ChemicalBook >> CAS DataBase List >>(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
- CAS No.
- 415918-91-1
- Chemical Name:
- (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
- Synonyms
- (S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine;(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine;(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine;]dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct.;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine, dichloroMethane adduct;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct,95%;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethaneadduct,min.95%;3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
- CBNumber:
- CB1405194
- Molecular Formula:
- C36H30NO2P
- Molecular Weight:
- 539.61
- MDL Number:
- MFCD04117687
- MOL File:
- 415918-91-1.mol
- MSDS File:
- SDS
Last updated:2023-06-08 17:06:34
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Properties
Melting point | 102-103 °C |
---|---|
Boiling point | 710.7±63.0 °C(Predicted) |
alpha | +427° (c 0.83, CHCl3) |
storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
pka | -0.57±0.20(Predicted) |
form | Powder |
color | white |
Sensitive | moisture sensitive |
CAS DataBase Reference | 415918-91-1 |
SAFETY
Risk and Safety Statements
Symbol(GHS) | ![]() GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H302-H315-H319-H335 |
Precautionary statements | P261-P280-P301+P312-P302+P352-P305+P351+P338 |
Hazard Codes | Xn |
Risk Statements | 36/37/38-22 |
Safety Statements | 26-36/37/39 |
WGK Germany | 3 |
HS Code | 2934.99.4400 |
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT price More Price(12)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
TCI Chemical | D4994 | (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine >98.0%(HPLC) | 415918-91-1 | 200mg | $174 | 2024-03-01 | Buy |
TCI Chemical | D4994 | (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine >98.0%(HPLC) | 415918-91-1 | 1g | $531 | 2024-03-01 | Buy |
Strem Chemicals | 15-1520 | (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95% | 415918-91-1 | 100mg | $86 | 2024-03-01 | Buy |
Strem Chemicals | 15-1520 | (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95% | 415918-91-1 | 500mg | $335 | 2024-03-01 | Buy |
TRC | D455833 | (R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a'']dinaphthalen-4-yl)bis(1-phenylethyl)amine | 415918-91-1 | 50mg | $110 | 2021-12-16 | Buy |
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Chemical Properties,Uses,Production
Reactions
- A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
- Ligand used in the iridium-catalyzed, enantioselective addition of nucleophiles to achiral
- allylic esters.
- Asymmetric hydrogenation.
- Ir-catalyzed regio- and enantioselective Friedel-Crafts allylic alkylation of indoles.
- Asymmetric hydrovinylation.
- Used in 1,3-dipolar cycloaddition reactions of azomethine ylides and alkenes,9a and
- Rh-catalyzed [5+2] cycloaddition of alkyne-vinyl-cyclopropanes.9b
- Palladium-catalyzed enantioselective de-epimerization in catalytic asymmetric allylic alkylation.
- Palladium-catalyzed enantioselective diamination of alkyl dienes.
![Reactions of 415918-91-1](/NewsImg/2017-12-21/2017122117481841355.jpg)
Uses
(R,R,R)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a'']dinaphthalen-4-yl)bis(1-phenylethyl)amine (CAS# 415918-91-1) is an organic catalyst used in the stereoselective preparation of homoallylic nitriles.
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Preparation Products And Raw materials
Raw materials
Preparation Products
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT Suppliers
Global( 65)Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18657 | 58 |
CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49392 | 58 |
Career Henan Chemica Co | +86-0371-86658258 +8613203830695 | laboratory@coreychem.com | China | 30250 | 58 |
Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52861 | 58 |
Hangzhou MolCore BioPharmatech Co.,Ltd. | +86-057181025280; +8617767106207 | sales@molcore.com | China | 49739 | 58 |
PT CHEM GROUP LIMITED | peter68@ptchemgroup.com | China | 35426 | 58 | |
GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 50000 | 58 |
Shaoxin Catsyn Co., Ltd. | +undefined-0575-82040869 +86-0575-82040869; | sales@catsyn.com | China | 6116 | 58 |
Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 57511 | 58 |
Yantai Sheng Kai Lun Biological Products Co. , Ltd. | 3119594100 | mark@sklnchem.cn | China | 7806 | 58 |
415918-91-1((S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT)Related Search:
BARIUM DINONYLNAPHTHALENESULFONATE
(R)-MONOPHOS
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)[(1R)-1-PHENYLETHYL]AMINE
(R)-N-(2-PROPYL)-1-PHENYLETHYLAMINE HYDROCHLORIDE
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
(R)-MONOPHOS
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
(R)-(+)-N-BENZYL-1-PHENYLETHYLAMINE HYDROCHLORIDE
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
1of3
(S,R,R)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine,dichloromethaneadduct,min.95%
(+)-N,N-Bis[(1R)-1-phenylethyl]-dinaphtho[2,1-d:1μ,2μ-f][1,3,2]dioxaphosphepin-4-amine, (11bS)
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
(R)-2,2-Binaphthoyl-(S,S)-di(1-phenylethyl)aminoylphosphine
(S,R,R)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a
3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)amine
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct, min. 95%
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]aMine, dichloroMethane adduct
R-(3,5-Dioxa-4-Phospha-Cyclohepta[2,1-A:3,4-A']Dinaphthalen-4-yl)Bis[(1R)-1-Phenylethyl]aMine
3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct,95%
(11bR)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f]
[1,3,2]dioxaphosphepin-4-amine
]dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine, dichloromethane adduct.
(11bR)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f]
[1,3,2]dioxaphosphepin-4-amine,99%e.e.
(11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1R)-1-phenylethyl]-, (11bR)-
(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1R)-1-phenylethyl]amine dichloromethane adduct
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT
(11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE
415918-91-1
Privileged Ligands
DSM MonoPhos Phosphoramidites
Asymmetric Synthesis
Chiral Catalysts, Ligands, and Reagents
Chiral Phosphine
CPN