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ChemicalBook >> CAS DataBase List >>1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer

1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer

1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer Structure
1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer structure
CAS No.
467220-49-1
Chemical Name:
1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer
Synonyms
CX12;Umicore CX12;NAPHTHOQUINONE-1,3-BIS(MESITYL)IMIDAZOLE-2-YLIDENEPALLADIUM(0);PD(0)-NAPHTHOCHINONE-1,3-BIS(2,4,6-TRI-METHYLPHENYL)IMIDAZOL-2-YLIDENE;NAPHTHOQUINONE-1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLE-2-YLIDENEPALLADIUM(0);[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]palladium,naphthalene-1,4-dione;1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium dimer;1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene(1,4-naphthoquinone)palladium (0) dime;1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE(1,4-NAPHTHOQUINONE)PALLADIUM(O) DIMER;1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer
CBNumber:
CB2227603
Molecular Formula:
2C21H24N2Pd.2C10H6O2
Molecular Weight:
1138.02
MDL Number:
MFCD08705778
MOL File:
467220-49-1.mol
MSDS File:
SDS
Last updated:2026-09-12 18:50:31
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1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer Properties

Melting point >300 °C
storage temp. 2-8°C, protect from light, stored under nitrogen
form Powder
color orange-red
Sensitive air sensitive
InChI 1S/2C21H24N2.2C10H6O2.2Pd/c2*1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;2*11-9-5-6-10(12)8-4-2-1-3-7(8)9;;/h2*7-12H,1-6H3;2*1-6H;;
InChIKey ZTBFODSKEBBIJJ-UHFFFAOYSA-N
SMILES O=C1C=CC(=O)c2ccccc12.O=C3C=CC(=O)c4ccccc34.Cc5cc(C)c(N6C=CN(C6=[Pd])c7c(C)cc(C)cc7C)c(C)c5.Cc8cc(C)c(N9C=CN(C9=[Pd])c%10c(C)cc(C)cc%10C)c(C)c8
CAS DataBase Reference 467220-49-1
UNSPSC Code 12161600
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  Exclamation Mark (GHS07)
GHS07
Signal word  Warning
Hazard statements  H315-H317-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
target organs Respiratory system
PPE dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Hazard Codes  Xi
Risk Statements  36/37/38-43
Safety Statements  26-36/37
WGK Germany  3
HS Code  28439000
Storage Class 11 - Combustible Solids
Hazard Classifications Eye Irrit. 2
Skin Irrit. 2
Skin Sens. 1
STOT SE 3

1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 660272 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer 467220-49-1 1g $245 2026-04-30 Buy
Sigma-Aldrich 660272 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer 467220-49-1 250mg $90.2 2023-06-20 Buy
Strem Chemicals 46-0265 1,3-Bis(2,4,6-tri­methylphenyl)imidazol-2-ylidene(1,4-naphtho­quinone)palladium(0) dimer, 96% 96% 467220-49-1 250mg $77 2026-04-30 Buy
Strem Chemicals 46-0265 1,3-Bis(2,4,6-tri­methylphenyl)imidazol-2-ylidene(1,4-naphtho­quinone)palladium(0) dimer, 96% 96% 467220-49-1 1g $229 2026-04-30 Buy
aablocks AA003DEF 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene(1,4-naphthoquinone)palladium (0) dime 97% 467220-49-1 100mg $74 2026-05-28 Buy
Product number Packaging Price Buy
660272 1g $245 Buy
660272 250mg $90.2 Buy
46-0265 250mg $77 Buy
46-0265 1g $229 Buy
AA003DEF 100mg $74 Buy

1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer Chemical Properties, Uses, Production

Reaction

  1. Catalyst for Heck reactions in ionic liquids.
  2. Catalyst for the cross-coupling of aryl diazonium salts.
  3. Catalyst for the Kumada cross-coupling of alkyl chlorides.
Reactions of 467220-49-1

Chemical Properties

Orange crystal

Uses

It can be used as a catalyst in the Kumada cross-coupling of aryl magnesium reagents with functionalized alkyl chlorides at room temperature to form substituted alkanes.

General Description

1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer is an N-heterocyclic carbene based palladium catalyst that shows high catalytic activity in C-C coupling reactions.

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer Preparation Products And Raw materials

Raw materials

Preparation Products

1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer Suppliers

Global Suppliers ( 46)
Supplier Tel Email Country ProdList Advantage
J & K SCIENTIFIC LTD. 18210857532 18210857532 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006356688 18621169109 market03@meryer.com China 40202 62
Energy Chemical 400-0056266 sales8178@energy-chemical.com China 44852 61
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696 info@hanhongsci.com China 42917 64
Chengdu Ai Keda Chemical Technology Co., Ltd. 4008-755-333 18080918076 800078821@qq.com China 9706 55
Shanghai Incat Chemtech Co.,Ltd. 021-57603038 13601791340;13818007232 307593986@qq.com China 475 58
Shanghai JONLN Reagent Co., Ltd. 400-0066400 13621662912 422131432@qq.com China 9970 55
Chengdu HuaXia Chemical Reagent Co. Ltd 400-1166-196 13458535857 cdhxsj@163.com China 13323 58
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51389 80
Alfa Chemistry 1-516-6625404 support@alfa-chemistry.com United States 9170 60
Supplier Advantage
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Energy Chemical 61
Shanghai Hanhong Scientific Co.,Ltd. 64
Chengdu Ai Keda Chemical Technology Co., Ltd. 55
Shanghai Incat Chemtech Co.,Ltd. 58
Shanghai JONLN Reagent Co., Ltd. 55
Chengdu HuaXia Chemical Reagent Co. Ltd 58
Sigma-Aldrich 80
Alfa Chemistry 60

467220-49-1 (1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer) Related Search:

1 3-Bis(2 6-diisopropylphenyl)imidazol-& Naphthochinone-1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazole-2-ylidenepalladium(0)-dimer 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer
BIS[1,3-DIHYDRO-1,3-(2,4,6-TRIMETHYLPHENYL)-2H-IMIDAZOL-2-YLIDENE]BIS[MU-[(2,3-ETA)-1,4-NAPHTHALENEDIONE-KAPPAO]]DI-PALLADIUM PD(0)-NAPHTHOCHINONE-1,3-BIS(2,4,6-TRI-METHYLPHENYL)IMIDAZOL-2-YLIDENE NAPHTHOQUINONE-1,3-BIS(2,4,6-TRIMETHYLPHENYL)-IMIDAZOLE-2-YLIDENEPALLADIUM(0) 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene(1,4-naphthoquinone)palladium(0)dimer,96% bis[1,3-dihydro-1,3-(2,4,6-trimethylphenyl)-2h-imidazol-2-ylidene]bis[μ-[(2,3-η)-1,4-naphthalenedione-κo]]di-palladium NAPHTHOQUINONE-1,3-BIS(MESITYL)IMIDAZOLE-2-YLIDENEPALLADIUM(0) 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium dimer Umicore CX12 1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE(1,4-NAPHTHOQUINONE)PALLADIUM(O) DIMER [1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]palladium,naphthalene-1,4-dione 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene(1,4-naphthoquinone)palladium (0) dime 1,3-BIS(2,4,6-TRIMETHYLPHENYL)IMIDAZOL-2-YLIDENE (1,4-NAPHTHOQUINONE)PALLADIUM(0) DIMER ISO 9001：2015 REACH CX12 1,3-Bis(2,4,6-trimethylphenyl)imidazol-2-ylidene (1,4-naphthoquinone)palladium(0) dimer 467220-49-1 C62H60N4O4Pd2 C58H54N4O4Pd2 C21H24N2C10H6O2Pd2 Homogeneous Pd Catalysts Catalysis and Inorganic Chemistry Pd organometallic complex