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Phenylsilane

CAS No.
694-53-1
Chemical Name:
Phenylsilane
Synonyms
Silylbenzene;Phenylsilane, 98% 25ML;Fenylsilan;phenyl-silan;PHENYLSILANE;CHLORODIMETHYL;Benzene, silyl-;Silane, phenyl-;Phenylsilane>Phenylsilane,98%
CBNumber:
CB1677768
Molecular Formula:
C6H8Si
Molecular Weight:
108.21
MDL Number:
MFCD00013478
MOL File:
694-53-1.mol
MSDS File:
SDS
Last updated:2024-08-21 22:41:43

Phenylsilane Properties

Melting point -64 to -68°C
Boiling point 120 °C (lit.)
Density 0.877 g/mL at 25 °C (lit.)
refractive index n20/D 1.510(lit.)
Flash point 45 °F
storage temp. Flammables area
form clear liquid
color Colorless to Almost colorless
Specific Gravity 0.868
Water Solubility Contact with water releases a flammable alcohol. Soluble in water (Contact with water releases flammable gases), and most common organic solvents.
Sensitive Air & Moisture Sensitive
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
BRN 2935169
InChIKey PARWUHTVGZSQPD-UHFFFAOYSA-N
CAS DataBase Reference 694-53-1(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII P2EX7Q1UYS
EPA Substance Registry System Silane, phenyl- (694-53-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Danger
Hazard statements  H225-H302+H332-H315-H319-H335
Precautionary statements  P210-P301+P312+P330-P302+P352-P304+P340+P312-P305+P351+P338
Hazard Codes  F,Xn
Risk Statements  11-14/15-20/22-36/37/38
Safety Statements  16-43
RIDADR  UN 3399 4.3/PG 2
WGK Germany  1
RTECS  VV4825000
10-21
TSCA  Yes
HazardClass  4.3
PackingGroup  II
HS Code  29319090
NFPA 704
3
2 2
W

Phenylsilane price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 335150 Phenylsilane 97% 694-53-1 1g $35.6 2024-03-01 Buy
Sigma-Aldrich 335150 Phenylsilane 97% 694-53-1 5g $102 2024-03-01 Buy
TCI Chemical P1291 Phenylsilane >97.0%(GC) 694-53-1 5mL $161 2024-03-01 Buy
TCI Chemical P1291 Phenylsilane >97.0%(GC) 694-53-1 25mL $440 2024-03-01 Buy
Alfa Aesar A17901 Phenylsilane, 97% 694-53-1 5g $88.8 2024-03-01 Buy
Product number Packaging Price Buy
335150 1g $35.6 Buy
335150 5g $102 Buy
P1291 5mL $161 Buy
P1291 25mL $440 Buy
A17901 5g $88.8 Buy

Phenylsilane Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid

Uses

Phenylsilane (PhSiH3) may be used as a reducing agent for the partial reduction of phosphine oxide groups in poly(4,4′-diphenylphenylphosphine oxide) (PAPO) to phosphine. It can also undergo photopolymerization with methyl methacrylate(MMA) to form poly(MMA) containing SiH groups. PhSiH3 may be used as a silicon source to synthesize crystalline Si nanowires via Au-nanocrystal-seeded supercritical fluid-liquid-solid (SFLS) synthesis.

Uses

phenylsilane is used as a pharmaceutical intermediate.

Definition

ChEBI: Phenylsilane is an organosilicon compound that is benzene in which a hydrogen is replaced by a silyl group. It has a role as a reducing agent. It is an organosilicon compound and a member of benzenes.

Application

Employed in the reduction of esters to ethers. Reduces α,β-unsaturated ketones to saturated ketones in the presence of tri-n-butyltin hydride. Reduces tin amides to tin hydrides. Used in the tin-catalyzed reduction of nitroalkanes to alkanes. Reduces α-halo ketones in presence of Mo(0).

Synthesis

The method for preparing phenyl silane comprises the following steps: adding trichlorophenylsilane in a tetrahydrofuran solution dissolved with a catalyst, carrying out a reaction at the temperature of -10-0 ℃, after the completion of the reaction is monitored by a TLC method, adding the product into an inorganic acid dilute solution under an ice bath condition, and extracting an organic layer, to obtain phenyl silane.

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View Lastest Price from Phenylsilane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Phenylsilane pictures 2024-08-23 Phenylsilane
694-53-1
US $2000.00 / kg 1kg 99% 1 tons Anhui Royal Chemical Co., Ltd.
Phenylsilane pictures 2024-08-20 Phenylsilane
694-53-1
US $5.00-2.00 / KG 1KG 99% 10000kg Hebei Guanlang Biotechnology Co,.LTD
Trifluoromethanesulfonic anhydride pictures 2023-06-20 Trifluoromethanesulfonic anhydride
694-53-1
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
  • Phenylsilane pictures
  • Phenylsilane
    694-53-1
  • US $2000.00 / kg
  • 99%
  • Anhui Royal Chemical Co., Ltd.
  • Phenylsilane pictures
  • Phenylsilane
    694-53-1
  • US $5.00-2.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co,.LTD
Phenylsilane, 98% 5ML Phenylsilane,98% Phenylsilane≥ 98% (GC) PHENYLSILANE Benzene, silyl- Fenylsilan phenyl-silan Phenylsilane, silyl- Phenylsilane,97% Silane, phenyl- CHLORODIMETHYL Phenylsilane, 97.5% Phenylsilane> Phenylsilane, 98% 25ML Silylbenzene 694-53-1 C6H8Si C6H5SiH3 C6H5Si Organosilicon Others Organometallic Reagents Si (Classes of Silicon Compounds) Si-H Compounds Reduction Silane compounds Reduction Si (Classes of Silicon Compounds) Si-H Compounds Synthetic Organic Chemistry Organometallic Reagents Organosilicon Others