1,2,3,5-Tetrachlorobenzene
- CAS No.
- 634-90-2
- Chemical Name:
- 1,2,3,5-Tetrachlorobenzene
- Synonyms
- 1,2,3,5-tcb;1,2,3,5-Tetrachlorob;1,3,4,5-Tetrachlorbenzol;,2,3,5-TETRACHLOROBENZENE;Nicotinamide Impurity 249;1,2,3,5-TETRACHLOROBENZENE;tetrachloro1,2,3,5-benzene;1,2,4,6-tetrachlorobenzene;1,2,3,5-tetrachloro-benzen;1,3,4,5-Tetrachlorobenzene
- CBNumber:
- CB1395743
- Molecular Formula:
- C6H2Cl4
- Molecular Weight:
- 215.89
- MDL Number:
- MFCD00000543
- MOL File:
- 634-90-2.mol
- MSDS File:
- SDS
Melting point | 54.5°C |
---|---|
Boiling point | 246°C |
Density | 1.5578 (estimate) |
vapor pressure | 0.07 at 25 °C (extrapolated, Mackay et al., 1982) |
refractive index | 1.5348 (estimate) |
Flash point | 113 °C |
storage temp. | APPROX 4°C |
solubility | Soluble in alcohol, benzene, ether, and ligroin (Weast, 1986) |
color | White to Almost white |
Water Solubility | 4.016mg/L(25 ºC) |
BRN | 1618864 |
Henry's Law Constant | 58.0 at 25 °C (gas stripping-GC, Shiu and Mackay, 1997) |
CAS DataBase Reference | 634-90-2(CAS DataBase Reference) |
FDA UNII | I27N186CIN |
NIST Chemistry Reference | Benzene, 1,2,3,5-tetrachloro-(634-90-2) |
EPA Substance Registry System | 1,2,3,5-Tetrachlorobenzene (634-90-2) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07,GHS09 |
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Signal word | Warning | |||||||||
Hazard statements | H302-H410 | |||||||||
Precautionary statements | P264-P270-P273-P301+P312-P391-P501 | |||||||||
Hazard Codes | Xn,T,F | |||||||||
Risk Statements | 22-39/23/24/25-23/24/25-11 | |||||||||
Safety Statements | 22-24/25-45-36/37-16-7 | |||||||||
RIDADR | UN 1230 3/PG 2 | |||||||||
WGK Germany | 3 | |||||||||
RTECS | DB9445000 | |||||||||
HS Code | 2903.99.8001 | |||||||||
Toxicity | Acute oral LD50 for rats 1,727 mg/kg (quoted, RTECS, 1985). | |||||||||
NFPA 704 |
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1,2,3,5-Tetrachlorobenzene price More Price(13)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 36928 | 1,2,3,5-Tetrachlorobenzene PESTANAL | 634-90-2 | 250mg | $40 | 2024-03-01 | Buy |
TCI Chemical | T0870 | 1,2,3,5-Tetrachlorobenzene | 634-90-2 | 5G | $153 | 2024-03-01 | Buy |
TCI Chemical | T0870 | 1,2,3,5-Tetrachlorobenzene | 634-90-2 | 25G | $425 | 2024-03-01 | Buy |
TRC | T291995 | 1,2,3,5-Tetrachlorobenzene | 634-90-2 | 10g | $185 | 2021-12-16 | Buy |
Matrix Scientific | 098293 | 1,2,3,5-Tetrachlorobenzene 95+% | 634-90-2 | 10g | $238 | 2021-12-16 | Buy |
1,2,3,5-Tetrachlorobenzene Chemical Properties,Uses,Production
Uses
1,2,3,5-Tetrachlorobenzene is used in the synthesis of several organic compounds including that of polyarylated benzenes by multiple Suzuki-Miyaura reactions. It was used as part of study which investigated the antimicrobial activity of tetra substituted benzene derivatives which suggested antimicrobial activity tended to decrease with increasing size of halogen substituents.
Definition
ChEBI: A tetrachlorobenzene carrying chloro groups at positions 1, 2, 3 and 5.
General Description
White crystals or off-white solid.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
Simple aromatic halogenated organic compounds, such as 1,2,3,5-Tetrachlorobenzene , are very unreactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Materials in this group may be incompatible with strong oxidizing and reducing agents. Also, they may be incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. 1,2,3,5-Tetrachlorobenzene may react with oxidizers. .
Health Hazard
ACUTE/CHRONIC HAZARDS: 1,2,3,5-Tetrachlorobenzene may cause irritation on contact.
Fire Hazard
1,2,3,5-Tetrachlorobenzene is probably combustible.
Environmental Fate
Biological. A mixed culture of soil bacteria or a Pseudomonas sp. transformed 1,2,3,5-tetrachlorobenzene
to 2,3,4,6-tetrachlorophenol (Ballschiter and Scholz, 1980). The half-life of 1,2,3,5-
tetrachlorobenzene in an anaerobic enrichment culture was 1.8 d (Beurskens et al., 1993).
In an enrichment culture derived from a contaminated site in Bayou d’Inde, LA, 1,2,3,5-
tetrachlorobenzene underwent reductive dechlorination to 1,2,4- and 1,3,5-trichlorobenzene at
relative molar yields of 7 and 93%, respectively. The maximum dechlorination rate, based on the
recommended Michaelis-Menten model, was 94 nM/d (Pavlostathis and Prytula, 2000).
Photolytic. Irradiation (λ ≥285 nm) of 1,2,3,5-tetrachlorobenzene (1.1–1.2 mM/L) in an
acetonitrile-water mixture containing acetone (0.553 mM/L) as a sensitizer gave the following
products (% yield): 1,2,3-trichlorobenzene (5.3), 1,2,4-trichlorobenzene (4.9), 1,3,5-trichlorobenzene
(49.3), 1,3-dichlorobenzene (1.8), 2,3,4,4′,5,5′,6-heptachlorobiphenyl (1.41), 2,2′,3,4,4′,6,6′-
heptachlorobiphenyl (1.10), 2,2′,3,3′,4,5′,6-heptachlorobiphenyl (4.50), four hexachlorobiphenyls
(4.69), one pentachlorobiphenyl (0.64), trichloroacetophenone, 1-(trichlorophenyl)-2-propanone,
and (trichlorophenyl)acetonitrile (Choudhry and Hutzinger, 1984). Without acetone, the identified
photolysis products (% yield) included 1,2,3-trichlorobenzene (trace), 1,2,4-trichlorobenzene
(24.3), 1,3,5-trichlorobenzene (11.7), 1,3-dichlorobenzene (0.5), 1,4-dichlorobenzene (3.3),
pentachlorobenzene (1.43), 1,2,3,4-tetrachlorobenzene (5.99), two heptachlorobiphenyls (1.40),
two hexachlorobiphenyls (<0.01), and one pentachlorobiphenyl (0.75) (Choudhry and Hutzinger,
1984).
Purification Methods
Crystallise it from EtOH. [Beilstein 5 II 157, 5 III 551, 5 IV 668.]
1,2,3,5-Tetrachlorobenzene Preparation Products And Raw materials
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29884 | 58 |
Nanjing Dolon Biotechnology Co.,Ltd. | 18905173768 | sales@dolonchem.com | CHINA | 2972 | 58 |
Shanghai Worldyang Chemical Co.,Ltd. | +86-021-56795779 +8613651600618 | sales@worldyachem.com | China | 1243 | 58 |
Xi'an Kono chem co., Ltd., | 029-86107037 13289246953 | info@konochemical.com | China | 2993 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-6139-8061 +86-86-13650506873 | sales@chemdad.com | China | 39894 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49374 | 58 |
Richest Group Ltd | 18017061086 | oled@richest-group.com | CHINA | 5600 | 58 |
Neostar United (Changzhou) Industrial Co., Ltd. | +86-0519-85551759 +8613506123987 | marketing1@neostarunited.com | China | 8838 | 58 |
SIMAGCHEM CORP | +86-13806087780 | sale@simagchem.com | China | 17365 | 58 |
View Lastest Price from 1,2,3,5-Tetrachlorobenzene manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2019-07-06 | 1,2,3,5-Tetrachlorobenzene
634-90-2
|
US $1.00 / kg | 1kg | 95%-99% | as request | Career Henan Chemical Co |
- 1,2,3,5-Tetrachlorobenzene
634-90-2
- US $1.00 / kg
- 95%-99%
- Career Henan Chemical Co
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