CHLOROMETHYL PHENYL SULFOXIDE
- CAS No.
- 7205-94-9
- Chemical Name:
- CHLOROMETHYL PHENYL SULFOXIDE
- Synonyms
- Einecs 230-580-2;CHLOROMETHYL PHENYL SULFOXIDE;Phenyl (chloromethyl) sulfoxide;[(Chloromethyl)sulfinyl]benzene;[(chloromethyl)sulphinyl]benzene;Benzene, ((chloromethyl)sulfinyl)-;Chloromethyl phenyl sulfoxide >=97.0%
- CBNumber:
- CB2111210
- Molecular Formula:
- C7H7ClOS
- Molecular Weight:
- 174.65
- MDL Number:
- MFCD00042639
- MOL File:
- 7205-94-9.mol
- MSDS File:
- SDS
| Melting point | 33-35 °C |
|---|---|
| Boiling point | 109-111 °C/0.01 mmHg |
| Density | 1.35±0.1 g/cm3(Predicted) |
| Flash point | 100 °C |
| storage temp. | -20°C |
| solubility | sol CHCl3 and THF. |
| form | solid |
| BRN | 1617664 |
| EPA Substance Registry System | Benzene, [(chloromethyl)sulfinyl]- (7205-94-9) |
| UNSPSC Code | 12352100 |
SAFETY
Risk and Safety Statements
| Safety Statements | 22-24/25 |
|---|---|
| WGK Germany | 3 |
CHLOROMETHYL PHENYL SULFOXIDE price More Price(4)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| AK Scientific | 5388CA | Chloromethyl phenyl sulfoxide | 7205-94-9 | 1g | $534 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | HCH0067366 | CHLOROMETHYL PHENYL SULFOXIDE 95.00% | 7205-94-9 | 1G | $711.76 | 2021-12-16 | Buy |
| Crysdot | CD12039766 | ((Chloromethyl)sulfinyl)benzene 95+% | 7205-94-9 | 1g | $300 | 2021-12-16 | Buy |
| Alichem | 7205949 | ((Chloromethyl)sulfinyl)benzene | 7205-94-9 | 1g | $400 | 2021-12-16 | Buy |
CHLOROMETHYL PHENYL SULFOXIDE Chemical Properties,Uses,Production
Uses
Chloromethyl phenyl sulfoxide has been used in the preparation of:
- 1-chloroalkyl sulfoxides
- starting material for the synthesis alkyl sulfoxides and thiol ester acyl anion equivalent
Preparation
Chlorination of methylphenyl sulfoxide with sulfonyl chloride in dichloromethane or N-chlorosuccinimide in chloroform gives Chloromethyl phenyl sulfoxide in good yields. A one-step process starting from phenyl sulfide involves chlorination with sulfonyl chloride in dichloromethane followed by oxidation with the same reagent in the presence of wet silica gel. Another method uses silver(I) nitrate and sulfonyl chloride in acetonitrile.
Synthesis Reference(s)
Journal of the American Chemical Society, 90, p. 4496, 1968 DOI: 10.1021/ja01018a078
Synthesis, p. 831, 1986
Tetrahedron Letters, 17, p. 613, 1976
General Description
Chloromethyl phenyl sulfoxide has synthetic potential and exhibits unusual stereochemical specificity. Stereospecific hydroxyalkylation of chloromethyl phenyl sulfoxide has been investigated.
CHLOROMETHYL PHENYL SULFOXIDE Preparation Products And Raw materials
Raw materials
Preparation Products
CHLOROMETHYL PHENYL SULFOXIDE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696 | info@hanhongsci.com | China | 42957 | 64 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51456 | 80 |
| Aikon International Limited | 025-58859352 18068836627 | yftan@aikonchem.com | China | 15494 | 58 |
| Shanghai Maruhua Science and Technology Co. Ltd. | 021-57171708; 18721745940 | sales2@api-chem.com | China | 1938 | 58 |
| Zhengzhou Ruike Biochemical Technology Co., Ltd. | 18521304688 | 421551521@qq.com | China | 256 | 58 |
| Tianjin and Sinde Biotechnology Co., Ltd. | 15022315965; 18502259037 | sales_hxd@163.com | China | 507 | 58 |
| Shanghai Haohong Pharmaceutical Co., Ltd. | 400-8210725 4008210725 | malulu@leyan.com | China | 40026 | 58 |
| Bide Pharmatech Ltd. | 400-1647117 13681763483 | product02@bidepharm.com | China | 62072 | 58 |
| Bide Pharmatech Ltd. | 400-6005915 | sales@picasso-e.com | China | 39665 | 58 |
| Suzhou Victorypharm Co.,Ltd. | 512-68242903 13916956214 | sales@victory-pharm.com | China | 1457 | 58 |
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