ChemicalBook >> CAS DataBase List >>(-)-3,9-Dihydro-2,3,3,9-tetramethylfuro[2,3-b]quinoline-4(2H)-one

(-)-3,9-Dihydro-2,3,3,9-tetramethylfuro[2,3-b]quinoline-4(2H)-one

CAS No.
31520-95-3
Chemical Name:
(-)-3,9-Dihydro-2,3,3,9-tetramethylfuro[2,3-b]quinoline-4(2H)-one
Synonyms
Ifflaiamine;(-)-3,9-Dihydro-2,3,3,9-tetramethylfuro[2,3-b]quinolin-4(2H)-one;(-)-3,9-Dihydro-2,3,3,9-tetramethylfuro[2,3-b]quinoline-4(2H)-one;(-)-3,9-Dihydro-2,3,3,9-tetramethylfuro[2,3-b]quinoline-4(2H)-one;Furo[2,3-b]quinolin-4(2H)-one, 3,9-dihydro-2,3,3,9-tetramethyl-, (-)-
CBNumber:
CB12188354
Molecular Formula:
C15H17NO2
Molecular Weight:
243.3
MDL Number:
MFCD28100647
MOL File:
31520-95-3.mol
MSDS File:
SDS

(-)-3,9-Dihydro-2,3,3,9-tetramethylfuro[2,3-b]quinoline-4(2H)-one Properties

Boiling point 334.5±42.0 °C(Predicted)
Density 1.19±0.1 g/cm3(Predicted)
pka -1.33±0.60(Predicted)

(-)-3,9-Dihydro-2,3,3,9-tetramethylfuro[2,3-b]quinoline-4(2H)-one price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Arctom AS019861 Ifflaiamine ≥98% 31520-95-3 5mg $371 2021-12-16 Buy
Crysdot CD32001674 Ifflaiamine 95+% 31520-95-3 5mg $852 2021-12-16 Buy
Product number Packaging Price Buy
AS019861 5mg $371 Buy
CD32001674 5mg $852 Buy

(-)-3,9-Dihydro-2,3,3,9-tetramethylfuro[2,3-b]quinoline-4(2H)-one Chemical Properties,Uses,Production

Description

This furanoquinoline alkaloid has been obtained from the bark of the Australian tree Flindersia ifflaiana. It is obtained in the form of a colourless gum which cannot be crystallized. The alkaloid is laevorotatory with [α]29D~~9 - 0.6° or [α]29D~~o - 3.6° (c 8.0, MeOH). From aqueous solvents, a crystalline hydrate is formed, m.p. 62-3°C. The ultraviolet spectrum in MeOH shows absorption maxima at 215, 236, 309 and 320 mil with a shoulder at 251 and an inflexion at 298 mil. A yellow crystalline picrate is known, m.p. 207-9°C. The probable structure obtained from infrared and NMR spectra, and dependent upon analogy with other alkaloids of this type, has been confirmed by the total synthesis of the (±)-form, m.p. 128-9°C.

References

Bosson et al., Austral. 1. Chem., 16, 480 (1963) Total syn thesis: Chamberlain, Grundon., Tetrahedron Lett., 3547 (1967)

(-)-3,9-Dihydro-2,3,3,9-tetramethylfuro[2,3-b]quinoline-4(2H)-one Preparation Products And Raw materials

Raw materials

Preparation Products

(-)-3,9-Dihydro-2,3,3,9-tetramethylfuro[2,3-b]quinoline-4(2H)-one Suppliers

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(-)-3,9-Dihydro-2,3,3,9-tetramethylfuro[2,3-b]quinoline-4(2H)-one Ifflaiamine (-)-3,9-Dihydro-2,3,3,9-tetramethylfuro[2,3-b]quinolin-4(2H)-one Furo[2,3-b]quinolin-4(2H)-one, 3,9-dihydro-2,3,3,9-tetramethyl-, (-)- (-)-3,9-Dihydro-2,3,3,9-tetramethylfuro[2,3-b]quinoline-4(2H)-one 31520-95-3