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fumitremorgin B
- CAS No.
- 12626-17-4
- Chemical Name:
- fumitremorgin B
- Synonyms
- Lanosulin;Fumitremorgin;FUMITREMORGENB;fumitremorgin B;B Fumitremorgin B;(5aR)-1,2,3,5a,6,11,12,14aβ-Octahydro-5aβ,6β-dihydroxy-9-methoxy-11-(3-methyl-2-butenyl)-12α-(2-methyl-1-propenyl)-5H,14H-pyrrolo[1'',2'':4',5']pyrazino[1',2':1,6]pyrido[3,4-b]indole-5,14-dione;5H,14H-Pyrrolo[1'',2'':4',5']pyrazino[1',2':1,6]pyrido[3,4-b]indole-5,14-dione, 1,2,3,5a,6,11,12,14a-octahydro-5a,6-dihydroxy-9-methoxy-11-(3-methyl-2-buten-1-yl)-12-(2-methyl-1-propen-1-yl)-, (5aR,6S,12S,14aS)-
- CBNumber:
- CB11387239
- Molecular Formula:
- C27H33N3O5
- Molecular Weight:
- 479.57
- MDL Number:
- MOL File:
- 12626-17-4.mol
- MSDS File:
- SDS
Last updated:2023-05-21 10:59:17
Melting point | 205-207 °C |
---|---|
Boiling point | 724.3±60.0 °C(Predicted) |
Density | 1.35±0.1 g/cm3(Predicted) |
storage temp. | Store at -20°C |
solubility | DMSO: Soluble,Methanol: Soluble |
form | A solid |
pka | 10.74±0.60(Predicted) |
FDA UNII | ITN5B384F8 |
fumitremorgin B Chemical Properties,Uses,Production
Description
This tremorgenic alkaloid is highly toxic and is elaborated by Aspergillus jurnigatus. The structure given above has been determined from X-ray crystallography. The crystals are orthorhombic with space group P2 1212 1, a = 14.771, b = 24.925 and c = 7.321 A with Z = 4. The absolute configuration is based upon that of L( - )-proline formed by acid hydrolysis of the alkaloid.
Definition
ChEBI: An organic heteropentacyclic compound that is a mycotoxic indole alkaloid produced by several fungi via a tryptophan-proline diketopiperazine intermediate.
References
Yamazaki et al., Tetrahedron Lett., 27 (1975)
fumitremorgin B Preparation Products And Raw materials
Raw materials
Preparation Products
fumitremorgin B Suppliers
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12626-17-4(fumitremorgin B)Related Search:
fumitremorgin B
FUMITREMORGENB
(5aR)-1,2,3,5a,6,11,12,14aβ-Octahydro-5aβ,6β-dihydroxy-9-methoxy-11-(3-methyl-2-butenyl)-12α-(2-methyl-1-propenyl)-5H,14H-pyrrolo[1'',2'':4',5']pyrazino[1',2':1,6]pyrido[3,4-b]indole-5,14-dione
Lanosulin
5H,14H-Pyrrolo[1'',2'':4',5']pyrazino[1',2':1,6]pyrido[3,4-b]indole-5,14-dione, 1,2,3,5a,6,11,12,14a-octahydro-5a,6-dihydroxy-9-methoxy-11-(3-methyl-2-buten-1-yl)-12-(2-methyl-1-propen-1-yl)-, (5aR,6S,12S,14aS)-
B Fumitremorgin B
Fumitremorgin
12626-17-4
C27H33N3O5