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(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE

(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE structure

CAS No.: 63126-47-6

Chemical Name:: (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE

Synonyms: SMP;H-PRO-OL(ME);H-S-PYR-MEOME;L-Prolinol-OMe;O-METHYL-D-PROLINOL;O-METHYL-L-PROLINOL;PROLINOL-METHYL-ETHER;L-PROLINOL METHYL ETHER;O-Methyl-L-prolinol, SMP;(S)-2-(METHOXYMETHYL)PYRROLIDINE

CBNumber:: CB2124340

Molecular Formula:: C6H13NO

Molecular Weight:: 115.17

MDL Number:: MFCD00010408

MOL File:: 63126-47-6.mol

MSDS File:: SDS

Last updated:2025-01-27 09:38:02

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(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE Properties

Boiling point	62 °C40 mm Hg(lit.)
Density	0.933 g/mL at 25 °C(lit.)
refractive index	n20/D 1.446
Flash point	114 °F
storage temp.	Keep in dark place,Inert atmosphere,2-8°C
solubility	sol H2O, ether, dichloromethane.
pka	10.01±0.10(Predicted)
form	Liquid
color	Clear colorless to yellow
optical activity	[α]20/D +2.4°, c = 2 in benzene
Sensitive	Air Sensitive
BRN	3587324
CAS DataBase Reference	63126-47-6(CAS DataBase Reference)
UNSPSC Code	12352005
NACRES	NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS07

Signal word

Warning

Hazard statements

H226-H315-H319-H335

Precautionary statements

P210-P302+P352-P305+P351+P338

Hazard Codes

Risk Statements

10-36/37/38

Safety Statements

26-36

RIDADR

UN 1993 3/PG 3

WGK Germany

3-9-34

HazardClass

PackingGroup

III

HS Code

29339900

NFPA 704

	2
3		1

(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE price More Price(41)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	277053	(S)-(+)-2-(Methoxymethyl)pyrrolidine 99%	63126-47-6	500mg	$92.6	2023-06-20	Buy
Sigma-Aldrich	277053	(S)-(+)-2-(Methoxymethyl)pyrrolidine 99%	63126-47-6	5g	$249	2023-06-20	Buy
TCI Chemical	M1161	(S)-2-(Methoxymethyl)pyrrolidine >98.0%(GC)	63126-47-6	1g	$72	2024-03-01	Buy
TCI Chemical	M1161	(S)-2-(Methoxymethyl)pyrrolidine >98.0%(GC)	63126-47-6	5g	$242	2024-03-01	Buy
Alfa Aesar	L09608	(S)-(+)-2-(Methoxymethyl)pyrrolidine, 98%	63126-47-6	1g	$107.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
277053	500mg	$92.6	Buy
277053	5g	$249	Buy
M1161	1g	$72	Buy
M1161	5g	$242	Buy
L09608	1g	$107.65	Buy

(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE Chemical Properties,Uses,Production

Chemical Properties

clear colorless to yellow liquid

Uses

(S)-(+)-2-(Methoxymethyl)pyrrolidine may be used to prepare planar chiral 2-phospha[3]ferrocenophanes. It may also be used as an organocatalyst in the cross-aldol reaction of dihydroxyacetone with p-nitrobenzaldehyde to form the corresponding polyol. SMP reacts with benzoylformic acid to form (S)-N-benzoylformyl-2-(methoxymethyl)-pyrrolidine.

Definition

ChEBI: (S)-2-(methoxymethyl)pyrrolidine is a member of the class of pyrrolidines in which the only substituent is a methoxymethyl group at position 2 (the S-enantiomer0. It is a member of pyrrolidines and an ether.

Application

(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE is used for chiral auxiliary; asymmetric syntheses with SMP enamines and SMP amides; asymmetric Birch reductions; asymmetric Diels-Alder reactions.

storage

(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE stores at 0-4 °C under an argon atmosphere.

(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE Preparation Products And Raw materials

Raw materials

Preparation Products

(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE Suppliers

Global( 177)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Capot Chemical Co.,Ltd.	+86-（0）57185586718 +86-13336195806	sales@capot.com	China	29792	60
career henan chemical co	+86-0371-86658258 +8613203830695	sales@coreychem.com	China	29871	58
Jinan Carbotang Biotech Co.,Ltd.	+8615866703830	figo.gao@foxmail.com	China	8497	58
Chongqing Chemdad Co., Ltd	+86-023-6139-8061 +86-86-13650506873	sales@chemdad.com	China	39894	58
Alchem Pharmtech,Inc.	8485655694	sales@alchempharmtech.com	United States	63687	58
CONIER CHEM AND PHARMA LIMITED	+8618523575427	sales@conier.com	China	49476	58
Shaanxi Dideu Medichem Co. Ltd	+86-29-87569262 +86-15003564040	1087@dideu.com	China	3167	58
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418671 +8618949823763	sales@tnjchem.com	China	34563	58
Win-Win chemical CO., Limited	+86-0086-577-64498589 +86-15355981851	sales@win-winchemical.com	China	14431	58
BOC Sciences	16314854226; +16314854226	inquiry@bocsci.com	United States	19741	58

Supplier	Advantage
Capot Chemical Co.,Ltd.	60
career henan chemical co	58
Jinan Carbotang Biotech Co.,Ltd.	58
Chongqing Chemdad Co., Ltd	58
Alchem Pharmtech,Inc.	58
CONIER CHEM AND PHARMA LIMITED	58
Shaanxi Dideu Medichem Co. Ltd	58
Hefei TNJ Chemical Industry Co.,Ltd.	58
Win-Win chemical CO., Limited	58
BOC Sciences	58

View Lastest Price from (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE manufacturers

Image	Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
	2019-07-06	(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE 63126-47-6	US $1.00 / kg	1kg	95%-99%	as request	Career Henan Chemical Co

(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE
63126-47-6
US $1.00 / kg
95%-99%
Career Henan Chemical Co

(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE Spectrum

(S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE(63126-47-6)IR (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE(63126-47-6)Raman

63126-47-6((S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE)Related Search:

L-PYROGLUTAMIC ACID PENTACHLOROPHENYL ESTER DIHYDROERGOTAMINE MESYLATE Ethyl D-(-)-pyroglutamate DIHYDROERGOTAMINE TARTRATE Methyl L-prolinate hydrochloride

Z-HYP-OME (R)-(+)-1-AMINO-2-(METHOXYMETHYL)PYRROLIDINE Methyl pyrrolidine-2-carboxylate hydrochloride (S)-(-)-1-AMINO-2-(METHOXYMETHYL)PYRROLIDINE H-PRO-OTBU

N-CBZ-L-PROLINE TERT-BUTYL ESTER (S)-(-)-2-(METHOXYMETHYL)-1-PYRROLIDINECARBOXALDEHYDE L-Proline benzyl ester hydrochloride Ethyl L-pyroglutamate (S,S)-(+)-2,5-BIS(METHOXYMETHYL)PYRROLIDINE

N-METHYL-D-PROLINOL (R)-(+)-1-FORMYL-2-(METHOXYMETHYL)PYRROLIDINE (S)-(+)-2-[HYDROXY(DIPHENYL)METHYL]-1-METHYLPYRROLIDINE

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(S)-2-Methoxymethyl-pyrrolidine hydrochloride L-PROLINOL METHYL ETHER H-PRO-OL(ME) H-S-PYR-MEOME PROLINOL-METHYL-ETHER O-METHYL-L-PROLINOL O-METHYL-D-PROLINOL (S)-2-PYRROLIDINEMETHYL-METHYL ETHER (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE (S)-2-(METHOXYMETHYL)PYRROLIDINE (S)-2-(METHOXYMETHYL)-PYRROLIDINEMETHYL SMP (S)-(+)-2-(METHOXYMETHYL)PYRROLIDINE, 99 % (S)-(+)-2-(Methoxymethyl)pyrrplidine PROLINOL-METHYL-ETHER, (S)-2-PYRROLIDINEMETHYL-METHYL ETHER, (S)-2-(METHOXYMETHYL)-PYRROLIDINEMETHYL (S)-2-Pyrrolidinemethyl-methyl ether, (S)-2-(Methoxymethyl)-pyrrolidinemethyl L-Prolinol-OMe O-Methyl-L-prolinol, SMP (S)-2-Methoxymethylpyrrolidine[SMP] (S)-(+)-2-(Methoxymethyl)pyrrolidine,O-Methyl-L-prolinol, SMP (2S)-2-(Methoxymethyl)pyrrolidine (S)-(+)-2-(Methoxymethyl)pyrolidine H-Pro-Ol-Me, O-Methyl-L-prolinol (S)-(+)-2-(MethoxyMethyl)pyrrolidine, 99% 2.5GR (S)-(+)-2-(MethoxyMethyl)pyrrolidine, 99% 500MG (S)-(+)-2-(MethoxyMethyl)pyrrolidine puruM, >=98.0% (suM of enantioMers, GC) SMP, O-Methyl-L-prolinol, L-Prolinol methyl ether (S)-2-(Methoxymethyl)-pyrrolidine HCl Pyrrolidine,2-(methoxymethyl)-, (2S)- (S)-2-(Methoxymethyl)pyrrolidine> (S)-(+)-2-(Methoxymethyl)pyrrolidine, 98.5% (+)-(S)-2-(Methoxymethyl)pyrrolidine 63126-47-6 631260-47-6 AMINE Chiral Catalysts, Ligands, and Reagents Proline-Based Organocatalysts Asymmetric Synthesis Imidazoles, Pyrroles, Pyrazoles, Pyrrolidines Asymmetric Synthesis Synthetic Organic Chemistry Chiral Compound