonic anhydride Properties

Melting point 64-67 °C (lit.)
Boiling point 125 °C/4 mmHg (lit.)
Density 1,36 g/cm3
vapor density 3.3 (vs air)
refractive index 1.5300 (estimate)
Flash point 125°C/4mm
storage temp. Store at <= 20°C.
solubility Soluble in organic solvents.
form Powder, Crystals and/or Chunks
color White to light brown to gray
Sensitive Moisture Sensitive
BRN 972316
InChIKey IZDROVVXIHRYMH-UHFFFAOYSA-N
CAS DataBase Reference 7143-01-3(CAS DataBase Reference)
FDA UNII J492U7J4PB
NIST Chemistry Reference Methanesulfonic anhydride(7143-01-3)
EPA Substance Registry System Methanesulfonic acid, anhydride (7143-01-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C
Risk Statements  14-35
Safety Statements  26-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
3-10
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29041000
NFPA 704
1
3 2
W

Methanesulfonic anhydride price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 269190 Methanesulfonic anhydride 97% 7143-01-3 5g $29.8 2024-03-01 Buy
Sigma-Aldrich 269190 Methanesulfonic anhydride 97% 7143-01-3 25g $85.7 2024-03-01 Buy
Alfa Aesar A13328 Methanesulfonic anhydride, 98% 7143-01-3 10g $32.65 2024-03-01 Buy
Alfa Aesar A13328 Methanesulfonic anhydride, 98% 7143-01-3 25g $69.65 2024-03-01 Buy
Alfa Aesar A13328 Methanesulfonic anhydride, 98% 7143-01-3 50g $136 2024-03-01 Buy
Product number Packaging Price Buy
269190 5g $29.8 Buy
269190 25g $85.7 Buy
A13328 10g $32.65 Buy
A13328 25g $69.65 Buy
A13328 50g $136 Buy

Methanesulfonic anhydride Chemical Properties,Uses,Production

Chemical Properties

white to light brown to grey powder, crystals and/

Uses

Methanesulfonic anhydride is used to prepare methylsulfonyl esters called as mesylates. It finds application in the reaction of aromatic alkylation. It reacts with dimethylsulfoxide to get sulfoxonium complex, which is a useful oxidizing agent.

Preparation

Methanesulfonic anhydride may be prepared by the dehydration of methanesulfonic acid with phosphorus pentoxide.
P2O5 + 6 CH3SO3H → 3 (CH3SO2)2O + 2 H3PO4
Methanesulfonic anhydride can be purified by distillation under vacuum (distillation of a solid) or by recrystallized from Methyl tert-butyl ether/toluene.

Safety

Not only is Methanesulfonic anhydride corrosive, posing potential risks to skin, eyes, and mucous membranes, but it is also sensitive to moisture. As a hygroscopic substance, exposure to water can lead to degradation, compromising its efficacy and safety. Therefore, meticulous storage conditions are paramount to ensure the stability of the compound. To safeguard the integrity of methanesulfonic anhydride, storing it in a cool and dry environment is recommended. The storage facility should be adequately ventilated to prevent the accumulation of vapors and maintain optimal conditions for the compound. Furthermore, the storage containers must be tightly sealed to prevent moisture ingress and subsequent degradation.

34557-54-5
75-75-2
7143-01-3
Synthesis of Methanesulfonic anhydride from Methane, ion(2+)
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View Lastest Price from Methanesulfonic anhydride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Methanesulfonic anhydride pictures 2024-01-18 Methanesulfonic anhydride
7143-01-3
US $6.00-0.60 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Methanesulfonic anhydride pictures 2023-08-29 Methanesulfonic anhydride
7143-01-3
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Methanesulfonic anhydride pictures 2021-08-12 Methanesulfonic anhydride
7143-01-3
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
METHANESULFONIC ANHYDRIDE METHYLSULFONIC ANHYDRIDE methanesulfonicacid,anhydride Methanesulfonic anhydride, 98+% Methanesulfonicanhydride,2Msoln.indichloromethane Methanesulphonicanhydride,98% METHANESULFONIC ANHYDRIDE, 2M SOL. IN DICHLOROMETHANE Bis(methanesulfonic)anhydride METHANE SULPHONIC ANHYDRIED Bismethanesulfonic anhydride Methanesulfonic anhydride,97% Methanesulphonic anhydride, 2M soln. in dichloromethane Methanesulfonic anhy Methanesulfonic anhydride, 97% 100GR Methanesulfonic anhydride, 97% 25GR Methanesulfonic acid, 1,1'-anhydride Methanesulfoneic Anhydride Methane Sulphonic Anhydride (MSA) Methanesulfonic anhydride 97% METHANESULFONIC ANHYDRIDE FOR SYNTHESIS fonic acid, 1,1'-anhydride Methanesulfonic anhydride, 98%, for synthesis Methanesulfonic anhydride ISO 9001:2015 REACH Elagolix Impurity 34 SKL265 Methane Sulphonic Anhydride pure METHANESULPHONIC ANHYDRIDE Mesyl anhydride Methanesulfonic acid, anhydride Mesic anhydride methylsulfonyl methanesulfonate 7143/1/3 methanesulfonyl methanesulfonate Methanesulfonyl anhydride 7143-01-3- Methanesulfonic anhydride (6CI, 7CI, 8CI) 7143-01-3 1914970 7143-1-3 7134-01-3 43-01-3 1914-97-0 7141-01-3 C2H6O5S2 CH3SO22O Organic Building Blocks Sulfonic/Sulfinic Acid Anhydrides Sulfur Compounds Building Blocks Organic Building Blocks Sulfonic/Sulfinic Acid Anhydrides Sulfur Compounds bc0001