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PENTAETHYLENEHEXAMINE

CAS No.
4067-16-7
Chemical Name:
PENTAETHYLENEHEXAMINE
Synonyms
PENTAETHYLENEHEXAMIN;PENTAETHYLENEHEXAMINE;bis(N2-(2-aminoethyl);Pentaethylenehexamide;PentaethylenehexaMine PENTAETHYLENEHEXAMINE, TECH.;Pentaethylenehexamine mixture;1,4,7,10,13,16-Hexaazahexadecane;Pentaethylenehexamine (so called);PENTAETHYLENEHEXAMINE FOR SYNTHESIS
CBNumber:
CB1783025
Molecular Formula:
C10H28N6
Molecular Weight:
232.37
MDL Number:
MFCD00008167
MOL File:
4067-16-7.mol
MSDS File:
SDS
Last updated:2024-12-18 14:07:02

PENTAETHYLENEHEXAMINE Properties

Melting point -35 °C
Boiling point 380 °C
Density 0.95 g/mL at 25 °C (lit.)
vapor pressure <1 hPa (20 °C)
refractive index n20/D 1.5096(lit.)
Flash point >230 °F
storage temp. Store below +30°C.
solubility water: soluble500g/L at 20°C
pka 10.07±0.19(Predicted)
form Liquid
color Clear yellow
PH 11 (10g/l, H2O)
BRN 1768042
Stability Stable. Incompatible with strong oxidizing agents, strong acids.
CAS DataBase Reference 4067-16-7(CAS DataBase Reference)
FDA UNII 9K5VZU43LE
EPA Substance Registry System Pentaethylenehexamine (4067-16-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07,GHS09
Signal word  Danger
Hazard statements  H314-H317-H410
Precautionary statements  P261-P272-P273-P280-P303+P361+P353-P305+P351+P338
Hazard Codes  C,N
Risk Statements  34-43-50/53-21/22
Safety Statements  26-36/37/39-45-60-61
RIDADR  UN 2735 8/PG 3
WGK Germany  2
RTECS  RZ2680000
Autoignition Temperature 360 °C
HazardClass  8
PackingGroup  III
HS Code  29211999
Toxicity LD50 orl-rat: 1600 mg/kg 37ASAA 7,580,79
NFPA 704
1
3 0

PENTAETHYLENEHEXAMINE price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.40076 Pentaethylenehexamine (mixture of isomers) for synthesis 4067-16-7 25mL $31.4 2024-03-01 Buy
Sigma-Aldrich 8.40076 Pentaethylenehexamine (mixture of isomers) for synthesis 4067-16-7 1L $125 2024-03-01 Buy
Sigma-Aldrich 292753 Pentaethylenehexamine technical grade 4067-16-7 250ml $45.1 2024-03-01 Buy
Sigma-Aldrich 292753 Pentaethylenehexamine technical grade 4067-16-7 1l $116 2024-03-01 Buy
TCI Chemical P0622 Pentaethylenehexamine (so called) 4067-16-7 25g $26 2024-03-01 Buy
Product number Packaging Price Buy
8.40076 25mL $31.4 Buy
8.40076 1L $125 Buy
292753 250ml $45.1 Buy
292753 1l $116 Buy
P0622 25g $26 Buy

PENTAETHYLENEHEXAMINE Chemical Properties,Uses,Production

Chemical Properties

dark yellow-green liquid

Uses

5.Pentaethylenehexamine has been used in the preparation of:

  • polyisobutylene succinimide (PIBSI) dispersants, used as engine oil-additives
  • poly(glycidyl methacrylate) (P(GMA)) homopolymers
  • poly(amidoamine)s

General Description

Yellowish liquid with an odor of ammonia.

Air & Water Reactions

Water soluble.

Reactivity Profile

PENTAETHYLENEHEXAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

Contact with eyes can cause slight to moderate irritation and possible burns. May cause transient fogging of the eyes as a result of corneal edema, which is reversible. May cause moderate skin irritation or allergic skin reaction with symptoms of redness, itching, swelling, or rash. Vapors may irritate the eyes, nose, throat, and respiratory tract. May cause coughing, headache, nausea and vomiting. If swallowed, may cause nausea, vomiting and abdominal pain. May cause burns of the mouth, throat, esophagus, and stomach.

Safety Profile

Moderately toxic by ingestion. Mutation data reported. Whenheated to decomposition it emits toxic fumes of NOx.

Purification Methods

Fractionally distil it twice at 10-20mm, the fraction boiling at 220-250o being collected. It can be further purified via the hydrochloride. Its solution in MeOH (40mL of base in 250mL) is cooled in an ice-bath and conc HCl (~50mL) is added dropwise with stirring. The precipitated hydrochloride is filtered off, washed with Me2CO, and Et2O, then dried in a vacuum desiccator. The free base is then obtained by basification, extraction into Et2O, drying (NaOH), filtering, evaporating and distilling the residue as before. It forms a Cu complex [Cu(C10H28N6)]2+. [Jonassen et al. J Am Chem Soc 79 4279 1957, Beilstein 4 IV 1245.]

23435-23-6
111-40-0
4067-16-7
Synthesis of PENTAETHYLENEHEXAMINE from AZIRIDINE TRIMER and Diethylenetriamine

PENTAETHYLENEHEXAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 164)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Weibang Biotechnology Co., Ltd
+8615531157085 abby@weibangbio.com China 8810 58
Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578 sales@hbmojin.com China 12834 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5857 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
Hangzhou FandaChem Co.,Ltd.
+8615858145714 FandaChem@Gmail.com China 9087 55
career henan chemical co
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Chongqing Chemdad Co., Ltd
+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23541 58
Dideu Industries Group Limited
+86-29-89586680 +86-15129568250 1026@dideu.com China 22784 58

View Lastest Price from PENTAETHYLENEHEXAMINE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
PENTAETHYLENEHEXAMINE pictures 2024-11-27 PENTAETHYLENEHEXAMINE
4067-16-7
US $10.00 / KG 1KG 99% 10 mt Hebei Weibang Biotechnology Co., Ltd
Pentaethylenehexamine pictures 2024-10-25 Pentaethylenehexamine
4067-16-7
US $40.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.
PENTAETHYLENEHEXAMINE pictures 2023-09-04 PENTAETHYLENEHEXAMINE
4067-16-7
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
PENTAETHYLENEHEXAMINE N1,N1'-(ethane-1,2-diyl)bis(N2-(2-aMinoethyl)ethane-1,2-diaMine) PentaethylenehexaMine technical grade bis(N2-(2-aminoethyl) 3,6,9,12-TETRAAZATETRADECANE-1,14-DIAMINE 3,6,9,12-tetraazatetradecamethylenediamine Pentaethylenehexamide PENTAETHYLENEHEXAMINE, TECH. Pentaethylenehexamine Alkylene polyamine Pentaethylenehexamine (so called) 3,6,9,12-tetra-azatetradecamethylenediamine pentacthylenehexamine Pentaethylenehexamine, 30.5% nitrogen, tech. Pentaethylenehexaminetech.30.5% nitrogen 1,4,7,10,13,16-Hexaazahexadecane 2,2'-[Ethylenebis(iminoethyleneimino)]bis(ethanamine) N,N''-[Ethylenebis(iminoethylene)]bis(ethylenediamine) PENTAETHYLENEHEXAMIN 3,6,9,12-Tetraazatetradecamethylendiamin 1,2-Bis[[2-[(2-aminoethyl)amino]ethyl]amino]ethane Pentaethylenehexamine mixture PentaethylenehexaMine, tech., 30.5% nitrogen 250ML PentaethylenehexaMine  PENTAETHYLENEHEXAMINE FOR SYNTHESIS PENTAETHYLENEHEXAMINE ISO 9001:2015 REACH 4067-16-7 H2NCH2CH2NH5H NH2CH2CH2NHCH2CH2NH3CH2CH2NH2 C10H28N6 C10H34N6 Building Blocks Organic Building Blocks Nitrogen Compounds Polyamines Building Blocks Chemical Synthesis Nitrogen Compounds Organic Building Blocks Polyamines