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(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE

(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE Structure
(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE structure
CAS No.
66283-23-6
Chemical Name:
(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE
Synonyms
(2S,2''S)-(-)-2-HYDROXYMETHYL-1-[(1-METHY;2-hydroxymethyl-(1-methylpyrrolidin-2ylmethyl)pyrrolidine;(-)-2-HYDROXYMETHYL-(1-METHYLPYRROLIDIN- 2-YLME)PYRROLIDINE;(1-((1-Methylpyrrolidin-2-yl)methyl)pyrrolidin-2-yl)methanol;(2S,2S)-1-(1-Methyl-2-pyrrolidinylmethyl)pyrrolidine-2-methanol;2-PyrrolidineMethanol,1-[[(2S)-1-Methyl-2-pyrrolidinyl]Methyl]-, (2S)-;(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE;(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDINE-2-YL)-METHYL]-PYRROLIDINE
CBNumber:
CB1272323
Molecular Formula:
C11H22N2O
Molecular Weight:
198.31
MDL Number:
MFCD00040527
MOL File:
66283-23-6.mol
Last updated:2025-01-15 11:04:30
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(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE Properties

Boiling point 275-277 °C
alpha [α]28D -130° (c 0.36, EtOH)
refractive index n20/D 1.494
solubility sol hexane, toluene, Me2O, Et2O, n-Pr2O, THF, dimethoxymethane.

SAFETY

Risk and Safety Statements

Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  1760
HazardClass  8
PackingGroup  III

(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE price

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
American Custom Chemicals Corporation CHM0004584 (2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE 95.00% 66283-23-6 5MG $501.06 2021-12-16 Buy
Labseeker SC-58427 (2S,2'S)-(-)-2-Hydroxymethyl-1-[(1-methylpyrrolidin-2-yl)-methyl]-pyrrolidine 95 66283-23-6 5g $1150 2021-12-16 Buy
Product number Packaging Price Buy
CHM0004584 5MG $501.06 Buy
SC-58427 5g $1150 Buy

(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE Chemical Properties,Uses,Production

Uses

(2S,2′S)-2-Hydroxymethyl-1-[(1-methylpyrrolidin-2-yl)methyl]pyrrolidine is a chiral ligand for alkyllithium, dialkylmagnesium, alkynyllithium, and functionalized organolithiums in the enantioselective addition to aldehydes; accelerates the basicity of alkyllithiums; catalyzes the addition of dialkylzinc to aldehyde.

Preparation

Preparative Method of (2S,2′S)-2-Hydroxymethyl-1-[(1-methylpyrrolidin-2-yl)methyl]pyrrolidine: reduction of N-[N(-benzyloxycarbonyl)prolyl]proline methyl ester with Lithium Aluminum Hydride affords the title reagent in 81% yield.

(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE synthesis

17708-83-7
66283-23-6
Synthesis of (2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE from L-Proline, 1-[1-[(phenylmethoxy)carbonyl]-L-prolyl]-, methyl ester

(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE Suppliers

Global( 9)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Holy Biohemdeviser Co., Ltd 021-61551100 China 444 57
Supplier Advantage
Shanghai Holy Biohemdeviser Co., Ltd 57

66283-23-6((2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE)Related Search:

BPP 9A Fmoc-Pro-Pro-OH (2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE BOC-PRO-PRO-OH H-PRO-PRO-PRO-OH
Z-PRO-PRO-OH BRADYKININ POTENTIATOR B BIG ENDOTHELIN-2 (22-37), HUMAN GLY-PRO-HYDROXY-PRO ACETATE SALT H-GLY-PRO-HYP-OH
FMOC-GLY-PRO-HYP-OH HIV (GP120) FRAGMENT (421-438) H-GLY-PRO-PRO-OH BOC-PRO-PRO-PRO-PRO-OH BRADYKININ POTENTIATOR C
DOLASTATIN 15 H-PRO-PRO-PRO-PRO-OH H-ARG-PRO-PRO-OH SULFATE SALT

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(2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDIN-2-YL)-METHYL]-PYRROLIDINE (2S,2'S)-(-)-2-HYDROXYMETHYL-1-[(1-METHYLPYRROLIDINE-2-YL)-METHYL]-PYRROLIDINE (-)-2-HYDROXYMETHYL-(1-METHYLPYRROLIDIN- 2-YLME)PYRROLIDINE 2-hydroxymethyl-(1-methylpyrrolidin-2ylmethyl)pyrrolidine (2S,2S)-1-(1-Methyl-2-pyrrolidinylmethyl)pyrrolidine-2-methanol (2S,2''S)-(-)-2-HYDROXYMETHYL-1-[(1-METHY 2-PyrrolidineMethanol,1-[[(2S)-1-Methyl-2-pyrrolidinyl]Methyl]-, (2S)- (1-((1-Methylpyrrolidin-2-yl)methyl)pyrrolidin-2-yl)methanol 66283-23-6