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PYROGALLOL RED

CAS No.
32638-88-3
Chemical Name:
PYROGALLOL RED
Synonyms
PR;PYROGALLOLUM;PYROGALLOL RED;PyrogallolRedGr;PYROGALLIC ACID;PYROGALLOL RED AR;PYROGALLIC ACID RED;1,2,3-BENZENETRIOL RED;PYROGALLOL RED-LACTONE;Pyrogallol Red,98%,pure
CBNumber:
CB1314191
Molecular Formula:
C19H12O8S
Molecular Weight:
400.36
MDL Number:
MFCD00005046
MOL File:
32638-88-3.mol
MSDS File:
SDS
Last updated:2024-12-18 14:07:02

PYROGALLOL RED Properties

Melting point 133-134 °C(lit.)
Boiling point 309 °C(lit.)
Density 1.082 g/mL at 20 °C
vapor density 4.4 (vs air)
vapor pressure 10 mm Hg ( 167.7 °C)
refractive index n20/D 1.387
storage temp. Inert atmosphere,Room Temperature
pka 7.86±0.20(Predicted)
form Liquid
color Dark brown
Water Solubility Soluble in water, ammonium hydroxide (10 mg/ml), and ethanol.
BRN 363738
InChI InChI=1S/C19H12O8S/c20-12-7-5-10-17(15(12)22)26-18-11(6-8-13(21)16(18)23)19(10)9-3-1-2-4-14(9)28(24,25)27-19/h1-8,20-23H
InChIKey KUQNCHZOCSYKOR-UHFFFAOYSA-N
SMILES S1(=O)(=O)C2=CC=CC=C2C2(C3=C(C(O)=C(O)C=C3)OC3=C2C=CC(O)=C3O)O1
CAS DataBase Reference 32638-88-3
EPA Substance Registry System Spiro[3H-2,1-benzoxathiole-3,9'-[9H]xanthene]-3',4',5',6'-tetrol, 1,1-dioxide (32638-88-3)

SAFETY

Risk and Safety Statements

Hazard Codes  Xn,Xi
Risk Statements  20/21/22-52/53-68-36/37/38
Safety Statements  36/37-61-24/25-22-36-26
RIDADR  UN 2811 6.1/PG 3
WGK Germany  3
RTECS  UX2800000
8
TSCA  Yes
HS Code  2934 99 90
NFPA 704
0
1 0

PYROGALLOL RED price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich P8759 Pyrogallol Red 32638-88-3 5g $198 2024-03-01 Buy
Sigma-Aldrich 1.07534 Pyrogallol red metal indicator 32638-88-3 1g $232 2024-03-01 Buy
TCI Chemical P0572 Pyrogallol Red 32638-88-3 1g $53 2024-03-01 Buy
TCI Chemical P0572 Pyrogallol Red 32638-88-3 5g $151 2024-03-01 Buy
TCI Chemical P1976 Pyrogallol Red [for Protein Research] 32638-88-3 1g $106 2024-03-01 Buy
Product number Packaging Price Buy
P8759 5g $198 Buy
1.07534 1g $232 Buy
P0572 1g $53 Buy
P0572 5g $151 Buy
P1976 1g $106 Buy

PYROGALLOL RED Chemical Properties,Uses,Production

Chemical Properties

Also know nas pyrogallol and 1,2,3-trihydroxy-benzene,C6H3(OH)3 is white,lustrous crystals that turn gray on exposure to light. It is soluble in water,alcohol,and ether. A solution of pyrogallol acquires a brown color on exposure to air. This absorption of oxygen and change of color take place rapidly when the solution is made alkaline. Derivation is by heating gallic acid in an autoclave with three times its weight of water.
Uses are as a protective colloid in preparation of metallic colloidal solutions, photography, dyes, intermediates, synthetic drugs, medicine (antibacterial), process engraving, laboratory reagent, gas analysis (an oxygen absorber), reducing agent, and antioxidant in lubricating oils.

Chemical Properties

dark brown powder

Uses

The white powdery crystal was made by the superheating of gallic acid. Pyrogallic acid, popularly known as pyro, is one of the earliest developers and its use has spanned three centuries. It was first used in an acid state to physically develop wet collodion negatives. When silver bromide gelatin plates were adopted pyro was used again but in an alkaline state for chemical development. It was used throughout the 20th century and often chosen for the peculiar yellow stain it imparted to gelatin negatives.

Uses

Pyrogallol Red is a complexometric indicator for the metal elements molybdenum and copper. Dyes and metabolites.

Purification Methods

It is recrystallised from aqueous alkaline solution (Na2CO3 or NaOH) by precipitation on acidification, filter it off and dry in a vacuum. [Suk Collect Czech Chem Commun 31 3127 1966, Beilstein 19 H 407, 19 II 417, 19 III/IV 599, 19/10 V 226.]

81-08-3
87-66-1
32638-88-3
Synthesis of PYROGALLOL RED from 2-Sulfobenzoic anhydride and Pyrogallol

PYROGALLOL RED Preparation Products And Raw materials

Global( 199)Suppliers
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Hubei Lidu New Material Technology Co., Ltd
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View Lastest Price from PYROGALLOL RED manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
PYROGALLOL RED pictures 2024-12-20 PYROGALLOL RED
32638-88-3
US $0.00-0.00 / g 1g 95% 20tons Hubei Lidu New Material Technology Co., Ltd
PYROGALLOL RED pictures 2024-10-30 PYROGALLOL RED
32638-88-3
US $0.00 / KG 1KG 99% 500000kg Hebei Weibang Biotechnology Co., Ltd
PYROGALLOL RED pictures 2024-10-25 PYROGALLOL RED
32638-88-3
US $40.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.
  • PYROGALLOL RED pictures
  • PYROGALLOL RED
    32638-88-3
  • US $0.00-0.00 / g
  • 95%
  • Hubei Lidu New Material Technology Co., Ltd
  • PYROGALLOL RED pictures
  • PYROGALLOL RED
    32638-88-3
  • US $0.00 / KG
  • 99%
  • Hebei Weibang Biotechnology Co., Ltd
  • PYROGALLOL RED pictures
  • PYROGALLOL RED
    32638-88-3
  • US $40.00 / kg
  • 0.99
  • Hebei Yanxi Chemical Co., Ltd.
PYROGALLOL RED INDICATOR FOR & PyrogallolRedGr Pyrogallol Red, indicator grade, pure Pyrogallol Red, pure, 98% Spiro(3H-2,1-benzoxathiole-3,9’(9H)xanthene)-3’,4’,5’,6’-tetrol,1,1-dioxide spiro[3h-2,1-benzoxathiole-3,9’-[9h]xanthene]-3’,4’,5’,6’-tetrol,1,1-dioxide PR PYROGALLOL RED, INDICATOR FOR COMPLEXO-M ETRY Pyrogallol red, pure, indicator grade 3',4',5',6'-Tetrahydroxyspiro[3H-2,1-benzoxathiole-3,9'-[9H]xanthene]1,1-dioxide Pyrogallol Red,98%,pure PYROGALLOL RED METAL INDICATOR Pyrogallol Red [for Protein Research] 3',4',5',6'-tetrahydroxyspiro[benzo[c][1,2]oxathiole-3,9'-xanthene] 1,1-dioxide 1,2,3-BENZENETRIOL RED 1,2,3-TRIHYDROXYBENZENE RED ALKALINE POTASSIUM PYROGALLATE SOLUTION ALKALINE PYROGALLOL REAGENT PYROGALLOL RED PYROGALLOL RED-LACTONE PYROGALLOLSULFONEPHTHALEIN PYROGALLOLSULFONPHTHALEIN PYROGALLOLUM PYROGALLOSULFONPHTHALEIN PYROGALLATE ABSORPTION SOLUTION, ALKALINE PYROGALLIC ACID PYROGALLIC ACID RED Pyrogallolred,monohydrate Pyrogallolsulfonphalein 2-(3,4,5,6,9-PENTAHYDROXYXANTHEN-9-YL)BENZENESULFONIC ACID-9-LACTONE Pyrogallolsulfonphthalein (PR) PYROGALLOL RED AR 3',4',5',6'-Tetrahydroxyspiro[benzo[c][1,2]oxathiole-3,9'-xanthene] 1,1-dioxide 32638-88-3 C19H12O8S 87661 Chelating Reagents Bipyridyls, etc. (Chelating Reagents) Analytical Chromatography Product Catalog Metal Titration Indicators Indicators Titration Analytical Chemistry Bipyridyls, etc. (Chelating Reagents) Chelating Reagents