Dibenzotetrathiafulvalene
- CAS No.
- 24648-13-3
- Chemical Name:
- Dibenzotetrathiafulvalene
- Synonyms
- DBTTF;Dibenzotetrathiafulvalene;Δ2,2'-Bi(1,3-benzodithiol);Δ2,2'-Bi[1,3-benzodithiole];Dibenzotetrathiafulvalene 97%;2,2'-Bibenzo[d][1,3]dithiolylidene;Δ2,2'-Bi[4,5-[1,3]butadieno-1,3-dithiol];[2,2]Bi[benzo[1,3]dithiolylidene], DB-TTF;2-(1,3-benzodithiol-2-ylidene)-1,3-benzodithiole;1,3-Benzodithiole,2-(1,3-benzodithiol-2-ylidene)-
- CBNumber:
- CB21238143
- Molecular Formula:
- C14H8S4
- Molecular Weight:
- 304.47
- MDL Number:
- MFCD00443822
- MOL File:
- 24648-13-3.mol
- MSDS File:
- SDS
Dibenzotetrathiafulvalene price More Price(7)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 695637 | Dibenzotetrathiafulvalene 97% | 24648-13-3 | 500mg | $111 | 2024-03-01 | Buy |
| Biosynth Carbosynth | FD31218 | Dibenzotetrathiafulvalene | 24648-13-3 | 250mg | $160 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FD31218 | Dibenzotetrathiafulvalene | 24648-13-3 | 500mg | $250 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FD31218 | Dibenzotetrathiafulvalene | 24648-13-3 | 1g | $375 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | BTM0000098 | DIBENZOTETRATHIAFULVALENE 95.00% | 24648-13-3 | 500MG | $659.61 | 2021-12-16 | Buy |
Dibenzotetrathiafulvalene Chemical Properties,Uses,Production
Uses
Dibenzotetrathiafulvalene(DBTTF, also known as 1,3-Benzodithiole,2-(1,3-benzodithiol-2-ylidene)-) is an organic electronic material that can be used to form semiconductor charge transfer salts with electron accepting (n-type) materials (TCNQ and F4TCNQ). It can also be used to form charge transfer complexes (TCNQ and DDQ) with a variety of semiconductor crystals for the manufacture of organic field effect transistors (OFETs) and organic light emitting diodes (OLEDs).
Synthesis
Dibenzotetrathiafulvalene was prepared from 2,2'-Bi-1,3-benzodithiol under reaction conditions with 2,3-dicyano-5,6-dichloro-p-benzoquinone and dichloromethane. The specific method of operation is described below:
General procedure: Dithioacetal (0.1 mmol) and DDQ (68 mg, 0.30 mol) were dissolved in CH2Cl2 (3 mL). The resultant dark blue mixture was stirred at room temperature for 16 h and was then washed with a saturated NaOH aqueous solution (2 mL) and CH2Cl2 (10 mL). The orange organic phase was dried over anhydrous Na2SO4, filtered, and then evaporated under reduced pressure. The crude solid was recrystallized from hexane to give the corresponding dibenzotetrathiafulvalene derivative. Dibenzotetrathiafulvalene. Yield: 30 mg (99%); orange solid; mp 239.8-243.0 °C. 1H NMR (500 MHz, CDCl3): δ = 7.27-7.24 (m, 4 H), 7.13-7.10 (m, 4 H). 13C NMR (125 MHz, CDCl3): δ = 136.6, 125.9, 121.9, 110.6. MS (FAB): m/z = 304 [M+]. HRMS (FAB): m/z calcd for [M]+ (C14H8S4): 303.9509; found: 303.9519.
Dibenzotetrathiafulvalene Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
| Jilin Chinese Academy of Sciences-yanshen Technology | +undefined18143011203 | info@chemextension.com | China | 42056 | 58 |
| Aladdin Scientific | +1-+1(833)-552-7181 | sales@aladdinsci.com | United States | 57505 | 58 |
| Shanghai Aladdin Bio-Chem Technology Co.,LTD | 400-6206333 18021050169 | market@aladdin-e.com | China | 25003 | 65 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51456 | 80 |
| Wuhan Yuqing Jiaheng Pharmaceutical Co., Ltd | 027-83855382 15926260338 | 15926260338@163.com | China | 2030 | 58 |
| Energy Chemical | 021-58432009 400-005-6266 | marketing1@energy-chemical.com | China | 44807 | 58 |
| Jilin Chinese Academy of Sciences - Yanshen Technology Co., Ltd | 0431-80514535 19917294565 | caoy@chemextension.com | China | 4751 | 58 |
| JiangSu Star Science Co.,Ltd | 400-400-605-7200-7200 15335295587 | sales037@b2star.com | China | 3761 | 58 |
| Shanghai Maclean Biochemical Technology Co., LTD | 021-50706066 15221275939 | shenlinxing@macklin.cn | China | 30016 | 58 |