ChemicalBook >> CAS DataBase List >>(S)-(+)-alpha-Methoxyphenylacetic acid
(S)-(+)-alpha-Methoxyphenylacetic acid
- CAS No.
- 26164-26-1
- Chemical Name:
- (S)-(+)-alpha-Methoxyphenylacetic acid
- Synonyms
- O-METHYL-L-MANDELIC ACID;O-Methyl-(S)-mandelicacid;L-α-Methoxyphenylacetic Acid;(+)-Methoxyphenylacetic acid;(S)-(+)-O-MethylMandelic Acid;(S)-α-Methoxybenzeneacetic acid;(S)-(+)-METHOXYPHENYLACETIC ACID;(αS)-α-Methoxybenzeneacetic acid;Acetic acid, Methoxyphenyl-, (S)-;(s)-(+)-à-methoxyphenylacetic acid
- CBNumber:
- CB1742293
- Molecular Formula:
- C9H10O3
- Molecular Weight:
- 166.17
- MDL Number:
- MFCD00064216
- MOL File:
- 26164-26-1.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
Melting point | 64-66 °C(lit.) |
---|---|
Boiling point | 164-166°C 18mm |
alpha | 160 º (C=1, MEOH) |
Density | 1.1708 (rough estimate) |
refractive index | 147 ° (C=0.5, EtOH) |
Flash point | 164-166°C/18mm |
storage temp. | Sealed in dry,Room Temperature |
solubility | Chloroform (Slightly), Ethanol (Slightly) |
pka | 3.10±0.10(Predicted) |
form | Fine Crystalline Powder or Crystals |
color | White |
optical activity | [α]17/D +150°, c = 1 in ethanol |
Water Solubility | Soluble |
BRN | 2361718 |
CAS DataBase Reference | 26164-26-1(CAS DataBase Reference) |
FDA UNII | VL35DS7HGX |
NIST Chemistry Reference | Benzeneacetic acid, «alpha»-methoxy-, (s)-(26164-26-1) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H315-H319-H335 | |||||||||
Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 36/37/38 | |||||||||
Safety Statements | 26-36 | |||||||||
WGK Germany | 3 | |||||||||
HS Code | 29189900 | |||||||||
NFPA 704 |
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(S)-(+)-alpha-Methoxyphenylacetic acid price More Price(26)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 248983 | (S)-(+)-α-Methoxyphenylacetic acid 99% | 26164-26-1 | 1g | $296 | 2024-03-01 | Buy |
TCI Chemical | M0829 | (S)-(+)-α-Methoxyphenylacetic Acid >98.0%(GC)(T) | 26164-26-1 | 1g | $102 | 2024-03-01 | Buy |
TCI Chemical | M0829 | (S)-(+)-α-Methoxyphenylacetic Acid >98.0%(GC)(T) | 26164-26-1 | 5g | $309 | 2024-03-01 | Buy |
Alfa Aesar | L08748 | (S)-(+)-alpha-Methoxyphenylacetic acid, 99% | 26164-26-1 | 250mg | $42.65 | 2024-03-01 | Buy |
Alfa Aesar | L08748 | (S)-(+)-alpha-Methoxyphenylacetic acid, 99% | 26164-26-1 | 1g | $104.65 | 2024-03-01 | Buy |
(S)-(+)-alpha-Methoxyphenylacetic acid Chemical Properties,Uses,Production
Chemical Properties
White Solid
Uses
Reactant involved in the synthesis of biologically active molecules including:
- Acyclonucleoside phosphonates structural analogs of adefovir
- Labeled discodermolide for studying binding to tubulin
- 10-Isocyano-4-cadinene used for antifouling activity
Reactant involved in studies of immunostimulating chromanones gonytolides A-C
Reactant involved in:
- Hydroxylations and epoxidations
- Hydrogenations
Uses
(S)-(+)-α-Methoxyphenylacetic Acid (cas# 26164-26-1) is a compound useful in organic synthesis.
Purification Methods
Purify the acids by recrystallising from *C6H6/pet ether (b 80-100o). [Neilson & Peters J Chem Soc 1519 1962, Weizmann et al. J Am Chem Soc 70 1153 1948, Pirie & Smith J Chem Soc 338 1932, NMR: Dale & Mosher J Am Chem Soc 9 5 512 1973, for resolution: Roy & Deslongchamps Can J Chem 63 651 1985, Trost et al. J Am Chem Soc 1 0 8 4974 1986.] The racemic mixture has m 72o, b 121-122o/0.4mm, 165o/18mm (from pet ether) [Braun et al. Chem Ber 6 3 2847 1930]. [Beilstein 10 IV 566.]
(S)-(+)-alpha-Methoxyphenylacetic acid Preparation Products And Raw materials
Raw materials
1of3
Preparation Products
Global( 177)Suppliers
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View Lastest Price from (S)-(+)-alpha-Methoxyphenylacetic acid manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2022-09-28 | (S)-(+)-alpha-Methoxyphenylacetic acid
26164-26-1
|
US $0.00-0.00 / kg | 1kg | 98% | 1Ton | Henan Aochuang Chemical Co.,Ltd. | ||
2020-02-01 | (S)-(+)-alpha-Methoxyphenylacetic acid
26164-26-1
|
US $1.00 / KG | 1KG | 99% | 200kgs | Career Henan Chemical Co |
- (S)-(+)-alpha-Methoxyphenylacetic acid
26164-26-1
- US $0.00-0.00 / kg
- 98%
- Henan Aochuang Chemical Co.,Ltd.
- (S)-(+)-alpha-Methoxyphenylacetic acid
26164-26-1
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
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(S)-(+)-alpha-Methoxyphenylacetic acid,99%
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(S)-(+)-alpha-Methoxyphenylacetic acid, 99% 1GR
(S)-(+)-O-MethylMandelic Acid
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L-α-Methoxyphenylacetic Acid
(S)-(+)-α-Methoxyphenylacetic acid, for chiral derivatization
(S)-(+)-α-Methoxyphenylacetic acid, 99%, for chiral derivatization
(S)-(+)-α-MethoxyphenylaceticAcid>
Benzeneacetic acid, α-methoxy-, (αS)-
(S)-(-)-α-methoxyphenylacetic acid
(+)-Methoxyphenylacetic acid
26164-26-1
C6H5CHOCH3CO2H
CARBOXYLIC ACID
Chiral Derivatization
Chiral Resolution Reagents
Asymmetric Synthesis
Analytical Chromatography Product Catalog
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Carboxylic Acids (Chiral)
e.e. / Absolute Conefiguration Determination (NMR)
Enantiomer Excess & Absolute Conefiguration Determination
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Analytical Chemistry
Carboxylic Acids (Chiral)
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e.e. / Absolute Configuration Determination (NMR)
Enantiomer Excess & Absolute Configuration Determination
Synthetic Organic Chemistry
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