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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex structure

CAS No.: 95464-05-4

Chemical Name:: 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

Synonyms: Pd（dppf）2Cl2;Pd(dppf)Cl2.CH2Cl2;PdCl2(dppf)DCM;[PdCl2(dppf)]CH2Cl2;Palladium[PdCl2(dppf)]CH2Cl2;[1,1-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane PdCl2(dppf)CH2Cl2;CHEMDOSE;Pd(dppf)Cl2;ex with dichL;adium(II),compL

CBNumber:: CB1347621

Molecular Formula:: C34H28Cl2FeP2Pd.CH2Cl2

Molecular Weight:: 816.63

MDL Number:: MFCD00792899

MOL File:: 95464-05-4.mol

MSDS File:: SDS

Last updated:2025-01-27 09:38:02

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1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Properties

Melting point	275-280 °C(lit.)
Density	1 g/cm³
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
solubility	Chloroform (Slightly), Methanol (Slightly)
form	Powder
color	orange-red
Water Solubility	Insoluble in water.
Stability	Light Sensitive
CAS DataBase Reference	95464-05-4(CAS DataBase Reference)
UNSPSC Code	12352200
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H302+H312+H332-H315-H319-H335

Precautionary statements

P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338

Hazard Codes

Risk Statements

20/21/22-36/37/38-40-67-48/20/22

Safety Statements

23-24/25-26-36/37

WGK Germany

TSCA

HS Code

28439000

NFPA 704

	1
2		1

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex price More Price(61)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	379670	[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane	95464-05-4	1g	$64.3	2024-03-01	Buy
Sigma-Aldrich	379670	[1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane	95464-05-4	5g	$160	2024-03-01	Buy
TCI Chemical	B2064	[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct >98.0%(T)	95464-05-4	1g	$58	2024-03-01	Buy
TCI Chemical	B2064	[1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct >98.0%(T)	95464-05-4	5g	$174	2024-03-01	Buy
Alfa Aesar	041225	Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), complex with dichloromethane (1:1), Pd 13%	95464-05-4	1g	$59.9	2023-06-20	Buy

Product number	Packaging	Price	Buy
379670	1g	$64.3	Buy
379670	5g	$160	Buy
B2064	1g	$58	Buy
B2064	5g	$174	Buy
041225	1g	$59.9	Buy

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Chemical Properties,Uses,Production

Reaction

Catalyst for the borylation of aryl halides.
β-Alkyl Suzuki-Miyaura cross-coupling reactions with potassium alkyltrifluoroborates.
Catalyst for modified Negishi coupling.
Synthesis of polyheterocycles by a Pd-catalyzed intramolecular N-arylation/C-H bond activation/aryl-aryl bond-forming domino process.
Catalyst for Stille allylation.
Catalyst for the amination of aryl bromides.

Chemical Properties

orange/red solid

Uses

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is used in the preparation of imidazoles, benzimidazoles, and tetrahydropyrimidines,it is also used as a catalyst for Suzuki and Stile couplings.

Uses

suzuki reaction

Application

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is an organometallic compound that can be used as a noble metal catalyst for carbonylation reactions, cross-coupling reactions, Suzuki reaction.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

Synthesis

1. Dissolve 2.00 grams of sodium palladium chloride in 30mL of anhydrous ethanol to obtain the ethanol solution of sodium palladium chloride;
2. Dissolve 4.15 grams of 1,1 '-bis (diphenylphosphine) ferrocene in 41mL dichloromethane to obtain 1,1' -bis (diphenylphosphine) ferrocene dichloromethane solution;
3. Under stirring conditions, add the ethanol solution of sodium palladite chloride in step 1 to dichloromethane solution of 1, 1 '-bis (diphenylphosphine) ferrocene in step 2. Stir and react for 1h at 25℃. 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex crystal, yield 90.46%.
In this method, the target product 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex was synthesized directly with dichloromethane as the solvent in one step, eliminating the synthesis process of precursor PDCl2 (DPPF). The reaction process is simple, the synthesis cycle is short, easy to operate, and the purity of the synthesized product is 99.4%.

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Preparation Products And Raw materials

Raw materials

Acetonitrile 1,1'-Bis(diphenylphosphino)ferrocene Toluene Palladium chloride Dichloromethane

Preparation Products

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Suppliers

Global( 453)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Wuhan Huahan Dingcheng New Material Technology Co., Ltd	+undefined-027-81388558 +undefined086-1878077615	huahandingcheng@sina.com	China	342	58
Hebei Chuanghai Biotechnology Co,.LTD	+86-13131129325	sales1@chuanghaibio.com	China	5868	58
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	20235	58
Frapp's ChemicalNFTZ Co., Ltd.	+86 (576) 8169-6106	sales@frappschem.com	China	880	50
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29730	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-+86-371-66670886	info@dakenam.com	China	19805	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21628	55
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1803	55
ATK CHEMICAL COMPANY LIMITED	+undefined-21-51877795	ivan@atkchemical.com	China	33024	60
AB PharmaTech,LLC	323-480-4688	sales@acrospharmatech.com	United States	989	55

Supplier	Advantage
Wuhan Huahan Dingcheng New Material Technology Co., Ltd	58
Hebei Chuanghai Biotechnology Co,.LTD	58
Henan Fengda Chemical Co., Ltd	58
Frapp's ChemicalNFTZ Co., Ltd.	50
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Shanghai Time Chemicals CO., Ltd.	55
ATK CHEMICAL COMPANY LIMITED	60
AB PharmaTech,LLC	55

View Lastest Price from 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2025-04-21	1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex 95464-05-4	US $0.00-0.00 / kg	1kg	98	1000	Wuhan Circle Star Chem-medical Technology Co.,Ltd
2025-04-04	1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex 95464-05-4	US $0.00-0.00 / KG	1KG	98%	1ton	Henan Aochuang Chemical Co.,Ltd.
2025-03-21	1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex 95464-05-4	US $100.00 / kg	1kg	99%	50000KG/month	Hebei Mujin Biotechnology Co.,Ltd

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
95464-05-4
US $0.00-0.00 / kg
98
Wuhan Circle Star Chem-medical Technology Co.,Ltd

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
95464-05-4
US $0.00-0.00 / KG
98%
Henan Aochuang Chemical Co.,Ltd.

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
95464-05-4
US $100.00 / kg
99%
Hebei Mujin Biotechnology Co.,Ltd

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex Spectrum

1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex(95464-05-4)IR

95464-05-4(1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex)Related Search:

Palladium chloride Cobalt chloride ETHYNYLFERROCENE Palladium Dichloromethane

Acetylferrocene Ferrocenecarboxylic acid [1,1'-bis(diphenylphosphino)ferrocene]palladium(ii) dichloride dichloromethane complex (1:1) Aminoferrocene Ferrocene

(1,3-BIS-(2,4,6-TRIMETHYLPHENYL)-2-IMIDAZOLIDINYLIDENE)DICHLORO(O-ISOPROPOXYPHENYLMETHYLENE)RUTHENIUM Pd-107 [1,2-Bis(dicyclohexylphosphino)ethane]palladiuM(II) chloride,95% 1,1'-Bis(diphenylphosphino)ferrocene Phenyl phosphine

Diphenylphosphine Chloromethane 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

1of4

[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II) Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II) dichloMethane coMplex (1,1'-Bis(diphenylphosphino)ferrocene)dichloropalladiuM-dichloroMethane (1:1) [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane, ChemDose(TM) tablets Loading: 2mumol per tablet 1,1'-Bis(diphenylphosphino)ferrocene-palladium dichloride dichloromethane adduct 1, 1-Bis(diphenylphosphino)Ferrocene] dichloropalaldium(II) complex with DCM Palladium, [1,1'-bis(diphenylphosphino-κP)ferrocene]dichloro-, (SP-4-2)-, compd. with dichloromethane Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), complex with dichloromethane (1:1) Bis(diphenylphosphino)ferrocene palladium dichloride, dichloromethane solvate Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladium(II), complex with dichloromethane [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane, ChemDose? tablets 1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]-PALLADIUM DICHLOROMETHANE ADDUCT DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHANE COMPLEX 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENEPALLADIUM(II) DICHLORIDE, DICHLOROMETHANE [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), COMPLEX WITH DICHLOROMETHANE (1:1) 1,1'-Bis(diphenylphosphiNA)ferrocene-palladiuM(II)dichloride dichloroMethane coMplex DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) DICHLOROMETHA 1,1'-Bis(diphenylphosphino)fer 1,1'-Bis(diphenylphosphino)ferrocene palladium(Ⅱ)chloride dichloromethane complex PALLADIUM, [1,1''-BIS(DIPHENYLPHOSPHINO-.KAPPA.P)FERROCENE]DICHLORO-, (SP-4-2)-, COMPD. WITH DICHLOROMETHANE [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, complex with dichloromethane (1:1), Pd 13% [1,1μ-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane, ChemDose(R) tablets ChemDose(R), [1,1μ-Bis(diphenylphosphino)ferrocene]dichloropalladium(II )complex with dichloromethane impregnated tablets [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, complex with dichloromethane (1:1), Pd [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), DCM ADDUCT [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II), DICHLOROMETHANE ADDUCT [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]DICHLOROPALLADIUM(II) DICHLOROMETHANE COMPLEX 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM (II) CHLORIDE [1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE]PALLADIUM(II) CHLORIDE, 1:1 COMPLEX WITH DICHLOROMETHANE 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE PALLADIUM (II) CHLORIDE, COMPLEX WITH DICHLOROMETHANE 1,1'-Bis(diphenylphosphino)ferrocene-palladiuM(II) (1,1'-Bis(diphenylphosphino)ferrocene)dichloropalladium-dichloromethane [1,1'-Bis(diphenylphosphino)ferrocene] dichloropalladiuM(II) coMplex with dichlor 1,1'-Bis(diphenylphosphino)ferrocene-palladiuMdichloride dichloroMethanecoMplex [1,1'-bis (diphenylphosphino) ferrocene] dichloropalladiuM dichloroMethane coMplex [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (1:1) Pd(dppf)Cl2 DCM [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride, complex with dichloromethane (1:1) [1,1Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane PdCl2(dppf)H2Cl2 [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex.dichloromethane [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) dichloromethane 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex [Pd(dppf)Cl2.CH2Cl2] [1,1′-Bis(diphenylphosphino)ferrocene]dichloropalladium(II), complex with dichloromethane,Pd(dppf)Cl2 · DCM 1,1'-Bis(diphenylphosphino)ferrocene-palladiuM(II)dichloride dic 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane com 1,1'-Bis(diphenylphosphino)ferrocene palladium(II)chloride dichloromethane complex ,97% [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) chloride dichloromethane complex Dichloro[1,1'-bis(diphenylphosphino)ferrocene]palladiuM(II) dichloroMethane adduct, (DPPF)PdCl2·CH2Cl2 Dichloro 1,1'-bis(diphenylphosphino)ferrocene palladium (II) dichloromethane, 99% cyclopenta-2,4-dien-1-yl(diphenyl)phosphane DICHLORO[1,1'-BIS(DIPHENYLPHOSPHINO)F dichloride dichloromethane complex [1,1'-Bis(diphenylphosphino)ferrocene]palladium(II) Dichloride Dichloromethane Adduct> [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(Ⅱ), Dichloromethane Adduct 1’1-Bis(diphenylphosphino)fewocene Palladium(II)chloride dichloromethane chloride CHEMDOSE 1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) complex with dichloromethane, ChemDose(TM) tablets