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4-tert-Butylcatechol

CAS No.
98-29-3
Chemical Name:
4-tert-Butylcatechol
Synonyms
TBC;4-tbc;4-TERT-BUTYL-1,2-BENZENEDIOL;PTBC;4-t-Butylcatechol;P-TERT-BUTYL CATECHOL;4-TERT-BUTYLPYROCATECHOL;T-BUTYL CATECHOL;P-T-BUTYLCATECHOL;p-tert-Butylpyrocatechol
CBNumber:
CB1390571
Molecular Formula:
C10H14O2
Molecular Weight:
166.22
MDL Number:
MFCD00002201
MOL File:
98-29-3.mol
MSDS File:
SDS
Last updated:2024-11-14 14:09:35

4-tert-Butylcatechol Properties

Melting point 52-55 °C(lit.)
Boiling point 285 °C(lit.)
Density 1.049
vapor pressure <1 hPa (25 °C)
refractive index n20/D 1.508
Flash point >230 °F
storage temp. Store below +30°C.
solubility methanol: soluble1g/10 mL, clear, colorless to slightly yellow
pka 9.92±0.10(Predicted)
form powder to lump
color White to Light yellow to Light red
Odor at 10.00?%?in?dipropylene glycol. phenolic
Water Solubility 0.2 g/100 mL (25 ºC)
Sensitive Hygroscopic
BRN 2043335
Exposure limits ACGIH: TWA 5 ppm (Skin)
NIOSH: TWA 5 ppm(20 mg/m3)
InChIKey XESZUVZBAMCAEJ-UHFFFAOYSA-N
LogP 1.98 at 25℃
Indirect Additives used in Food Contact Substances 4-TERT-BUTYLCATECHOL
FDA 21 CFR 175.105; 177.2600
CAS DataBase Reference 98-29-3(CAS DataBase Reference)
EWG's Food Scores 1-4
FDA UNII 9A069144KR
NIST Chemistry Reference 1,2-Benzenediol, 4-(1,1-dimethylethyl)-(98-29-3)
EPA Substance Registry System p-tert-Butylcatechol (98-29-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07,GHS09
Signal word  Danger
Hazard statements  H302+H312-H314-H317-H410
Precautionary statements  P260-P273-P280-P301+P312-P303+P361+P353-P305+P351+P338
Hazard Codes  C,N,T
Risk Statements  22-34-43-21-51/53-21/22-39/23/24/25-20/21/22-10-50/53
Safety Statements  26-36/37/39-45-61-24-60
RIDADR  UN 2923 8/PG 3
WGK Germany  2
RTECS  UX1400000
Autoignition Temperature 160 °C
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29072900
Toxicity LD50 orally in Rabbit: 815 mg/kg LD50 dermal Rat 1331 mg/kg
NFPA 704
1
2 0

4-tert-Butylcatechol price More Price(41)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.01987 4-tert-Butylpyrocatechol for synthesis 98-29-3 5G $38 2024-03-01 Buy
Sigma-Aldrich 8.01987 4-tert-Butylpyrocatechol for synthesis 98-29-3 250g $83.3 2024-03-01 Buy
Sigma-Aldrich 8.01987 4-tert-Butylpyrocatechol for synthesis 98-29-3 1kg $224 2024-03-01 Buy
Sigma-Aldrich 8.01987 4-tert-Butylpyrocatechol for synthesis 98-29-3 25kg $1800 2024-03-01 Buy
Sigma-Aldrich 19670 4-tert-Butylcatechol ≥98.0% (HPLC) 98-29-3 100g $39.3 2024-03-01 Buy
Product number Packaging Price Buy
8.01987 5G $38 Buy
8.01987 250g $83.3 Buy
8.01987 1kg $224 Buy
8.01987 25kg $1800 Buy
19670 100g $39.3 Buy

4-tert-Butylcatechol Chemical Properties,Uses,Production

Description

Para-tertiary butyl catechol is specially prepared by reacting the impure catechol fraction with tertiary butyl alcohol. Used for its various properties (inhibition of polymerization and as an antioxidizing agent) in the manufacture of rubber, plastics and paints, in the preparation of petrolatum products, and as an antioxidant in oils, it may induce vitiligo.

Chemical Properties

white to cream flakes

Uses

4-tert-butylcatechol (PTBC) is used as an antioxidant in fats, oils, and mineral oils, and as a stabilizer in polyester resins and polystyrene resins. A concentration of PTBC (up to 0.005%) can be found in paints, glues, thermal paper, lubricating oil, and mineral oil products.
4-tert-Butylcatechol is widely utilized as an inhibitor in polymerization of butadiene, styrene, vinyl acetate and other reactive monomers. It plays an important role in the synthesis of tungsten oxide nanoparticles by nonaqueous sol-gel process. It acts as a stabilizer in the manufacturing of polyurethane foam. It is employed as an antioxidant for synthetic rubber, polymers and oil derivatives. It is also utilized as a purification agent for aminoformate catalysts.

Uses

Polymerization inhibitor for styrene-butadiene and other olefins.
Inhibitor-remover packings and ready-to-use, disposable prepacked columns offer a quick and convenient means of removing small amounts of inhibitors which are added to reagents or solvents that would otherwise be unstable (e.g., they may polymerize, oxidize or darken) on storage.
The inhibitor removers are useful in applications which require that the stabilizer or inhibitor [i.e., hydroquinone (HQ), hydroquinone monomethyl ether (MEHQ, 4-methoxyphenol) or 4-tert-butylcatechol (TBC)] be removed prior to use.

General Description

4-tert-Butylcatechol,in the presence of O2 catalyzed by tyrosinase, yields 4-tert-butyl-o-benzoquinone. Electrochemical oxidation of 4-tert-Butylcatechol in the presence of 4-hydroxycoumarin as nucleophile has been studied using cyclic voltammetry and controlled-potential coulometry. It undergoes electrochemical trimerization via anodic oxidation and mechanism of trimerization has been studied using cyclic voltammetry and controlled-potential coulometry.

Hazard

Toxic by ingestion and skin absorption.

Flammability and Explosibility

Not classified

Contact allergens

p-tert-Butyl catechol is specially prepared by reacting the impure catechol fraction with tertiary butyl alcohol. It is used for its various properties (inhibitor of polymerization and antioxidizing agent) in the manufacture of rubber, plastics, and paints, in the preparation of petrolatum products, and as an antioxidant in oils. It may induce vitiligo.

Safety Profile

A poison by intravenous route. Moderately toxic by ingestion and skin absorption. A severe skin and eye irritant. Mutation data reported. Combustible when exposed to heat or flame. To fight fire, use Con, dry chemical, fog, mist. When heated to decomposition it emits acrid and irritating fumes

Purification Methods

Distil it in a vacuum, then recrystallise it from pentane or pet ether (or *C6H6). [Beilstein

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View Lastest Price from 4-tert-Butylcatechol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
 4-Tert-Butylcatechol pictures 2024-11-22 4-Tert-Butylcatechol
98-29-3
US $120.00 / kg 1kg 99% 10ton Hebei Zhuanglai Chemical Trading Co.,Ltd
4-tert-Butylcatechol  pictures 2024-11-22 4-tert-Butylcatechol
98-29-3
US $6.00 / kg 1kg 99% 2000KG/Month HebeiShuoshengImportandExportco.,Ltd
4-tert-Butylcatechol  pictures 2024-11-20 4-tert-Butylcatechol
98-29-3
US $6.00 / kg 1kg More than 99% 2000KG/Month Hebei Longbang Technology Co., Ltd
4-TERT-BUTYLCATECHOL 4-TERT-BUTYL-1,2-DIHYDROXYBENZENE 4-T-BUTYLPYROCATECHOL 4-(1,1-DIMETHYLETHYL)-1,2-BENZENEDIOL 4-tert-Butyl-1 4-tert-Butylcatechin 4-tert-butyl-pyrocatecho 4-tert-Butylpyrokatechin p-t-Butylpyrocatechol Pyrocatechol, 4-tert-butyl- Synox tbc synoxtbc 4-TERT.-BUTYLPYROCATECHOL WITH MAX. 15 % WATER, LIQUID 4-TERT.-BUTYLPYROCATECHOL WITH MAX. 15 % METHANOL, LIQUID 4-TERT-BUTYLCATECHOL SOLUTION & 4-TERT-BUTYLCATECHOL SOLUTION,>85% IN WA TER 4-TERT.-BUTYLPYROCATECHOL TECHNICAL (CRY STALLINE SOLID) Tris(2,3-Dibromopropyl-1)Isocyanurate 4-tert-Butylcatechol,98% 1,2-Benzenediol, 4-(1,1-dimethylethyl-) 1,2-benzenediol 1,2-Benzenediol,4-(1,1-dimethylethyl)- 1,2-Dihydroxy-4-tert-butylbenzene 2-Benzenediol,4-(1,1-dimethylethyl)-1 2-dihydroxybenene 4-(1,1-dimethylethyl)-2-benzenediol 4-tert-BUTYLCAtech gradeOL p-Tert-Butyl 4-TERT-BUTYLCATECHOL 99% P-TERT-BUTYL CATECHOL 85% IN METHANOL P-TERT-BUTYL CATECHOL 85% IN WATER p-tert-BUTYL CATECHOL pure TBC,4-Tert-Butylpy-Rocatechol PARA-TERTBUTYLCATECHOL PARA-TERT-BUTYLPYROCATECHOL PARA-TERTIARY-BUTYLCATECHOL 5-tert-Butylcatechol 4-tert-Butylcatechol,99% 4-TERT-BUTYLPYROCATECHOL FOR SYNTHESIS 4-tert-Butylcatechol >=98.0% (HPLC) 4-tert-Butylcatechol >=99.0% 4-tert-Butylca 4-Tert-butyl-1、2-dihydroxybenene 4-tert-Butylpyrocatechol, extra pure Para-Tert-Butylcatechol (TBC) 4-tert-Butylcatechol(TBC) 4-tert-Butylcatechol, 99% 100GR 4-tert-Butylcatechol p-t-Butylcatechol 〔4-t-Butylpyrocatechol〕 4-tert-Butylpyrocatechol(TBC) p-t-Butyl catechol 1,2-Dihydroxy-4-t-butylbenzene JACS-98-29-3 butanedioic acid bis(prop-2-enyl) ester 4-tert-Butylpyrocatechol > 4-(1,1-Dimethylethyl)-1,2-benzoldiol solid and methanol solution) 4-tert-BUTYL CATECHOL Extra Pure 4-TERT-BUTYL-1,2-BENZENEDIOL 4-TERT-BUTYLPYROCATECHOL