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Methanesulfonic anhydride

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CAS:7143-01-3
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Methanesulfonic anhydride Basic information
Product Name:Methanesulfonic anhydride
Synonyms:METHANESULFONIC ANHYDRIDE;METHYLSULFONIC ANHYDRIDE;methanesulfonicacid,anhydride;Methanesulfonic anhydride, 98+%;Methanesulfonicanhydride,2Msoln.indichloromethane;Methanesulphonicanhydride,98%;METHANESULFONIC ANHYDRIDE, 2M SOL. IN DICHLOROMETHANE;Bis(methanesulfonic)anhydride
CAS:7143-01-3
MF:C2H6O5S2
MW:174.19
EINECS:230-442-1
Product Categories:Organic Building Blocks;Sulfonic/Sulfinic Acid Anhydrides;Sulfur Compounds;bc0001
Mol File:7143-01-3.mol
Methanesulfonic anhydride Structure
Methanesulfonic anhydride Chemical Properties
Melting point 64-67 °C (lit.)
Boiling point 125 °C/4 mmHg (lit.)
density 1,36 g/cm3
vapor density 3.3 (vs air)
refractive index 1.5300 (estimate)
Fp 125°C/4mm
storage temp. Store at <= 20°C.
solubility Soluble in organic solvents.
form Powder, Crystals and/or Chunks
color White to light brown to gray
Sensitive Moisture Sensitive
BRN 972316
InChIKeyIZDROVVXIHRYMH-UHFFFAOYSA-N
CAS DataBase Reference7143-01-3(CAS DataBase Reference)
NIST Chemistry ReferenceMethanesulfonic anhydride(7143-01-3)
EPA Substance Registry SystemMethanesulfonic acid, anhydride (7143-01-3)
Safety Information
Hazard Codes C
Risk Statements 14-35
Safety Statements 26-36/37/39-45
RIDADR UN 3261 8/PG 2
WGK Germany 3
3-10
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29041000
MSDS Information
ProviderLanguage
Methanesulfonic anhydride English
SigmaAldrich English
ALFA English
Methanesulfonic anhydride Usage And Synthesis
Chemical Propertieswhite to light brown to grey powder, crystals and/
UsesMethanesulfonic anhydride is used to prepare methylsulfonyl esters called as mesylates. It finds application in the reaction of aromatic alkylation. It reacts with dimethylsulfoxide to get sulfoxonium complex, which is a useful oxidizing agent.
PreparationMethanesulfonic anhydride may be prepared by the dehydration of methanesulfonic acid with phosphorus pentoxide.
P2O5 + 6 CH3SO3H → 3 (CH3SO2)2O + 2 H3PO4
Methanesulfonic anhydride can be purified by distillation under vacuum (distillation of a solid) or by recrystallized from Methyl tert-butyl ether/toluene.
SafetyNot only is Methanesulfonic anhydride corrosive, posing potential risks to skin, eyes, and mucous membranes, but it is also sensitive to moisture. As a hygroscopic substance, exposure to water can lead to degradation, compromising its efficacy and safety. Therefore, meticulous storage conditions are paramount to ensure the stability of the compound. To safeguard the integrity of methanesulfonic anhydride, storing it in a cool and dry environment is recommended. The storage facility should be adequately ventilated to prevent the accumulation of vapors and maintain optimal conditions for the compound. Furthermore, the storage containers must be tightly sealed to prevent moisture ingress and subsequent degradation.
Tag:Methanesulfonic anhydride(7143-01-3) Related Product Information
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